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Advances in Condensed Matter Physics

Volume 2013 (2013), Article ID 234546, 11 pages

http://dx.doi.org/10.1155/2013/234546

## Structural, Optical Constants and Photoluminescence of ZnO Thin Films Grown by Sol-Gel Spin Coating

^{1}Laboratoire de Nanotechnologie et d’Instrumentation Optique, Institut Charles Delaunay, CNRS UMR 6279, Université de Technologie de Troyes, 12 rue Marie Curie, BP 2060, 10010 Troyes Cedex, France^{2}National Institute of Laser Enhanced Science, Laser Sciences and Interactions, Cairo University, Giza 12613, Egypt^{3}Physics Department, Faculty of Education, Ain Shams University, Roxy, Cairo 11757, Egypt

Received 8 May 2013; Revised 17 August 2013; Accepted 4 September 2013

Academic Editor: Yuri Galperin

Copyright © 2013 Abdel-Sattar Gadallah and M. M. El-Nahass. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

#### Abstract

We report manufacturing and characterization of low cost ZnO thin films grown on glass substrates by sol-gel spin coating method. For structural properties, X-ray diffraction measurements have been utilized for evaluating the dominant orientation of the thin films. For optical properties, reflectance and transmittance spectrophotometric measurements have been done in the spectral range from 350 nm to 2000 nm. The transmittance of the prepared thin films is 92.4% and 88.4%. Determination of the optical constants such as refractive index, absorption coefficient, and dielectric constant in this wavelength range has been evaluated. Further, normal dispersion of the refractive index has been analyzed in terms of single oscillator model of free carrier absorption to estimate the dispersion and oscillation energy. The lattice dielectric constant and the ratio of free carrier concentration to free carrier effective mass have been determined. Moreover, photoluminescence measurements of the thin films in the spectral range from 350 nm to 900 nm have been presented. Electrical measurements for resistivity evaluation of the films have been done. An analysis in terms of order-disorder of the material has been presented to provide more consistency in the results.

#### 1. Introduction

One of the most important wide bandgap oxide semiconductors that draw worldwide attention of researchers is zinc oxide (ZnO) [1]. This unintentional n-type compound with hexagonal (wurtzite) structure possesses unique properties such as high electrochemical stability, resistivity control, transparency in the visible range with a wide bandgap, absence of toxicity, abundance in nature, important piezoelectric properties, and high quantum yield. These appealing properties are utilized in a wide range of applications including stimulated emissions with high optical gain and low loss [2], UV detectors [3], solar cells [4], light emitting diodes [5], and gas sensing [6]. Hence, there is continuous motivation to report manufacturing and characterization of ZnO.

More growth methods have been utilized for ZnO thin films including molecular beam epitaxy [7], metal-organic chemical-vapor deposition [8], pulsed laser deposition [2], radio frequency magnetron sputtering [9], spray pyrolysis [6], thermal oxidation, and sol-gel spin coating [10, 11]. Although these methods are used for the preparation of thin films, a simple and economic method, which has high growth rate and mass production capability and suitable for incorporating of foreign impurities (dopants), is generally desirable. Sol-gel spin coating is one of such methods which involves low cost equipments and raw materials. This method is basically a simple technology in which an ionic solution—containing the constituent elements of a compound in the form of soluble salts—is spun on the substrate and heated at the crystallization temperature. The polycrystalline ZnO thin films with c-axis orientation prepared by the sol-gel process depends on the sol concentration, heat-treatment conditions [11], substrates used [12], and film thickness [13].

In this effort, transparent and semiconducting nanocrystalline ZnO thin films have been grown by low cost sol-gel spin coating method on glass substrates. Investigations of the effect of the growth parameters such as preheating temperature, spin speed, initial concentration on the crystallization, optical constants, photoluminescence, and electrical resistivity of ZnO thin films are presented. In addition, an analysis in terms of order-disorder of the material to provide consistency in the results is reported.

#### 2. Material and Methods

Zinc acetate dihydrate, (CH_{3}COO)_{2} Zn·2H_{2}O (ZAD), diethanolamine (NH(CH_{2}CH_{2}OH)_{2}), and n-butyl alcohol (C_{4}H_{9}OH) were purchased from Oxford Laboratory Reagent, Scharlau, and British Drug Houses, respectively. All chemicals have been utilized without further purification. Thin films have been spun on a microscope glass substrates using spin coater, model Spin-1200D, MIDAS system.

The preparation method of ZnO thin films was reported elsewhere [10]. Namely, ZAD, n-butyl alcohol, and diethanolamine were utilized as a zinc precursor, solvent, and stabilizer, respectively. The concentration of ZAD was 1.3 M and 0.35 M for sample 1 (S1) and sample 2 (S2), respectively. The molar ratio of ZAD to diethanolamine was 1 : 1, and the volume of n-butyl alchohol is 10 mL. The resulting solution was stirred at 70°C to form a clear and homogeneous mixture. The transparent sol was left for about 24 h to allow good adhesion with the substrate. For cleaning the glass substrate, it was rinsed in boiling nitric acid for about 10 minutes and then rinsed in hot acetone and hot isopropanol. Finally, the substrate was rinsed in boiling distilled water. The substrate was then dried for 10 minutes, and it was ready for spin coating process. The coating solution was dropped onto the glass substrate, which was rotated at 3000 rpm for 30 s for S1 and 4000 rpm for 30 s for S2 using spin coater. Each as-coated film was heated from room temperature to 300°C (at a heating rate of 10°C/min) and then maintained at 300°C for 20 min. This preheating is to evaporate the solvents. These procedures were repeated four times. The samples were then heated at 550°C (at a heating rate of 10°C/min) and then maintained at 550°C for 2 h in a furnace in air ambiance to obtain a crystallized ZnO thin films.

The ZnO films were characterized by XRD for the structural properties using a Philips (PW1710 BASED) diffractometer. The surface morphology of the ZnO thin films was measured by scanning electron microscope, model Quanta 250 FEG.

Optical transmittance and reflectance spectra have been recorded by Jasco V-670 double-beam recording spectrophotometer in the range from 350 nm to 2000 nm. The absolute values of transmittance and reflectance have been calculated from the measured transmittance and reflectance [14–16]. The optical bandgap energy was estimated using an extrapolation of the linear portion of ()^{2} versus where is the absorption coefficient and is the photon energy. For investigating photoluminescence and photoluminescence intensity as a function of the excitation intensity, He-Cd laser operating at 325 nm and third harmonic pulsed Nd:YAG laser at 355 nm with density filters have been used as excitation sources. The laser beam was directed with an angle of 45° normal to the surface of the thin film and focused to a 1 mm^{2} spot. The backscattered emission normal to the surface was collected and focused to a spectrometer, which is coupled to a Peltier-cooled CCD camera. Electrical resistivity has been measured using four-point probe. All measurements have been carried out at room temperature.

#### 3. Results and Discussion

##### 3.1. Structural Investigations

Figure 1 shows the XRD results of S1 and S2. Both thin films show polycrystalline with hexagonal structure of ZnO (JCPDS card 79-0205). However, S1 has the strongest reflection at (002) plane which is the densest plane of this sample. On the other hand, S2 has the strongest reflection at (101), the densest plane of this sample. Reflections for planes (100), (002), (101), (102), (110), (103), and (112) are observed for both samples. Useful information that characterizes the growth is extracted from the XRD measurements. These include the average crystallite size, defect density, lattice strain, and stress. The average crystallite sizes () of the films have been calculated using Scherrer equation [17]: where , , and are X-ray wavelength (1.54 Å), full width at half maximum of the diffraction peak, and the diffraction angle. Using (1) and the data obtained from Figure 1, the crystallite sizes of S1 and S2 are 12.8 nm and 11 nm, respectively. Moreover, the defect density , defined as the length of the dislocation line per unit volume, is given by [18]

Its value for S1 is 6.13 × 10^{−3} nm^{−2} and for S2 is 8.31 × 10^{−3} nm^{−2}. The lower the dislocation density is, the better is the quality of the crystallized thin film. Further, the lattice strain caused by mismatch between the glass substrate and the ZnO thin film is given by [19]

This gives a lattice strain of 2.9 × 10^{−2} for S1 and 3.3 × 10^{−2} for S2. Further, the lattice constants of the hexagonal structure are given by [17]

The values of and for S1 are 3.295 Å and 5.289 Å. For S2, they are 3.295 Å and 5.317 Å. The standard values of and for the hexagonal structure of ZnO are 3.253 Å and 5.215 Å. Hence, these standard values are close to our reported values. The residual stress in the thin film can be determined by [20] where Å is the unstrained lattice constant for bulk ZnO. This gives a residual stress of −3.68 GPa for S1 and −4.94 GPa for S2. The minus sign indicates that the residual stress is compressive.

##### 3.2. Surface Morphology

Figure 2 shows top view micrographs of S1 and S2 using SEM measurements. It illustrates that both films are packed and continuous without the presence of porosity or voids. In addition, no cracking is observed. The surfaces of S1 and S2 are smooth. These effects are attributed to the fast ramp rate of 10°C/min. Such ramp rate produces small fine nuclei and lead to flat or smooth surface.

##### 3.3. Optical Properties

Transmission and reflection spectra from 350 to 2000 nm of the thin films are shown in Figure 3. As the concentration increases from S2 to S1, the transmission decreases. This is attributed to the increase of the roughness of the sample as the concentration increases. This is in agreement with the results published in [21]. The highest transmittance values at 2000 nm for S2 and S1 are 92.4% and 88.4%, respectively. S2 has low scattering and thus has higher transmittance than S1. For the reflectivity spectra of S2, it decreases with increasing the wavelength for wavelengths longer than the bandgap transition, which is the normal dispersion of the optical material. In addition, there is a peak in reflectivity near the bandgap wavelength and it is attributed to interband transition from the valence band to the conduction band. For S1, some peaks in the reflectivity curve are observed. Similar behavior is reported in [22]. The value of the reflectivity over measured wavelengths for this sample vary from about 5% to about 17%.

The absorption coefficient is related to the transmittance , the reflectance , and the film thickness by the following expression [23]:

Figure 4 illustrates the absorption coefficientfor S1 and S2 in the spectral region from 350 nm to 1100 nm. The absorption curve can be divided into three regions, namely, strong absorption region for nm, absorption tail region near the band edge for 390 nm 570 nm, and weak absorbing region for wavelengths >570 nm. In the strong absorption region, an electron in the valence band absorbs certain photon energy and transits to the conduction band leaving a hole in the valence band, that is, formation of exciton. In the absorption tail region, the electron transits to shallow states below the conduction band. Further, the absorption coefficient is related to the absorbance in the strong absorption region by Beer-Lambert’s law:

The film thickness is estimated from cross-sectional view of SEM and is 292 nm for S1 and 52 nm for S2. The peak value of the absorption coefficient is about 2.5 × 10^{5} cm^{−1} for S1 and 2.2 × 10^{5} cm^{−1} for S2. This value is compared to that obtained by pulsed laser deposition and other reported sol-gel technique. In addition, the relation between the absorption coefficient and the incident photon energy for determination of the optical bandgap is given by [24]
where is a constant and is equal to 1 for direct bandgap material such as ZnO. The constantdepends on the refractive index of the material and the probability of absorption. From the above relationship, the optical bandgap energy was estimated. The dependence of ()^{2} on is presented in Figure 5. From the figure, the value of is about 3.2 eV for S1 and 3.28 eV for S2. This shift in the optical bandgap from S1 to S2 is attributed to the decrease in the crystallite size. This confirms the results evaluated from X-ray diffraction measurements that the crystallite size of S2 is smaller than that of S1.

Figure 6 shows the dependence of the absorption coefficient on the energy of the incident photon near the band edge. Such dependence is governed by Urbach relation, which is [25] where is a constant and is the Urbach energy and it corresponds to the width of the band tail or the width of the localized state in the bandgap. Urbach energy can be evaluated from Figure 6 as the reciprocal of the slope in the linear part of the curve. Its value is 101 meV for S1 and 85.4 meV for S2.

The refractive index is related to reflectance, transmittance, and extinction coefficient by [23] where

Figure 7 shows the refractive index of the prepared ZnO thin films with different growth parameters. S2 has a peak in refractive index at the vicinity of the bandgap transition. The highest value of the refractive index of S2 near the interband transition is around 2.96. At wavelength of 1000 nm, the refractive index of S2 is around 1.8. S1 has anomalous refractive index dependence on wavelength. The highest value of refractive index of S1 is about 2.37 at 680 nm.

Real dielectric constant as a function of wavelength is shown in Figure 8. For S2, there is a peak in near the energy bandgap, which means a strong interaction between photons and electrons at this wavelength. The value of in the vicinity of the bandgap wavelength for sample S2 is 8.5. At 2000 nm the dielectric constant of S1 and S2 approaches the value of 3 to 3.2.

Imaginary dielectric constant of the prepared samples as a function of the wavelength is depicted in Figure 9. S2 has the highest value of at bandgap transition. At longer wavelengths, gets small for S1 and S2.

The volume energy loss function velf and surface energy loss function self, which are measures for the rate of energy loss of electrons as they traverse the bulk or the surface is plotted for the prepared thin films and depicted in Figure 10. The behavior of velf and self of the samples is similar. The value of velf is higher than that of self at higher energy. S2 with lower sol concentration has lower velf and self compared to S1. For S2, at energy of 3.5 eV the velf is around 0.07. This value increases to 0.45 for S1 at the same energy. The rate of energy loss in S1 is thus more than 6 times higher than that of S2.

For S2 at wavelengths longer than the bandgap wavelength, the refractive index decreases with increasing the wavelength. This suggests that the sample shows normal dispersion behavior. Thus, the dispersion data of the refractive index can be analyzed by single oscillator model [26], namely,
where and are the dispersion energy and oscillator energy, which are characteristics of the prepared thin films. Experimental verification for the pervious equation can be obtained by plotting versus ()^{2}. Figure 11 shows such plot. It depicts the dielectric response for energies below the optical bandgap. From the intercept of the straight line with and the slope of the straight line, one can determine the dispersion energy and the oscillator energy . They are 9.7 eV and 4.1 eV, respectively.

In the weak absorption region, the square of refractive index is related to the square of the wavelengthby the following relation [27]:
where ,, , , and /*m** are lattice dielectric constant, free space dielectric constant, electron charge, velocity of light, and ratio of free carrier concentration to free carrier effective mass. By plotting relation between *n*^{2} and, the lattice dielectric constant and the ratio of *N*/*m** can be obtained. Figure 12 shows this plot. The intercept of the curve with *n*^{2} axis at zero wavelength gives a lattice dielectric constant of 3.25. Further, the slope of the straight line gives the ratio of *N*/*m**, which is about cm^{−3} g^{−1}.

Disordering in ZnO thin films arises from two main sources, namely, point defects and line defects (also called dislocation). The point defects include oxygen vacancy , zinc vacancy , oxygen interstitial O_{i}, zinc interstitial , and antisite oxygen O_{zn}. These defect states introduce levels inside the bandgap of the material. Figure 13 shows a schematic drawing of the band structure of ZnO thin film [28]. Three types of transitions can occur in ZnO thin films with considering these levels into account. These transitions involve interband transition (transition from conduction band to valance band), free to bound transition (transition from valence band to impurity level), and bound to bound transition also called (donor-acceptor pair transition).

Figure 14 illustrates the photoluminescence of the prepared samples with He-Cd laser excitation. For S1, there are three bands peaked at around 380 nm, 523 nm, and 760 nm. The UV emission at 380 nm is due to radiative recombination of free exciton [29]. The emission in the green region at 523 nm is due to transition from the conduction band to oxgen antisite level. The calculated wavelength of this transition using Figure 13 is 521 nm, which matches the experimental result and is consistent with other reported work [28]. The peak at 760 nm is due to second order diffraction from the grating for the peak at 380 nm. S2 shows three bands peaked at around 398 nm, 520 nm, and 730 nm. The violet/blue at 398 nm could be attributed to donor-acceptor pair transition [30], and the green emission centered at about 520 nm is attributed to transition from conduction band to oxygen antisite level. The broad band centered at around 730 nm with a full width at half maximum (FWHM) of about 155.5 nm might be due to transition from conduction band to oxygen vacancy level; we refer to Figure 13.

The variation of photoluminescence from S1 to S2 can be analyzed in terms of order-disorder of the material. S1 shows emission at UV with FWHM of about 20 nm, whereas S2 does not show this band, but it shows emission at the violet/blue band. In fact, the interband UV emission is a measure of the ordering in ZnO, the higher and narrower this band, the better the ordering of the ZnO thin film. Besides, the violet/blue band in S2 is broad with a FWHM of about 60 nm, and it shows pronounced band shape asymmetry in the low energy side, which is an indication of the disordering in S2 compared to S1. Further, the photoluminescence intensity was measured as a function of the excitation intensity to explain order-disorder for both samples at both low excitation regime using CW He-Cd laser with power up to 1 W/cm^{2} and at high excitation regime using pulsed third harmonic Nd:YAG laser with power up to 1.3 MW/cm^{2}. The photoluminescence intensity is related to the excitation intensity through [30, 31]
where and are constants. For interband transition, and for donor acceptor pair or free to bound transition . Figure 15 shows the with He-Cd laser excitation. While the at 380 nm for S1 shows superlinear dependence on the excitation intensity with , the at 398 nm of S2 shows linear dependence on the excitation intensity. Further, Figure 16 shows with pulsed laser excitation. In this case, of UV band at 380 nm of S1 shows superlinear dependence on the excitation intensity with , while at violet/blue band of S2 shows power dependence with . Such power dependence agrees well with the literature, (14). S1 shows a variation of the peak photoluminescence wavelength of about 0.6 nm in low excitation and 6.7 nm in high excitation intensity as illustrated in Figure 17. Such red shift of about 6.7 nm is attributed to bandgap renormalization [32]. S2, on the other hand, shows a variation on the peak photoluminescence wavelength of about 1.8 nm using low excitation and 0.6 nm using high excitation intensity.

For electrical measurements of the films, the resistivity of S1 was measured using four-point probe. According to this method the resistivity is related to the film thickness , the voltage , and the current through [33]

Figure 18 shows the *I-V* curve of S1, from which the slope is obtained to evaluate the resistivity. It was found to be 82 MΩcm. For S2, the current was too low to be measured by the instrument. The low current arises from the disorder that occurs in S2, which is consistent with the results of photoluminescence and X-ray diffraction. Enhancing the electrical properties of these films is a future prospect by enhancing ordering or by intentional doping of the material.

#### 4. Conclusions

Growth of ZnO nanocrystalline thin films has been prepared by sol-gel method. Different preparation parameters such as initial zinc concentration, spin speed, and heating rate have been changed to obtain different properties of ZnO thin films. Structural characterization using X-ray diffraction for the samples has been reported. The transmittance of the thin films is 92.4% and 88.4% which is relatively high. Optical bandgap of the prepared samples has been estimated, and it varied from 3.2 to 3.28 eV. Real and imaginary dielectric constants of the samples have been reported. Using single oscillator model, the oscillation energy and the dispersion energy of the thin films have been reported, and they were found to be 4.1 eV and 9.7 eV, respectively. Velf and self of the prepared samples have been reported as a function of energy. They increase with increasing the initial zinc concentration. Photoluminescence measurements in the range from 350 nm to 900 nm have been investigated. Electrical resistivity for the films has been measured and explained. An analysis in terms of order-disorder of the material has been presented to provide more consistency in the results. It is believed that the low cost method of preparation and tuning the properties of the films is crucial in advancement of ZnO in different fields.

#### Acknowledgment

Abdel-Sattar Gadallah would like to thank G. Lérondel and Campus France for photoluminescence measurements and financial support, respectively.

#### References

- Ü. Özgür, D. Hofstetter, and H. Morkoc, “ZnO devices and applications: a review of current status and future prospects,”
*Proceedings of the IEEE*, vol. 98, pp. 1255–1268, 2010. View at Publisher · View at Google Scholar - A.-S. Gadallah, K. Nomenyo, C. Couteau, D. J. Rogers, and G. Lérondel, “Stimulated emission from ZnO thin films with high optical gain and low loss,”
*Applied Physics Letters*, vol. 102, no. 17, Article ID 171105, 4 pages, 2013. View at Publisher · View at Google Scholar - M. G. Ali, S. Singh, and P. Chakrabarti, “Ultraviolet ZnO photodetectors with high gain,”
*Journal of Electronic Science and Technology*, vol. 8, pp. 55–59, 2010. View at Google Scholar - Y.-H. Lin, P.-C. Yang, J.-S. Huang, et al., “High-efficiency inverted polymer solar cells with solution-processed metal oxides,”
*Solar Energy Materials and Solar Cells*, vol. 95, no. 8, pp. 2511–2515, 2011. View at Publisher · View at Google Scholar - L. J. Mandalapu, Z. Yang, S. Chu, and J. L. Liu, “Ultraviolet emission from Sb-doped p-type ZnO based heterojunction light-emitting diodes,”
*Applied Physics Letters*, vol. 92, no. 12, Article ID 122101, 3 pages, 2008. View at Publisher · View at Google Scholar - S. S. Badadhe and I. S. Mulla, “Effect of aluminium doping on structural and gas sensing properties of zinc oxide thin films deposited by spray pyrolysis,”
*Sensors and Actuators B*, vol. 156, no. 2, pp. 943–948, 2011. View at Publisher · View at Google Scholar - Y. W. Heo, D. P. Norton, and S. J. Pearton, “Origin of green luminescence in ZnO thin film grown by molecular-beam epitaxy,”
*Journal of Applied Physics*, vol. 98, no. 7, Article ID 073502, 6 pages, 2005. View at Publisher · View at Google Scholar - S. T. Tan, B. J. Chen, X. W. Sun et al., “Blueshift of optical band gap in ZnO thin films grown by metal-organic chemical-vapor deposition,”
*Journal of Applied Physics*, vol. 98, no. 1, Article ID 013505, 5 pages, 2005. View at Publisher · View at Google Scholar - Q. P. Wang, X. J. Zhang, C. Q. Wang, S. H. Chen, X. H. Wu, and H. L. Ma, “Influence of excitation light wavelength on the photoluminescence properties for ZnO films prepared by magnetron sputtering,”
*Applied Surface Science*, vol. 254, no. 16, pp. 5100–5104, 2008. View at Publisher · View at Google Scholar - K. C. Kim, E. K. Kim, and Y. S. Kim, “Growth and physical properties of sol-gel derived Co doped ZnO thin film,”
*Superlattices and Microstructures*, vol. 42, pp. 246–250, 2007. View at Publisher · View at Google Scholar - Y. Kim, W. Tai, and S. Shu, “Effect of preheating temperature on structural and optical properties of ZnO thin films by sol-gel process,”
*Thin Solid Films*, vol. 491, no. 1-2, pp. 153–160, 2005. View at Publisher · View at Google Scholar · View at Scopus - S. Chakrabarti, D. Ganguli, and S. Chaudhuri, “Substrate dependence of preferred orientation in sol-gel-derived zinc oxide films,”
*Materials Letters*, vol. 58, no. 30, pp. 3952–3957, 2004. View at Publisher · View at Google Scholar · View at Scopus - M. H. Aslan, A. Y. Oral, E. Menşur, A. Gül, and E. Basşaran, “Preparation of C-axis-oriented zinc-oxide thin films and the study of their microstructure and optical properties,”
*Solar Energy Materials and Solar Cells*, vol. 82, pp. 543–552, 2004. View at Google Scholar - M. M. El-Nahass, “Optical properties of tin diselenide films,”
*Journal of Materials Science*, vol. 27, no. 24, pp. 6597–6604, 1992. View at Publisher · View at Google Scholar · View at Scopus - A. M. Bakry and A. H. El-Naggar, “Doping effects on the optical properties of evaporated a-Si:H films,”
*Thin Solid Films*, vol. 360, no. 1-2, pp. 293–297, 2000. View at Publisher · View at Google Scholar · View at Scopus - H. Murmann, “Der spektrale Verlauf der anomalen optischen Konstanten dünnen Silbers,”
*Zeitschrift für Physik*, vol. 101, no. 9-10, pp. 643–648, 1936. View at Publisher · View at Google Scholar · View at Scopus - B. D. Cullity and S. Rstock,
*Elements of X-Ray Diffraction*, Prentice Hall, New Jersey, NJ, USA, 2001. - G. B. Williamson and R. C. Smallman, “Dislocation densities in some annealed and cold-worked metals from measurements on the X-ray debye-scherrer spectrum,”
*Philosophical Magazine*, vol. 1, no. 1, pp. 34–46, 1956. View at Publisher · View at Google Scholar - H. P. Klug and L. E. Alexander,
*X-Ray Diffraction Procedures for Polycrystalline and Amorphous Materials*, Wiley, New York, NY, USA, 1974. - Y. G. Wang, S. P. Lau, H. W. Lee et al., “Comprehensive study of ZnO films prepared by filtered cathodic vacuum arc at room temperature,”
*Journal of Applied Physics*, vol. 94, no. 3, pp. 1597–1604, 2003. View at Publisher · View at Google Scholar · View at Scopus - S. O'Brien, L. H. K. Koh, and G. M. Crean, “ZnO thin films prepared by a single step sol-gel process,”
*Thin Solid Films*, vol. 516, no. 7, pp. 1391–1395, 2008. View at Publisher · View at Google Scholar · View at Scopus - C. E. Benouis, A. Sanchez-Juarez, and M. S. Aida, “Physics properties comparison between undoped ZnO and AZO, IZO doped thin films prepared by spray pyrolysis,”
*Journal of Applied Sciences*, vol. 7, no. 2, pp. 220–225, 2007. View at Google Scholar · View at Scopus - M. Di Giulio, G. Miccci, R. Rella, P. Siciliano, and A. Tepore, “Optical absorption of tellurium suboxide thin films,”
*Physica Status Solidi A*, vol. 136, pp. K101–K104, 1993. View at Publisher · View at Google Scholar - J. Tauc,
*Amorphous and Liquid Semiconductors*, Plenum, London, UK, 1974. - F. Urbach, “The long-wavelength edge of photographic sensitivity and of the electronic absorption of solids,”
*Physical Review*, vol. 92, no. 5, pp. 1324–1324, 1953. View at Publisher · View at Google Scholar - S. H. Wemple and M. DiDomenico, “Behavior of the electronic dielectric constant in covalent and ionic materials,”
*Physical Review B*, vol. 3, no. 4, pp. 1338–1351, 1971. View at Publisher · View at Google Scholar · View at Scopus - P. O. Edward,
*Handbook of Optical Constants of Solids*, Academic Press, New York, NY, USA, 1985. - B. Lin, Z. Fu, and Y. Jia, “Green luminescent center in undoped zinc oxide films deposited on silicon substrates,”
*Applied Physics Letters*, vol. 79, no. 7, p. 943, 2001. View at Publisher · View at Google Scholar - X. Q. Zhang, I. Suemune, H. Kumano, J. Wang, and S. H. Huang, “Surface-emitting stimulated emission in high-quality ZnO thin films,”
*Journal of Applied Physics*, vol. 96, no. 7, pp. 3733–3736, 2004. View at Publisher · View at Google Scholar · View at Scopus - M. Peres, S. Magalhães, M. R. Soares et al., “Disorder induced violet/blue luminescence in rf-deposited ZnO films,”
*Physica Status Solidi C*, vol. 10, no. 4, pp. 662–666, 2013. View at Google Scholar - T. Schmidt, K. Lischka, and W. Zulehner, “Excitation-power dependence of the near-band-edge photoluminescence of semiconductors,”
*Physical Review B*, vol. 45, no. 16, pp. 8989–8994, 1992. View at Publisher · View at Google Scholar · View at Scopus - D. M. Bagnall, Y. F. Chen, Z. Zhu, T. Yao, M. Y. Shen, and T. Goto, “High temperature excitonic stimulated emission from ZnO epitaxial layers,”
*Applied Physics Letters*, vol. 73, no. 8, pp. 1038–1040, 1998. View at Publisher · View at Google Scholar · View at Scopus - F. M. Smits, “Measurement of sheet resistivities with the four-point probe,”
*Bell System Technical Journal*, vol. 37, no. 3, pp. 711–718, 1958. View at Publisher · View at Google Scholar