Cobalt(II) and Manganese(II) Complexes of Novel Schiff Bases, Synthesis, Charcterization, and Thermal, Antimicrobial, Electronic, and Catalytic Features

Table 1

Electrochemical data of the title compounds.

Compound	Scan rate (mV/s)	() (V)	(V)	(V)
L^1	100	0.87, −1.18 (−0.57, 0.88)	0.88	0.01
	250	0.87, −0.06, −1.24 (−0.48, 1.00)	—	0.13
	500	0.94, −0.08, −1.32 (−0.42, 1.04)	—	0.15
	750	0.90, −0.12, −1.40 (−0.38, 1.12)	—	0.22
	1000	0.90, −0.14, −1.42 (−0.35, 1.14)	—	0.24
[Co(L^1)(H2O)2]2AcO	100	0.72, −1.14 (−0.58, 0.80)	—	0.12
	250	0.76, −1.28 (−0.50, 0.93)	—	0.17
	500	0.93, −1.40 (−0.46, 1.03)	—	0.16
	750	0.97, −1.47 (−0.46, 1.07)	—	0.21
	1000	0.87, −1.54 (−0.42, 1.17)	—	0.30
[Mn(L^1)(H2O)2]2AcO	100	0.98, −1.11 (−0.52, 1.07)	—	0.09
	250	0.98, −1.13 (−0.54, 1.02)	—	0.04
	500	0.97, −1.28 (−0.40, 1.08)	—	0.13
	750	0.96, −1.41 (−0.33, 1.26)	—	0.30
	1000	0.97, −1.47 (−0.26, 1.22)	—	0.25
L^2	100	0.09, −0.90 (−0.56, −0.01, 0.82)	—	−0.10
	250	0.91, 0.03, −1.01 (−0.53, 0.93)	0.92	0.02
	500	0.94, −0.02, −1.09 (−0.50, 0.95)	0.95	0.01
	750	0.98, −1.12 (−0.44, 0.99)	0.99	0.01
	1000	0.96, −1.31 (−0.35, 0.99)	0.98	0.03
[Co(L^2)(H2O)2]2AcO	100	1.13, −0.03, −0.91 (−0.53, 0.14, 1.25)	—	0.17
	250	0.99, −0.07, −0.96 (−0.47, 0.20, 1.10)	0.72	0.12
	500	0.96, −0.08, −1.02 (−0.50, 1.13)	0.76	0.17
	750	0.95, −1.19 (−0.41, 1.10)	—	0.15
	1000	0.97, −1.42 (−0.27, 1.10)	—	0.13
[Mn(L^2)(H2O)2]2AcO	100	1.10, −0.05, −0.92 (−0.54, 1.19)	—	0.20
	250	0.96, 0.01, −1.00 (−0.49, 1.18)	0.75	0.22
	500	0.97, 0.13, −1.12 (−0.42, 1.07)	—	0.12
	750	0.96, −1.22 (−0.30, 1.11)	—	0.15
	1000	0.93, −1.43 (−0.24, 1.15)	—	0.22