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Advances in Condensed Matter Physics
Volume 2010 (2010), Article ID 920860, 18 pages
Review Article

Electron-Phonon Interaction in Strongly Correlated Systems

ISC-CNR and Dipartimento di Fisica, Università di Roma “La Sapienza”, Piazzale Aldo Moro 5, 00185 Roma, Italy

Received 20 January 2010; Accepted 24 April 2010

Academic Editor: Alexandre Sasha Alexandrov

Copyright © 2010 M. Capone et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


The Hubbard-Holstein model is a simple model including both electron-phonon interaction and electron-electron correlations. We review a body of theoretical work investigating, the effects of strong correlations on the electron-phonon interaction. We focus on the regime, relevant to high- superconductors, in which the electron correlations are dominant. We find that electron-phonon interaction can still have important signatures, even if many anomalies appear, and the overall effect is far from conventional. In particular in the paramagnetic phase the effects of phonons are much reduced in the low-energy properties, while the high-energy physics can still be affected by phonons. Moreover, the electron-phonon interaction can give rise to important effects, like phase separation and charge-ordering, and it assumes a predominance of forward scattering even if the bare interaction is assumed to be local (momentum independent). Antiferromagnetic correlations reduce the screening effects due to electron-electron interactions and revive the electron-phonon effects.

1. Introduction

A wealth of materials, including the most challenging systems (cuprates, manganites, fullerenes, etc), present clear signatures of both electron-electron (e-e) and electron-phonon (e-ph) interactions, leading to a competition-or- interplay which can give rise to different physics according to the value of relevant control parameters and of the chemical and electronic properties of the materials. The results presented in this paper are mainly motivated by high-temperature superconductors, with the copper-oxide compounds (cuprates) in a prominent role, and an attention to the alkali-doped fullerides.

In the case of the cuprates, which are arguably the most accurately studied materials in the last twenty-five years, the signatures of electron-phonon interactions are nowadays clear, even though the overall scenario is far from ordinary [13]: Electron-phonon fingerprints are evident in some properties, while they are weak or absent in other observables. Specifically, clear polaronic features are observed in optical conductivity [46] as well as in angle-resolved photoemission experiments (ARPES) [7] in very lightly doped compounds. A substantial e-ph coupling can also be inferred by the Fano line shapes of phonons in Raman spectra and by the rather large frequency shift and linewidth broadening of some phonons at . Phonons are also good candidates to account for the famous “kink” in the electronic dispersions observed in ARPES experiments [8, 9]. Tunneling experiments are often advocated as providing the most important evidence of strong e-ph coupling [10]. Also Scanning Tunneling Spectroscopy measurements suggest a direct role of a phonon mode in superconductivity [11]. Isotope effects on different quantities can be sizable, even if they present highly unconventional features [12].

On the other hand, phonons, which typically affect resistivity in standard metals, hardly appear in transport experiments on cuprates. For instance, the resistivity around optimal doping is ubiquitously linear in temperature (even in systems with relatively low critical temperature) [1316] and no high-temperature saturation seems to be present up to the highest achieved temperatures [17]. While in the overdoped materials the resistivity evolves towards a Fermi-liquid behavior, it is the whole scenario at all dopings (and the material dependencies), which contrasts with the relevance of e-ph interaction in transport (at least in its standard formulation). If one were just considering cuprates with rather high critical temperatures around optimal doping (like, e.g., ) one would not find it difficult to get a reasonable agreement between transport experiments and the standard e-ph approach [10]. This dichotomous behavior of cuprates, which display clear phononic features in some experiments and limited effects in others is one of the puzzling and challenging issues raised in these materials.

Although there is a wide range of suggestions for the superconducting mechanism, it is almost universally recognized that a key player in the cuprate game is the e-e correlation. Electron-electron correlation makes the parent compounds Mott insulators, and is expected to be important at least in the pseudogap region. Therefore, it is not surprising that the signatures of e-ph interaction in the cuprates can hardly be understood in terms of the standard theory of e-ph interactions in weakly correlated metals, and a new theoretical framework including e-e correlations is needed. We will argue here that this change of perspective can indeed reconcile the different relevance of phonons in the various observables in correlated systems.

On the other hand, the superconducting members of the fulleride family, of composition AC with A an alkali-metal atom, are often considered as standard phononic superconductors, in which the coupling between electrons and the local vibrations associated the distortion of the carbon buckyballs is the driving force of superconducting pairing [18]. The conventional nature of these compounds is indeed challenged by recent investigations in expanded fullerides revealing several physical properties associated to e-e correlations [19]. Indeed, the CsC solid with A15 structure is an antiferromagnetic Mott insulator at ambient pressure which becomes superconducting only under applied pressure, with reaching 38 K [20, 21]. The phase diagram as a function of pressure closely resembles that of cuprates as a function of doping, suggesting a central role of correlations. Consequently, e-e interactions are expected to be important in other members of the fulleride family. Indeed, it has been shown that, thanks to the orbital degeneracy and the Jahn-Teller nature of the relevant phonons, there is no contradiction between a phononmediated superconductivity and the relevance of electronic correlations, and the two interactions turn out to cooperate in providing relatively high critical temperature [22].

In an extremely broad sense, these materials (cuprates and fullerides), as well as many others that we did not talk about, raise the same conceptual problem, namely the investigation of systems in which both e-e interaction and e-ph coupling are nonnegligible and the physics can be explained only taking both into account. On the other hand the same phenomenology suggests that this competition may result in completely different physics according to specific aspects of the materials. In general, we can expect different behaviors because of: (i) Different parameters within the same model (e.g., which is the largest scale between electron-phonon interaction and electron-electron repulsion); (ii) Different form for the interaction term, or more generally, different models.

Here we focus on point (i), and we choose an extremely simplified model, the Hubbard-Holstein model, in which one band of correlated electrons with local Coulomb repulsion is coupled with a dispersionless phonon mode and the coupling only involves the local electronic charge [23]. Even for this simplified model we immediately realize that several relevant physical parameters control the physics. As we will discuss in the following section, we have to deal at least with the electronic bandwidth, the Coulomb repulsion, the strength of electron-phonon interaction, the phononic frequency and the chemical potential that controls the band filling. This determines a multidimensional phase diagram, which can hardly be understood in its entirety within a single analysis and it is expected to present several different regimes. Therefore, even if we choose one given simple model, it may be useful to focus on a given physical regime, which essentially implies to select a hierarchy between the different energy scales, or to fix (or neglect) some of them.

Our choice is to focus on the “strongly correlated” metallic phases, that is, on system in which the Coulomb repulsion is the largest energy scale, and the system is either at half-filling (number of electrons equal to the number of sites) or close. The polar star of this work is the understanding of the fate of electron-phonon interaction in systems that are dominated by electron-electron interactions such as the cuprates. Nonetheless, our discussion will also follow some detours, which will help us to build a more comprehensive picture of the competition between the two interactions. One of these detours will touch point (ii) addressing the role of the phonon symmetry in its interplay with correlations. This point is crucial for the understanding of the synergy between e-ph interaction and e-e correlation in the fullerenes.

The paper is organized as follows: In Section 2 we introduce the Hubbard-Holstein model. Section 3 is devoted to a Fermi-liquid analysis of the effects of correlations on electron-phonon interactions and to a mean-field solution of the Hubbard-Holstein model within the slave-boson formalism. Section 4 presents a nonperturbative Dynamical Mean-Field Theory study of the Hubbard-Holstein model. Section 5 is dedicated to the charge instabilities of the model. Section 6 briefly compares the Hubbard-Holstein model with a three-band model with Jahn-Teller interactions introduced for the fullerenes. Section 7 presents our conclusions.

2. The Model

The simplest model of a strongly correlated electron system coupled to the lattice is given by the single-band Hubbard-Holstein (HH) model. In this work, the HH model is not used as a microscopic model for the cuprates, but rather as an idealized description of the competition between e-ph interaction and e-e interaction. In physical terms, the most crucial limitations is the local nature of the interactions. We refer to previous literature for analyses of nonlocal e-ph interactions [2428]. Considering a single band is a reasonable assumption for the cuprates, while in many materials the multiband nature needs to be taken into account.

The single-band HH model reads where indicate nearest-neighbor sites. is the local electron density, which is coupled via to the field of a dispersionless phonon [23]. The relevant physical parameters are the strength of the coulomb repulsion , the bare bandwidth , the bare phonon frequency , the bare dimensionless electron-phonon coupling , the chemical potential and the details of the bandstructure (e.g., inclusion of next-neighbor hopping). The chosen expression for would coincide with the standard definition (see, e.g., [29]) in the case of a band with a flat density of states . The dimensionality of the system also plays a major role. This multidimensional parameter space leads to an extremely rich physics, and the number of paper devoted to this simple model is countless. Various approaches have been considered to solve the HH model in the presence of strong correlations. Besides numerical techniques like quantum Monte Carlo [26, 3033], exact diagonalization [3439], and Dynamical Mean Field Theory (DMFT) [4050], Density-Matrix Renormalization Group [51, 52], (semi) analytical approaches like slave bosons (SB) [5357], large- expansions [58, 59], and variational approaches [24, 6063] including a modified Gutzwiller scheme [6466], have been useful to elucidate the renormalization of the e-ph coupling in the presence of (strong) correlations.

Even if our focus will be the strongly correlated HH model, we will discuss its results in comparison with some related models, like the Hubbard-tJ model, the three-band Hubbard model for the cuprates and a three-orbital Hubbard model with Jahn-Teller interactions for the doped fullerides. Our investigation will be mainly dedicated to the effects of e-ph interaction on the self-energy and the quasiparticle renormalization factor starting from a strongly correlated regime, in which the Coulomb interactions puts the system close to a Mott insulating phase. This is realized for large values of and for an half-filled or weakly doped band. Since the study of superconductivity within DMFT (our main tool of investigation) is limited to s-wave symmetry, we will not discuss superconductivity in the HH model which is expected to be d-wave if (repulsive) correlation dominates (specifically when the model can be mapped into a t-J model plus phonons). On the other hand we will study s-wave superconductivity in a three-orbital model for fullerides which emphasizes the role of the symmetry of e-ph interaction in presence of correlations.

3. Effect of Electron-Phonon Interaction in a Correlated Metal

3.1. Fermi-Liquid Analysis

In this section, we begin our analysis of the properties of e-ph interaction in a correlated metal within a Landau Fermi-liquid (FL) picture [29, 67]. Within this approach, the correlated metal is described as a collection of quasiparticles with an effective mass instead of the physical electron mass . In the presence of strong e-e correlations the motion of the carriers is naturally obstacled by the interactions, which is reflected in a large ratio between the effective mass and the bare mass and in a loss of low-energy spectral weight described by a small quasiparticle renormalization factor . The former reflects in an enhanced quasiparticle density of states ( being the bare density of states) and the latter renormalizes the quasiparticle interactions.

In order to characterize the fate of the e-ph interaction in a similar correlated metal, we need to consider also the vertex corrections introduced by e-e interactions, for which no Migdal theorem can be invoked.

We can gain a first insight on the way in which the e-ph interaction behaves in the presence of strong correlations by considering the effective dimensionless e-e interaction mediated by the exchange of a single-phonon By assuming that all the correlation effects are local, or equivalently that the self-energy is independent on momentum, the effective mass is related to by . In (2) includes the vertex corrections which renormalizes the e-ph vertex, and the last factor is the free phonon propagator. In order to focus on the effect of correlations on the phononmediated interaction, in both and we include only processes due to e-e interactions, as reminded by the index “e” that we attached to them.

Within a Landau Fermi-liquid picture we can use the Ward identities that connect the vertex corrections with the wavefunction renormalization . In the small frequency () and transferred momentum () regimes, these identities have two distinct forms depending on the order of the and limits. In the case of the charge-density vertex, which is relevant for our Holstein coupling, we have where is the symmetric Landau parameter. Equation (3) are exact Ward identities, which are satisfied irrespective of the details of the e-e interactions and show the drastic difference between the dynamic [] and static [] limits.

Plugging these results into (2) we obtain, in the two limits considered above where is the charge compressibility in the absence of e-ph coupling. The difference between the dynamic and static case can be dramatic in the case of a Fermi liquid with a large mass enhancement , and small compressibility renormalization . This requires to be much larger than one and proportional to the quasiparticle density of states . Equation (4) then lead to so that the effective one-phonon mediated e-e interaction is large in the dynamic limit and small in the static one. We emphasize that the key condition for the equalities (5) to hold is that . Therefore, they are verified also for a modest mass enhancement as long as the compressibility remains much smaller than it (cf. (4)).

The strong dependence in (5) has been demonstrated on really general grounds only in the small- and small- limits, whereas the case of finite 's and 's needs (approximate) analyses of specific models. The cases of the single-band and of the three-band Hubbard models with infinite local repulsion have been extensively considered in the literature as prototypical models of strong correlations. In this framework the issue of e-ph coupling has been considered by means of the Holstein [45, 53, 54, 58, 66] or (less frequently) of the so-called Su-Schrieffer-Heeger coupling (where phonons couple to the electron hopping term) [68, 69].

Results for these models show that the product remains of order one in the dynamical regime as long as the momentum and frequency lie outside the particle-hole continuum, while it is strongly suppressed (as in the static limit) inside the particle-hole continuum, where important screening processes take place. Moreover, strong correlations provide further suppression of the e-ph coupling when, within the static limit , the transferred momentum is increased [58]. These additional screening channels depend on the details of the electronic band structure determining particle-hole screening processes.

The general Fermi liquid discussion and the specific analysis of models with strong correlations generically demonstrates the relevant role of dynamics in the screening effects that e-e correlations induce on the e-ph coupling. This strong dependence of the e-ph vertex on momentum and frequency (and on their ratio) makes the effects of the e-ph coupling rather subtle, since different physical quantities, involving different dynamical regimes, may display more or less suppressed e-ph effects. In particular the e-ph coupling (and the e-e interaction mediated by phonons) will be depressed by strong e-e interactions whenever small energy and large momentum transfer are involved (e.g., in transport). This suppression may be substantial, for instance, in the low-doping region of the superconducting cuprates, where e-e correlations are strong due to the relative proximity to a correlation-induced insulating phase. On the other hand different physical processes involving dynamical processes could experience a more pronounced e-ph coupling. Specific calculations carried out in a single-band Hubbard-Holstein model within a large- treatment of the e-e correlations [58, 59] find that the Eliashberg spectral function determining superconductivity is much less reduced than the analogous quantity determining transport properties. As we will discuss in the following section, this different renormalization will found a counterpart in nonperturbative dynamical mean-field theory calculations.

Even if our focus is on the Hubbard-Holstein model, it can be useful to recall that in the case of phonons coupled to the electron current, Ward identities similar to those of (3) can be derived [67] where is the th component of the electronic vector vertex part. and are instead the th components of the quasiparticle velocity and of the current, respectively. Similarly to the case of a coupling with the density, the correlations suppress much more strongly the e-ph coupling in the static limit, while they affect little the coupling in the dynamical case (remember that the current is weakly touched by interactions and it even remains constant in translationally invariant systems).

3.2. The Hubbard-Holstein Model: Mean-Field Slave-Boson Approaches

A natural tool to address the screening effects beyond the small- and small- regime are mean-field approaches based on a slave-boson representation of the Hilbert space. These methods, although approximate, capture the main physical ingredients of the problem with a description of a Fermi liquid of quasiparticles coupled by a residual interaction. This is why we briefly summarize here some results obtained [54] in the simplest formulation of the slave-boson large- approach to the infinite- Hubbard model. Here one can reach a semiquantitative understanding of the effects of correlations on the e-ph coupling, which are in substantial agreement with the results of more sophisticated approaches.

In this discussion we will consider the infinite-repulsion limit, which simplifies the formalism. In this limit we have a sharp constraint of no double occupancy on each lattice site . The standard slave-boson technique implements the constraint [7076] by performing the usual substitution , where the fermionic operators represent quasiparticles, while the bosonic field labels the state of a site with no fermions in it. This formulation of slave bosons is here used in connection with a large- expansion [71] in order to introduce a small parameter allowing for a systematic perturbative expansion without any assumption on the smallness of any physical quantity. Within the large- scheme, the spin index runs from 1 to and the constraint assumes the form . A suitable rescaling of the hopping amplitudes must, in this model, be joined by the similar rescaling of the e- coupling in order to compensate for the presence of fermionic degrees of freedom. It is beyond the scope of this paper to report the technical details of this technique, which have been extensively presented in previous works [54]. Here we simply remind that the leading order in the large- expansion provides a mean-field description of the infinite- Hubbard model with uniform constant values of the bosonic field and of the Lagrange multiplier field implementing (on the average) the no-double-occupancy constraint. This gives rise to an insulating phase at half-filling (, doping ) and a Fermi liquid metallic phase at finite doping with small quasiparticle residue and large mass . The treatment of the fluctuations at the next leading order beyond mean-field introduces residual interactions between the quasiparticles and allows to determine the scattering amplitudes in the particle-particle (Cooper) channel and in the particle-hole channel . Taking the small- limits in this latter quantity also allows to determine the Landau parameter within the large- expansion. Setting we obtain Here is the bare electron dispersion calculated at the Fermi energy. As we already noted, enters in the FL expression of the compressibility. When the thermodynamic stability condition is violated and the system undergoes phase separation. We will discuss this issue in Section 6. We anticipate that, in the phase separated region, long-range Coulombic forces play a crucial role. It is indeed natural that a long-range interaction frustrates the formation of charge-rich regions. The outcome of this competition is, as we will see, a shift of the charge instability to finite momenta promoting the formation of a charge-density-wave phase. In this section we will consider parameters far from the phase separation instability. Nonetheless, in light of the central role played by long-range interactions in the phase separated case, we will also comment about their effect in these stable regions of parameters.

3.2.1. Static Properties

In the SB large- approach, the fluctuations of the bosonic fields mediate the residual interaction between the quasiparticles. If one only considers the fluctuations of the and fields, then only the effects of the electronic Hubbard repulsion are described and one can accordingly discuss the effect of the pure electronic screening processes on the e-ph vertex. For the specific model that we here briefly discuss, Figure 1 reports the Feynman-diagram representation of the electronic processes (schematized by the dashed line of the bosonic propagators) dressing the bare (empty dot) e-ph vertex. The ratio between the resulting screened e-ph vertex and the bare e-ph coupling is reported in Figure 2 both in the absence (dotted curve) and in the presence (solid curve) of a long-range Coulomb repulsion. In this latter case the strength is chosen to produce a repulsion of about  eV between electrons in nearest-neighbor cells. In both cases there is a strong reduction of the static e-ph coupling. In the short-range case the residual coupling is strongest at small momenta and it decreases as the momentum.

Figure 1: Leading-order in diagrammatic structure of the effective e- vertex dressed by electronic processes only: the dashed line is the slave-boson propagator only involving and bosons (pure e-e interaction), the solid dot is the dressed e- vertex, the open dots are the bare e- vertices and the grey dots are the quasiparticle-slave-boson vertices.
Figure 2: Static effective e- vertex in units of the bare e-ph coupling as a function of the transferred momentum (in units of the inverse lattice spacing ) in the direction. The vertex is calculated at leading order in for a HH model with  eV, ,  eV and doping . The dotted line is in the absence of long-range Coulomb forces (); the solid line is in the presence of long-range Coulomb forces with  eV (adapted from [54]).

On the other hand, as it is natural, the long-range potential screens out the long-range charge fluctuations thereby driving to zero the e-ph coupling at low momenta.

These findings can be obtained and confirmed with several different approaches. In particular, they reproduce exactly the results of large- calculations with Hubbard projectors instead of SB's [58, 59], and are in good agreement with calculations based on the flow-equation method [77] and recent Gutzwiller+RPA calculations at finite (but large) [66]. They also agree qualitatively QMC analysis [33] (although some differences are present, which can be attributed to the fact that QMC calculations are performed at finite temperature and at finite Matsubara frequencies) (cf. [66, Figures and ]).

All these results show that e-ph scattering at large momenta is typically weaker than scattering at low momenta in the presence of short range forces only (which is the case of metallic phases far from phase separation charge instabilities, where, on the contrary, long-range interactions start to play a crucial role). This can be of obvious relevance when the relative importance of e-ph couplings between the quasiparticles and specific phononic modes is considered [78]. Indeed it might well happen that in the presence of strong correlations modes that would be strongly coupled, but would exchange preferably large momenta, are more severely screened than other modes exchanging lower momenta. All this surely deserves a specific analysis.

3.2.2. Dynamical Properties

The previous subsection was focused on the screening of the static e-ph coupling by electronic processes. However the Fermi-liquid analysis carried out in Section 3.2 pointed out the great difference between screening processes in the static and in the dynamical regimes. While the Fermi liquid analysis was only able to provide definite statement in the small-() regime, within the SB large- approach we can investigate the role of dynamics in the screening processes beyond this limit.

Figure 3 displays the behavior of the effective e-ph vertex (again normalized to the bare ) as a function of Matsubara frequencies for two distinct momenta in the (1,0) direction for our HH model in the infinite- limit. In panel (a) a small momentum (again unit lattice spacing is used here) is reported, while panel (b) shows the behavior at a larger momentum . Clearly in the former case the e-ph coupling rapidly returns to its bare value, at Matsubara frequencies larger than . The scale is instead much larger in panel (b), where the effective e-ph vertex stays small over a much broader frequency range. This fully parallels the low-frequency and low-momentum limits discussed in Section 3.1.

Figure 3: Effective e-ph vertex in units of the bare e-ph coupling as a function of the Matsubara frequency in the HH model at leading order in . The parameters are the same as in Figure 2. Panel (a) is for a small transferred momentum (in units of inverse lattice spacing ); (b) is for a sizable transferred momentum (after [54]).

Again this result is not specific of this single-band model (or of its treatment) and it has been confirmed by the analysis of a three-band Hubbard model for the cuprate CuO planes with infinite repulsion on copper orbitals [53]. In this case, one can even notice in the small-momentum case an enhancement of the effective e-ph coupling above its bare value [79]. This is an overscreening effect due to interband processes. In any case, again one finds that low-momentum processes generically lead to larger e-ph couplings.

4. Strong-Coupling Regime and Polaron Formation in a Correlated Metal

4.1. Proximity to a Paramagnetic Mott Insulator

In this section we extend our analysis beyond the mean-field level and discuss the fate of the e-ph interaction in a correlated metal under the sole assumption that the physics is governed by the Hubbard repulsion close to a Mott-Hubbard transition, without assuming a weak e-ph coupling, and/or any approximation as far as the adiabatic ratio is concerned. This means that we need a theoretical approach able to treat several energy scales simultaneously, without assuming that any of them is negligible or perturbative. A natural candidate for this purpose is the Dynamical Mean-Field Theory (DMFT) [80], which treats all local interaction terms (such as both the Hubbard and the Holstein couplings) and the hopping term on the same footing and it is equally suitable to treat any parameter regime. Moreover, the method provides unbiased information about the dynamical properties.

The central approximation behind DMFT is the locality of the self-energy (both the electronic and the phononic contributions), a condition which becomes exact when the coordination number becomes large. The original lattice enters in the calculation only through the density of states, which we always choose to be a semicircular one of half-bandwidth (Obviously ). This approximation is appropriate for a model with local interactions such as our Hubbard-Holstein model, even if it does not allow to treat phases with nonlocal correlations such as intersite bipolarons [81] or d-wave superconductivity, which requires cluster extensions of DMFT. Even though these limitations imply that the approach can miss some important physics of the cuprates, our results provide valuable information about the interplay between e-e and e-ph interaction beyond any perturbative limit.

DMFT allowed to obtain a complete characterization of the Mott-Hubbard transition in the pure Hubbard model, and the emerging physical picture is able to explain several properties of correlated oxides. While we refer to original papers [80] for details, we recall here some aspects which are relevant to our discussion.

We first consider the half-filled system and, in order to focus on pure correlation effects, we consider a paramagnetic phase. In this regime, for large repulsion, the ground state of the HH model can become a “Mott” insulator, in which the electrons are localized because the electron motion is energetically unfavorable. Starting from the uncorrelated systems and increasing the correlation strength , the spectral weight is transferred from low to high frequency. In this process the spectral function evolves from a single band to a three-feature structure in which a renormalized band survives around the chemical potential, while precursors of the Hubbard bands develop around . As the correlation is further increased up to a value the quasiparticle band disappears, and the system becomes a Mott insulator with a preformed Hubbard gap. The key parameter that controls this Mott-Hubbard transition from a metal to an insulator is the quasiparticle weight , which is directly computed from the self-energy (which is a natural outcome of a DMFT calculation). measures the width and the total spectral weight of the low-energy quasiparticle peak, and its vanishing pinpoints the Mott transition. As soon as the system is doped away from half-filling the system is metallic regardless the value of . The chemical potential remains within the quasiparticle peak which moves towards one of the bands, but it is still well defined for a sizable doping region (dependent on the value of and on details of the bandstructure) [80]. Due to the momentum independence of the self-energy, also in DMFT we have that , so that the Mott transition is associated with a divergent effective mass of the renormalized carriers.

In the following part, we discuss the effect of a nonperturbative electron-phonon coupling in the strongly correlated metallic solution, that is, a system in which a quasiparticle peak at the Fermi level is separated from the Hubbard bands realizing a separation of energy scale. Starting from this situation, in which the quasiparticle bandwidth is times the bare width , the effect of the e-ph coupling is far from trivial. Indeed, there are two main effects associated to e-ph interaction. (i)The e-ph interaction can introduce a further quasiparticle renormalization, associated to the increase of the quasiparticle effective mass, which may eventually lead to polaronic effects for very strong coupling. This effect leads to a decrease of . In weak coupling we have at half-filling and a semicircular density of states of half width . (ii)The e-ph interaction mediates an attractive density-density interaction (the density-density form is specific for a Holstein coupling), which directly contrasts the Hubbard repulsion. If we integrate out the phonon degrees of freedom, the fermions interact through a dynamical (retarded) interaction [82] In the antiadiabatic regime the frequency dependence of the second term can be neglected and overall interaction is a static term , in which the e-ph interaction reduces the strength of the Hubbard term. When the phonon frequency becomes finite the interaction is retarded, but we still expect a similar effect. If we assume that the repulsion is the largest scale, the leading effect of e-ph interaction is to reduce the effective repulsion, making the system less correlated and increasing .

The balance between this two effects is not generic and it depends on the adiabatic ratio and on the precise value of the interactions. Yet, important conclusions can be drawn in the correlated regime, in which, also in the presence of e-ph interaction, the separation of energy scales determined by correlations survives. In this regard, it is important to recall that, within DMFT, the quasiparticle weight is associated to a Kondo resonance of an Anderson-Holstein impurity model. Assuming that the Hubbard is the largest scale of the problem, the Kondo coupling can be calculated in terms of virtual processes acting in the subspace in which the impurity is singly occupied obtaining an effective Hamiltonian for spin fluctuations [83]. The result is given by where the Kondo coupling in the absence of phonon is given by , is the state with phonons, and is the hybridization between the impurity and the bath. After some algebra, and introducing we can write, for small with This result would imply that the complicated interplay between the static Coulomb repulsion and the retarded e-ph coupling may be effectively described by an effective purely electronic Hubbard model with a reduced repulsion. We notice in passing that this calculation for the Anderson impurity model is analogous to the evaluation of the effect of phonons on the superexchange coupling of [84]. Interestingly the phonon dynamics only enters through the ratio , which can be considered as typically small because is by choice the largest scale of the problem, and is smaller than the hopping scale. In the relevant regime of small , we have .

These results can be tested through a DMFT solution of the Hubbard-Holstein model. We start our discussion from half-filling, where the separation of energy scales characteristic of correlated systems is clearer and more solid. We first computed the quasiparticle weight for finite fixed as a function of .

In Figure 4, we show the ratio , in order to emphasize the phonon contribution to the quasiparticle weight. It is apparent that the value of determines different regimes. For small , the e-ph interaction reduces (i.e., increases the effective mass) as expected in weakly interacting systems. Increasing , we approach an opposite behavior in which the e-ph interaction makes the quasiparticles lighter (even if they are obviously heavier than free particles because of the stronger renormalization determined by correlation, which is hidden in ). The effect becomes particularly strong at , which is very close to the Mott transition. Here even small variations of the effective can induce sizable variations in the effective mass. Obviously such sensitivity is enhanced in the present half-filling case, where an actual Mott transition can take place.

Figure 4: Effect of the electron-phonon interaction on the quasiparticle weight in the presence of electron-electron interaction of different strengths. The quantity plotted as a function of is the ratio between the full and the value of the Hubbard model without e-ph coupling () (after Sangiovanni et al. [45]).

This behavior confirms that, when the e-e correlation dominates, the leading effect of the e-ph interaction is a reduction of the effective , resulting in an increased quasiparticle mobility. We can now test the above prediction of an effective static repulsion including the effects of e-ph interaction as far as the low-energy physics is concerned.

Assuming a form for such an effective interaction, we obtained for several values of and simply determining the value of which gives, for a pure Hubbard model, the same we obtain for the Hubbard-Holstein model. The results are summarized in Figure 5, and confirm that is essentially a function of which starts off linear at small values of the argument before bending for larger values. The numerical value well reproduces (12) derived on the basis of the analogy with Kondo effect without fitting parameters. Obviously physically relevant frequencies are in the small range.

Figure 5: Effective static electron-electron interaction for the low-energy properties of the Hubbard-Holstein model. The picture shows the coefficient in as a function of (after Sangiovanni et al. [45]).

On the basis of our knowledge about the DMFT results for the pure Hubbard model, the quasiparticle weight completely characterizes the low-energy quasiparticle peak. Therefore, our analysis should imply that the low-energy part of the spectral function of our Hubbard-Holstein model can be described by means of the effective Hubbard model that we introduced. This is strikingly confirmed by a direct comparison, as shown in Figure 6. Here we show some examples of momentum integrated spectral functions for the Hubbard-Holstein model compared with the associated effective Hubbard model with the proper . Besides the spectacular confirmation of the validity of the effective model for the low-energy part of the spectrum (the quasiparticle peak), another important information emerges from the picture: The high-energy part of the spectrum is instead affected by phonons in a more “dynamical” way, meaning that the high-energy Hubbard bands acquire a modulation in frequency which can be related to phonon satellites, which are completely absent in the low-energy part, where nothing happens at the characteristic phonon frequency.

Figure 6: Comparison between the DMFT momentum-integrated spectral function ( being the local Green's function) for the Hubbard-Holstein model (dotted line) and the effective purely electronic Hubbard model with (solid line). The low-energy part of the spectra is perfectly reproduced by the effective model, while the high-energy features present phononic signatures that cannot be plugged in an effective static interaction (after Sangiovanni et al. [45]).

The picture that emerges for the half-filled model can be summarized as follows: Quasiparticle motion arises from virtual processes in which doubly occupied sites are created. Obviously, these processes are not so frequent, since the energy scale involved is large, but they are extremely rapid (the associated time scale is ), and consequently are poorly affected by phonon excitations with a characteristic time scale . When the phonon frequency is small with respect to , the phonon degrees are frozen during the virtual excitation processes. Therefore, despite the overall electron motion is quite slow due to the small number of virtual processes (which is reflected by the large effective mass), the e-ph interaction has no major effect except for a slight reduction of the total static repulsion.

According to what we have just described, we can conclude that strong correlations reduce the effect of the e-ph interaction on the low-energy properties, associated to quasiparticle propagation, while the high-energy properties present more standard phonon signatures, such as the satellites at the phononfrequency scale.

It has to be underlined that DMFT is not able to introduce momentum-dependent corrections to the electronic properties. The above analysis therefore, shows indeed that the “standard” electron-phonon interaction is heavily screened (and it actually loses its dynamical nature) when the low-energy quasiparticle properties are considered. Only “nonstandard” effects, such as the prevalence of forward scattering that we discussed in Section 3.1 can survive at low energy.

The above scenario has been carried out at half-filling, where the presence of e-e correlations has its most striking effects, both in terms of the phase diagram, as it can give rise to a Mott transition, and in terms of the separation of energy scales, which is clearly sharper than for doped systems. Therefore, as soon as we dope the Hubbard-Holstein model, even for the dominance of repulsive correlations is weaker and the interplay with e-ph coupling will be more subtle [46]. As a result, it is not possible to describe the effect of phonons on the highly correlated metal in terms of an effective static potential unless the system is very close to the antiadiabatic limit. Therefore, for small and intermediate phonon frequencies, we do not find situations in which increasing the electron-phonon coupling reduces the effective mass.

Nonetheless, if we consider reasonably large values of , the dominance of correlations will determine a reduce effectiveness of the e-ph coupling, and, for example, polaron formation will be pushed to significantly larger values of then for uncorrelated systems, as shown by the DMFT results of Figure 7. Here we plot as a function of and we compare the uncorrelated system with the system with (Here, since the density is different from half-filling, the system is always metallic even if is larger than the critical value for the Mott transition). While in the uncorrelated case grows exponentially when approaches a critical value of order 1 for all densities, signaling polaron formation, the correlated system displays a significantly weaker growth of up to .

Figure 7: Effective mass as a function of for three different densities different from half-filling in the uncorrelated (a) and strongly correlated (, (b)) system (after Sangiovanni et al. [46]).

The role of the adiabatic ratio is illustrated by Figure 8, where we report the renormalization of the linear coefficient of the mass enhancement defined by the relation . Here is the effective mass in the presence of both electron-electron and electron-phonon interactions and is the same quantity in the absence of coupling to the phonons. Here a negative implies a standard increase of the effective mass due to phonons. The results (again for ) show that in all cases the coefficient is smaller than one, confirming that correlations reduce the effective e-ph coupling, and a strong (and nonmonotonic) dependence on the antiadiabatic ratio. Only for very large values of becomes positive reflecting that the “screening” physics we described above is effective. The dependence on the density naturally reflects that fillings closer to display weaker phononic effects in the adiabatic regime of small frequencies and a more rapid evolution to an antiadiabatic regime in which .

Figure 8: Renormalization of the quasiparticle electron-phonon coupling as a function of for three different densities and (after Sangiovanni et al. [46]).

The scenario which emerges from DMFT calculations at finite can be confirmed by a semianalytical approach based on an extension of the Gutzwiller approach which treats phonon degrees of freedom on the same footing of the electrons. For more details see [64, 65]. The results of Figure 9 in the limit of infinite repulsion and for finite doping confirm the scenario arising from Figure 7: in the doped correlated system the electron-phonon interaction is considerably reduced with respect to the free system, but the qualitative effect of is an increase of the effective mass.

Figure 9: Renormalization of the effective mass due to electron-phonon coupling for infinite and as a function of for different doping levels. The inset shows the same data in a smaller range. Here the doping is given by and is twice as in the rest of the paper (after Barone et al. [64]).
4.2. Antiferromagnetic Correlations

The above analysis suggests that, as expected, strong e-e correlation essentially opposes to e-ph coupling, even though “anomalous” signatures of e-ph coupling still survive even in regions of parameters for which correlations prevail. Yet, these results are limited to the metallic paramagnetic state, in which no broken symmetry is allowed. At half-filling and for some finite doping region, strong correlations lead to an antiferromagnetically ordered state, and it is expected that finite-range antiferromagnetic correlations survive in a wider doping region. The relation between antiferromagnetism and e-ph interaction is hinted by the experimental framework. Indications of phonon signatures in high- superconductors are indeed particularly strong in the extremely underdoped region, where some kind of antiferromagnetic correlation is certainly present. For example, clear polaronic features are observed in the optical spectroscopy [85] and ARPES [7] of underdoped materials.

From a theoretical point of view, several investigations indeed suggest that the e-ph interaction is particularly effective for a hole in an antiferromagnetic background [8691], and for slightly doped t-J models. These results can be reconciled with the above findings for the nonmagnetic phase by simple arguments.

As we discussed in the previous sections, in the paramagnetic phase the effect of increasing correlations is a strong reduction of the quasiparticle weight associated with a divergent self-energy, which in turn strongly renormalizes the e-ph vertex, leading to the strong reduction of low-energy phononic signatures that we described above. Once antiferromagnetic correlations are allowed, the system can turn insulating even with a finite and a nondivergent self-energy, hence the e-ph vertex is not severely screened [92]. From a more physical point of view, the antiferromagnetic insulator allows for more charge fluctuations with respect to the pure Mott state at the same value of . Therefore, a Holstein coupling, which exploits precisely charge fluctuations to gain energy, is expected to be favored by antiferromagnetic correlations.

Direct DMFT calculations in the antiferromagnetic phase at half-filling confirm these expectations [92]. In Figure 10 we show the quantity for small ( being in the absence of e-ph interaction). This quantity measures the renormalizaton of the linear e-ph coupling induced by e-e correlations. The comparison between the paramagnetic solution and the antiferromagnetic state confirms the above expectations. While this coefficient rapidly drops as a function of in the paramagnetic state, the inclusion of antiferromagnetism leads to a much more robust e-ph coupling. We underline that, however, the e-ph interaction is still substantially reduced with respect to the noninteracting systems [92].

Figure 10: Effect of the Coulomb repulsion on the linear contribution in to the quasiparticle renormalization. DMFT results for the antiferromagnetic phase (AF-DMFT) are compared with DMFT in the paramagnetic state (P-DMFT) and to a self-consistent Born Approximation (SCBA) for the t-J model for parameters corresponding to the red dots AF-DMFT. Antiferromagnetism allows for a sizable e-ph coupling also in the present of very strong Coulomb repulsion, in contrast with paramagnetic results (after Sangiovanni et al. [92]).

The comparison with the uncorrelated system is shown in Figure 11, where the evolution of as a function of is followed beyond the perturbative regime. In all cases decreases monotonically, and a crossover from a metallic state to a polaronic one occurs. Yet, the decrease is more rapid for the uncorrelated system, and the characteristic coupling for polaron formation is significantly enhanced in the correlated antiferromagnetic state.

Figure 11: Quasiparticle renormalization as a function of for different values of and . The value of at which polaron formation occurs is only moderately increased by correlations with respect to the noninteracting case (after Sangiovanni et al. [92]).

The above discussion has been limited to half-filling. It is worth to briefly discuss the effect of doping in the antiferromagnetic state. In Figure 12 we present as a function of for different densities, which imply different values of the staggered magnetization . Notice that, within DMFT, the AFM state completely disappears only at . It is evident from the plots of Figure 12 that the reduction of the staggered magnetization reduces also the effect of the electron-phonon interaction. When the magnetization is small or vanishing, becomes essentially independent on for a wide range of values, signaling the screening of the e-ph interaction.

Figure 12: Quasiparticle renormalization as a function of for different values of the density (and consequently different magnetization ) at fixed and (after Sangiovanni et al. [92]).

5. Phonon Mediated Charge Instabilities

In the previous sections we focused on the metallic phases, without discussing the possible instabilities, either directly driven by the interaction terms, or favored by the weakness of the correlated metallic state. One can indeed expect, on very general grounds, that the reduced kinetic energy characteristic of the strongly correlated metal can be easily overcome by different localizing effects thereby destabilizing the metal in favor of ordered phases.

As we did in Section 3.1 in the discussion of the e-e screening of the e-ph vertex, we can start our analysis in a general FL framework before discussing in some more details model-specific results. The charge compressibility , which in a FL theory reads [29, 67] is the key quantity that controls the stability of the charge degrees of freedom. A positive is the stability condition. Therefore, if this condition is violated and the system undergoes a charge instability towards a phase-separated state.

It is important to stress that the results of Section 3.1 about the reduction of the static e-ph vertex do not necessarily imply that e-ph effects do not contribute to the charge compressibility in the presence of strong correlations. Indeed , where is the full dynamic effective scattering amplitude between the quasiparticles [67] including both e-e and e-ph interactions. As opposed to its static counterpart, the dynamic amplitude which enters is not depressed by the e-e vertex corrections. For example, at lowest order in and by performing an infinite-order RPA resummation of the e-ph screening processes, reads where is the dynamic vertex function determined by e-e correlation processes only. This equation indicates that a sufficiently large bare can overcome the effective residual repulsion between the quasiparticles leading to a phase separation instability marked by the Pomeranchuk condition . It is worth pointing out that requires a large bare repulsion between the physical electrons (a large Hubbard in our model) but this by no means requires a large residual interaction between the heavy quasiparticles. Therefore, even a small e-ph interaction can give rise to a phase separation instability.

Moreover, near the instability condition , the phonon contribution to the vertex becomes substantial and the e-ph interaction becomes relevant even in the static limit, at least at small 's. At large the analysis of specific models shows that the e-e interaction mediated by phonons is instead suppressed also near the instability region.

This is what indeed happens in the HH model treated within the SB-large- method described in Section 3.2. Within this approach it was first demonstrated that a metal with moderate e-ph coupling and strong e-e correlations could undergo a charge instability [54, 93] Specifically in the absence of long-range Coulombic forces the Pomeranchuk stability condition is violated. The doped HH model does not form a uniform phase and the system undergoes a phase separation between hole-rich regions and insulating half-filled regions (a phase separation instability was also found in the three-band HH model [53]).

In the presence of long-range Coulomb interactions the electrostatic cost of the charge-rich regions would become infinite, and the thermodynamic phase separation cannot take place. However, inhomogeneous charge-density wave ordering can establish as a compromise between the charge segregation tendency and the homogenizing effect of long-range interactions. This mechanism for charge ordering is the so-called “frustrated phase separation” [9497]. For the specific HH model described here it was found that for realistic values of the e-ph coupling and of the long-range repulsion, frustrated phase separation gives rise to a second-order quantum phase transition (quantum critical point, QCP) around optimal doping (doping ) [93] with the ordering and the periodicity influenced but not directly related to the structure of the Fermi surface. This instability arises instead from the energetic balance between the tendency to phase separation and the frustrating electrostatic cost of the long-range Coulomb interaction. Near this instability the phonon spectrum becomes highly anomalous. First of all the phonon acquires a strong coupling to the electronic degrees of freedom near the instability wavevector (which usually tend to occur at , for the relevant dopings and Fermi-surface shapes [54, 93]). Near the instability wavevector the phonon line-width becomes therefore, very broad and it even acquires a background of the order of the particle-hole continuum. At the same time the phonon dispersion softens and at the instability the frequency of this mixed phononelectron mode vanishes. Remarkably, since the critical wavevector is not so large (typically of the order of ) the region where the phonon dispersion becomes strongly anomalous is rather isotropic and substantial anomalies are present also in the (1,1) direction upon approaching the critical doping of the QCP. Figure 13 reports the anomalous phonon dispersion found in the HH model in [54].

Figure 13: Phonon dispersion curves (a) in the instability (0.28,0.86) direction and (b) in the (1,1) direction, for  eV, ,  eV,  eV, and  eV. The solid curves correspond to the critical doping , the dot-dashed and the dotted curves correspond to and , respectively.

Of course it is quite tempting to relate these anomalies, to the anomalies observed by inelastic neutron scattering [98104]. An alternative possibility can also be proposed for the anomalies detected in underdoped cuprates: charge ordering can give rise to rather anisotropic nearly one-dimensional dynamical charge textures. In this case Kohn anomalies can be expected along the stripes at wavevectors of the order in the stripe direction [105, 106].

6. Jahn-Teller Coupling in the Fullerenes

All the above analysis has been carried out for the HH model. It has to be emphasized that some of the effects we discussed may be less general than what the simple form of the Hamiltonian may suggest. As we discussed in details, the HH model is indeed characterized by two interaction terms which are both related to the charge degrees of freedom, and they indeed directly compete, as clearly shown by (8). This direct competition makes the two effects more exclusive than in general situations in which the e-ph coupling does not directly compete with the Coulomb repulsion. We can have two different ways to avoid the direct competition: a different functional form for the e-ph coupling in a single-band model, or a Jahn-Teller coupling in a multiorbital model.

The first situation can obviously have relevance for the cuprates, in which different phonon modes with specific symmetries may play a role, or for system dominated by the so-called Su-Schrieffer-Heeger coupling in which the phonons modulate the nearest-neighbor hopping. The second situation occurs instead in the fullerenes, where the relevant conduction band is a three-fold degenerate manifold of (-like) orbitals, which couple with Jahn-Teller active local distortions of the fullerene molecule. It is precisely this kind of coupling which is expected to be responsible for superconductivity in these compounds [18].

A three-band model which includes a strong Coulomb repulsion, a Hund's rule splitting and a moderate Jahn-Teller e-ph coupling has been studied in several papers [22, 107109], reaching an a priori surprising conclusion: The Jahn-Teller coupling is not harmed by large Coulomb repulsion, and the phonondriven superconductivity can actually be strongly enhanced in the proximity of the Mott transition, that is, in the region in which the correlations are most effective.

Here we do not discuss the physics of this model in details, since we are mainly interested in contrasting its behavior with the HH model. The key point is that the Jahn-Teller interaction does not touch the total charge on each molecule, as it couples with a combination of local spin and orbital degrees of freedom [22]. As a consequence, even when correlations are sufficiently strong to suppress the electronic motion, the localized electrons can still interact within a single fullerene molecule via the e-ph interaction. For example, if we consider the experimentally relevant situation of three electrons per fullerene molecule, as we approach the Mott state three electrons will remain stuck on each fullerene. Yet, the can still be in a high-spin state or low-spin state, and the energetic gain associated to the multiplet splitting will be the same as for a noninteracting molecule. Therefore, the e-ph driven interaction will be not renormalized by correlations, as opposed to the Holstein model. From a Fermi-liquid point of view, the lack of renormalization is determined by very large vertex corrections (divergent like as the Mott transition is approached) that compensate the factors [22, 109].

As a matter of fact, the effective interaction between quasiparticles obtained in a nonperturbative DMFT study of the model corresponds to a severely screened Hubbard repulsion plus an essentially unscreened phonondriven attraction that can be parameterized as where is the strength of the phononmediated attraction in the spin/orbital channel. This simple equation shows that, even if is chosen to be significantly larger than , when the Mott transition is approached (i.e., ) [107], the attraction will eventually prevail. Moreover, in this regime the quasiparticles are quite heavy, and their large effective density of states can lead to an enhancement of the effective dimensionless coupling, which is expected to reflect in an enhanced critical temperature.

This enhancement is explicitly found by solving the three-orbital model within DMFT in the s-wave superconducting phase. If we follow the evolution of the superconducting order parameter as a function of for a fixed small we first have a standard BCS-like region when is so small that the bare attraction simply overcomes the bare repulsion. Then superconductivity disappears because is large enough to kill the attraction, but is still close to 1. Further increasing we approach the Mott transition, decreases and it strongly renormalizes down the effective repulsion. Eventually the effective interaction becomes attractive and superconductivity re-emerges, with an order parameter that follows a bell-shaped curve before vanishing at the Mott transition point [22, 107]. This strongly correlated superconducting pocket displays a maximum critical temperature which exceeds the weak-coupling BCS value. In other words, phonondriven superconductivity is actually enhanced by strong correlations [22].

A full DMFT solution of the model has allowed both to predict the experimental observation only later provided in [20, 21], like the dome-behavior of the critical temperature as a function of doping, and the first-order transition to a spin-1/2 antiferromagnet when pressure is reduced to recover the ambient phase of A15 CsC, and to further characterize the properties of strongly correlated superconductors. For example, we predict a pseudogap in the photoemission spectra [110, 111], and a kinetic-energy driven superconductivity for the most expanded compounds [109].

In the context of this paper, our solution is a clear example of the crucial role of the phonon symmetry. In our multiband model it is possible to consider phonons which are by symmetry unharmed by correlations, as opposed to the Holstein model. The result is confirmed by investigations of simplified two-orbital models which share the same properties [110, 111] When we go back to the cuprates, and to single-band models, our findings suggest that phonon modes which are coupled to operators which are not proportional to the charge can indeed survive much better in a strongly correlated environment, in analogy with the findings of mean-field methods.

7. Conclusions

The focus of the paper is on the effects of strong electron-electron correlations on the electron-phonon coupling. We mostly considered the Hubbard-Holstein model, where both e-e and e-ph interactions locally couple to electron density fluctuations. In this case the competition between these interactions is quite effective, particularly in the proximity of the Mott-Hubbard transition.

In particular, we study strongly correlated metallic phases, where the system is either at half-filling or at small doping, and the correlation strength is large enough to put the system close to a Mott-Hubbard transition. In these conditions, since the e-e Hubbard repulsion makes the density fluctuations stiffer, the Holstein e-ph coupling is generically suppressed, even if the overall picture is far from trivial.

Along this paper we have discussed how this suppression depends on exchanged momentum and frequency, and on other physical parameters. A first observation is that the suppression is strong whenever the quasiparticle residuum is small. On the contrary we observed that in the antiferromagnetic phase, where the suppression of double occupancy imposed by the large Hubbard repulsion is due to the spin ordering and does not entail a small , the e-ph coupling is only weakly suppressed. This easily explains why polaronic features are present and clearly visible in weakly doped antiferromagnetic cuprates. The weakness of this suppression is likely to persist even in the metallic paramagnetic regime, if substantial residual antiferromagnetic correlations persist on a local basis. The opposite case of a strong suppression of the e-ph coupling,occurring for small (or more precisely when ), needs further specification. In particular we find that is more or less suppressed depending on the dynamical regime: for a small ratio between the transferred frequency and the transferred momentum the e-ph coupling is strongly reduced, while in the opposite limit no suppression is found and even an enhancement is possible. This latter finding leaves the possibility open of substantial phononic residual attractions between the quasiparticles competing with the residual repulsions in driving the system unstable toward long-wavelength charge instabilities. These two dynamical regimes are also visible in the DMFT approach where the scale is reflected in the width of the quasiparticle resonance. For frequencies smaller than this latter scale phononic features are absent, while they are clearly present at high-energy in the Hubbard sidebands.

The nearly static case again displays an intrinsic richness as far as momentum dependence is concerned: the strong suppression of already occurring at small momenta becomes really very strong at large transferred momenta. This suppression found both on general grounds within a Fermi-liquid analysis and within specific fieldtheoretic treatments of the Hubbard-Holstein model [53, 54, 58, 59, 77] can account for the impressive elusiveness of phononic features in transport experiments in cuprates. Indeed the fact that the resistivity in the metallic phase does not display any clear phononrelated feature is naturally explained by the strong suppression of the e-ph coupling in transport processes, where very low-energy and large transferred momenta are involved. Thus the strongly correlated nature of the cuprates is the key ingredient to solve the puzzles related to the dichotomous behavior of these materials, which display clear phononic features in some cases and none in others.

All the above findings are only partly peculiar of the specific HH model, where the electron density locally involves both the e-e and e-ph coupling: The analysis of other models like the Su-Schrieffer-Heeger [112] essentially produce the same results [68, 69, 113]. A qualitative difference only occurs for those phonons which couple to degrees of freedom which are not severely stiffened by the proximity to a Mott-Hubbard phase. In this regard we reported the important case of Jahn-Teller phonons in the Fullerenes. It would be interesting to search for similar phononic (or even nonphononic) degrees of freedom in the cuprates. In this regard, the buckling modes in some cuprates are interesting candidates, which are presently being investigated in this perspective [114].


The work that we review has been carried out in collaboration with G. Sangiovanni, P. Barone, S, Ciuchi, C. Di Castro, J. Lorenzana, G. Seibold, A. Di Ciolo, F. Becca, M. Fabrizio, E. Koch, O. Gunnarsson, P. Paci, and R. Raimondi. We acknowledge financial support by MIUR PRIN 2007 Prot. 2007FW3MJX003. M.Capone's activity is funded by the European Research Council under FP7/ERC Starting Independent Research Grant “SUPERBAD” (Grant Agreement no. 240524). M. Grilli acknowledges financial support from the Vigoni Program of the Ateneo Italo-Tedesco.


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