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Advances in Condensed Matter Physics
Volume 2013 (2013), Article ID 505219, 10 pages
History-Dependent Patterns in Randomly Perturbed Nematic Liquid Crystals
1Faculty of Natural Sciences and Mathematics, University of Maribor, Koroska 160, 2000 Maribor, Slovenia
2Condensed Matter Physics Department, Jožef Stefan Institute, Jamova 39, 1000 Ljubljana, Slovenia
3Department of Physics, University of Athens, 15784 Athens, Greece
Received 4 April 2013; Accepted 25 May 2013
Academic Editor: Lucjan Jacak
Copyright © 2013 A. Ranjkesh et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
We study the characteristics of nematic structures in a randomly perturbed nematic liquid crystal (LC) phase. We focus on the impact of the samples history on the universal behavior. The obtained results are of interest for every randomly perturbed system exhibiting a continuous symmetry-breaking phase transition. A semimicroscopic lattice simulation is used where the LC molecules are treated as cylindrically symmetric, rod-like objects interacting via a Lebwohl-Lasher (LL) interaction. Pure LC systems exhibit a first order phase transition into the orientationally ordered nematic phase at on lowering the temperature . The orientational ordering of LC molecules is perturbed by the quenched, randomly distributed rod-like impurities of concentration . Their orientation is randomly distributed, and they are coupled with the LC molecules via an LL-type interaction. Only concentrations below the percolation threshold are considered. The key macroscopic characteristics of perturbed LC structures in the symmetry-broken nematic phase are analyzed for two qualitatively different histories at . We demonstrate that, for a weak enough interaction among the LC molecules and impurities, qualitatively different history-dependent states could be obtained. These states could exhibit either short-range, quasi-long-range, or even long-range order.
Domains often appear in phases of broken continuous symmetry [1, 2]. The reason behind this is causality that is a finite speed of the information propagation . Consequently, in a fast enough phase transition in a different part of systems a different gauge component of the order parameter field is selected. This results in the appearance of regions in which the gauge field is essentially spatially homogeneous. These regions are referred to as domains and the mechanism of their formation as the Kibble-Zurek mechanism . At boundaries between domains topological defects (TDs)  reside carrying a topological charge . The total topological charge of the system is conserved. At a given time, a domain pattern is well determined by a single characteristic size . The initial size of visible domains (the so-called protodomains) is dictated by the phase transition quench rate [4, 6, 7]. The domain walls are energetically costly, and, consequently, the average domain size grows with time following the scaling law , where is a universal scaling coefficient . This growth is enabled by the annihilation of defects and antidefects. In ideal pure systems, a single domain would be gradually formed as a function of time. However, when impurities are present, they could stabilize the domain pattern depending on their concentration and interaction with the host . In some cases, impurities could be the carriers of topological charge, and thus, they give rise to additional TDs in order that is conserved. The resulting domain pattern might be very complex and exhibit strong memory effects . Different domain configurations could lead to effectively new materials , which can be exploited in various electrooptic applications, memory elements, and so forth. Consequently, it is of interest to understand in detail the mechanisms that control the key domain pattern characteristics.
Nematic liquid crystals (LCs) comprise a convenient, simple, and experimentally relatively easily accessible system to study the domain patterns. Due to their soft and liquid-like character, one can tune their structure using a relatively low power. In addition, they are optically transparent and anisotropic, which allows one to monitor the LC patterns using simple optical experiments (e.g., observing the textures by means of polarizing optical microscopy). For simplicity we henceforth consider LCs formed by rod-like molecules. In thermotropic LCs, a nematic () phase is reached on lowering temperature from the isotropic () phase. The latter phase is characterized by an isotropic liquid character. In the nematic phase the continuous symmetry is broken, and the molecules tend to be on average aligned parallel along a common direction, referred to as the director field , where the states are equivalent and . In equilibrium bulk phase is homogeneously aligned along a single symmetry-breaking direction.
In the past few decades, several studies have analyzed the phase transition and structural behavior of mixtures of LCs with aerosil spherical particles [10–14]. These mixtures represent adequate experimental model systems to study the influence of qualitatively different origins of disorder on phases with broken continuous symmetries. By changing the mass density of the aerosil particles, at least three qualitatively different regimes are established [11, 12]. Various studies report that either short-range order, quasi-long-range order or even long-range order might be established. In some cases glassy-like behavior and pronounced memory effects are also reported [10–14].
In this paper, we focus on the impact of history on nematic structures in randomly perturbed LCs. We use random anisotropy nematic (RAN) lattice model in which rod-like impurities and LC molecules interact via a Lebwohl-Lasher type interaction . Such systems roughly simulate the mixtures of LCs and aerosils. The macroscopic nematic structural properties are studied as a function of the impurities concentration , for a given interaction strength between impurities and LC molecules, and for two extremely different sample histories. It is shown that the nematic structures can exhibit either long-range order (LRO), quasi-long-range order (QLRO), or short-range (SRO) order on varying the disorder strength and sample history. In the case of QLRO orientational correlations decay algebraically with distance. Topological reasons for random-field type of disorder in mixtures of LCs and impurities are described in Section 2. The model we use to study macroscopic properties of systems of our interest is defined in Section 3. The corresponding results are presented in Section 4. Key conclusions are summarized in the last section. Some supporting derivations are assembled in the appendices.
2. Topology and Random-Field-Type Disorder
In mixtures of LCs with different particles (colloids or nanoparticles), to which we refer as impurities, the latter often introduces into the system a random-field (RF) type of disorder. In this subsection we present the basic mechanisms that mediate such a behavior.
At the continuum level, a local average orientation of LC molecules in the nematic phase is given by the director field and the scalar order parameter describing the amount of fluctuations about that direction. In the isotropic phase it holds , whereas a perfect alignment corresponds to . The equilibrium orientational configuration at a given temperature, for a fixed volume of the system, minimizes the free energy  The condensation free energy contribution term determines the degree of ordering in the bulk LC in the absence of any elastic distortions. The elastic term determines the elastic penalties if the system exhibits spatial inhomogeneities. The field term describes the impact of the external electric or magnetic fields. The interfacial contribution presents the interactions at the LC-particle interfaces. Within the lowest order approximation these terms are typically expressed as 
Here , , , represent material constants, and are the representative elastic constants, stands for an external ordering electric or magnetic field, is the corresponding field anisotropy constant, is the local normal of an LC-impurity interface, and is the surface interaction constant. It roughly holds that the quantities , , , , , and are temperature independent and .
In the bulk nematic equilibrium and in the absence of impurities, the LC orientational ordering is homogeneous along a single breaking direction. However, due to the broken continuous symmetry the nematic director field could exhibit topological defects (TDs), at which is not uniquely defined. Their key feature is defined by the topological charge [5, 17, 18].
The topological charge plays the key role in the classification of TDs in condensed matter. For a general -dimensional unit vector field , , in -dimensional space it is defined as  where are the coordinates determining the () dimensional sphere enclosing the defect and is the normalization constant. For example, for it holds , , and integration is performed along a closed line: For it holds , , and integration is performed along a closed surface: The stability of an isolated defect is guaranteed by the conservation of its topological charge. For example, a defect exhibiting a radial distribution of corresponds to . Furthermore, the total topological charge of the vector field enclosed within the () dimensional surface is conserved. The conservation laws of TDs are analogous to the laws of electric charges. They regulate the decay, merging, annihilation, and/or mutual transformations of TDs.
We henceforth focus our interest on the nematic LC ordering. Note that the nematic LC phase is characterized by the head-to-tail invariance of the director field . Therefore, for the sign of does not play a role. For later convenience we assign to the nematic defects (antidefects) a positive (negative) value of . One typically refers to the nematic TDs bearing () as the nematic monopole or hedgehog (antimonopole, antihedgehog). The nematic monopole and antimonopole attract each other and they tend to be mutually annihilated into a defect-free state characterized by . The total topological charge within a given volume is conserved if the boundary conditions remain unaltered. For example, for a homeotropic alignment at an enclosing surface (i.e., is aligned along the local surface normal) it holds . The quantity determines the Euler characteristic [5, 17] of the closed surface and is topologically invariant (it does not change under smooth deformations). For example, for the spherical topology it holds and.
In order to illustrate the impact of topology on the structural characteristics of the systems of interest, we consider a mixture of nematic LC and spherical impurities of radius . We set that the LC-impurity interfaces enforce a homeotropic anchoring (i.e., in (2d)). In the case of weak anchoring realized for , the elastic term prevails over the interface tendencies. Consequently, the impurities have mainly a dilution impact that reduces the effective LC-LC interactions as illustrated in Figure 1(a). In case that the system boundary conditions do not enforce a topological charge, the total topological charge equals to . In the strong anchoring limit, realized for , each impurity effectively acts as a radial hedgehog bearing a topological charge . The topological charge conservation law requires that a compensating antidefect with is created in the LC matrix. For appropriate LC elastic properties the combination of defect-anti-defect forms an effective topological dipole [19, 20] as shown in Figure 1(b). The corresponding structure enforces a local orientational anisotropy. On the contrary, an isolated impurity does not enforce any anisotropy. In some cases the interactions between impurities (e.g., in mixtures of LCs and aerosils where the latter tend, to self-assemble; see [11, 12]) give rise to an essentially randomly shaped network of impurities. Consequently, the orientational distribution of topological dipoles could be essentially randomly distributed within a system, imposing to the surrounding LC medium a kind of random field. These are the cases that are considered henceforth.
3. Theoretical Background
We use a semimicroscopic lattice model consisting of rod-like LC molecules and rod-like impurities. The orientational ordering of either of them at an th lattice site is presented by a unit vector exhibiting head-to-tail invariance (i.e., states and are equivalent). The LC molecules () and impurities () are henceforth referred to as LC spins and impurity spins, respectively. They occupy lattice sites of a 3D cubic simulation cell. A typical value of is chosen. An th site is occupied either by an LC or an impurity spin. Impurities of concentration are randomly distributed; thus, the system possesses impurities. Their orientations are also randomly distributed and quenched with time.
3.1. Interaction Potential
The total interaction of the system is given as the sum over the lattice site contributions , where [13, 21–23] The 1st term describes the short-range interaction between neighboring spins. The coupling constant can have one of the three values: (1) 0, if both neighbors are impurities (i.e., their orientations are quenched); (2) , if both neighbors are LC spins; and (3) for neighboring LC and impurity spins. The second part of (6) describes the interaction between the external field and the LC spins, where . At the mesoscopic level the first term in (6) is described by (2a), (2b), and (2d). Furthermore, the 2nd term corresponds to (2c).
In simulations we take into account the normalization by introducing the Lagrange multipliers in the functional , where The functional is minimized with respect to LC spins , yielding equations: Here is commonly referred to as the residuum, and is defined as In the absence of thermal fluctuations (i.e., at ), (4) is solved using the standard overrelaxation method. For finite temperatures the final (equilibrium or metastable) states are reached via the “real-time” relaxation process. The change of spin components in a time step is given by Here is the appropriate degenerated rotation diffusion constant of the system, and is the Boltzmann constant. The second term on the right hand side of (10) corresponds to the mechanical torque which tends to rotate an LC spin towards equilibrium, while the third term represents the random thermal fluctuations. Its determination is described in Appendix A.
We henceforth set and introduce a dimensionless time step and temperature . In the simulations it is set in order to obtain sensible reference results in bulk nematic phase.
It follows Using this method the fixed point configurations are calculated, for which the macroscopic properties of the system do not anymore change as a function of time. Therefore, these configurations correspond either to equilibrium or to metastable states surrounded by relatively high energy barriers.
3.2. Measured Quantities
From reached fixed point configurations the average tensor order parameter of a system and the orientational correlation function are calculated.
The traceless symmetric order parameter tensor, describing the average behavior of the whole system, is defined as The brackets denote a spatial averaging, is the identity matrix, and stands for the tensor product. The average scalar order parameter of the system is defined as the largest eigenvector of . The correlation function is calculated as where is the average over only those LC spin pairs which are separated by the distance .
In cases of SRO or QLRO it holds . In case of LRO it follows . In general, one expects an exponential decay towards a saturated value of on increasing for both LRO and SRO. On the other hand, for QLRO algebraic decay of correlations is expected .
In order to obtain structural details from for a finite system the correlation function is fitted using the empirical ansatz or
where , , , , , and are adjustable parameters. Note that it roughly holds , , and estimates an average linear size of a relatively well-correlated region, referred to as a domain. The ansatz is suitable for structures exhibiting either LRO or SRO. On the other hand, the expression is more appropriate for studying structures possessing QLRO.
4. Simulation Result
We first consider the typical temperature behavior of systems of interest using our modeling. Note that similar studies have already been performed using different approaches. Therefore, we just summarize the main results which are in line with these previous findings. The temperature behavior of the degree of orientational ordering in presence of impurities, upon increasing and decreasing , is shown in Figures 2 and 3, respectively. In Figure 2 the dependence is shown for concentrations , , and . One sees a hysteretic behavior related to the 1st order character of the transition. Therefore, the coupling strength between LC and impurity spins is below the critical value. Note that, due to the local ordering tendency of impurities, the isotropic phase is replaced by a paranematic phase for . In the presented cases the interaction between impurity and LC spins is weak enough so that the phase transition is preserved. In Figures 3(a) and 3(b) we compare the variations for different values of on increasing and decreasing , respectively. With increasing the degree of ordering gradually decreases due to the increasing role of randomness. Simulations reveal that finite-size effects are still evident despite using relatively large samples. This is evidently shown in the plot in Figure 4, where roughly estimates the temperature separating the paranematic and nematic phase on increasing . Impact of on for different interaction strengths is shown in Figure 5. One sees a roughly linear dependence on , where decreases on increasing . Note that simple dilution mechanism predicts a linear dependence as it is demonstrated in Appendix B. Therefore, in the above-shown cases the impact of disorder does not qualitatively change dilution-driven behavior.
We next consider the range of orientational order within samples. For this purpose we start from two significantly different histories of systems. We either initiate the simulations from LC structures homogeneously aligned along a single symmetry-breaking direction or from randomly aligned structures. We henceforth refer to these initial configurations as homogeneous and random histories, respectively. In Figure 6 we plot typical obtained profiles. In the case of short-range order drops to zero for . On the other hand, for QLRO or LRO the correlation function reaches a finite value in the limit .
We first calculate structures originating from the random history. For all the studied cases we obtain SRO. The profiles for and are shown in Figures 7(a) and 7(b), respectively. The size of domains is estimated using the ansatz of Equation (14a), where and is plotted in Figure 8. As expected with increasing value of the size of domains shrinks. Note that with increasing the value of one observes increasingly pronounced dependence. With decreasing the domains appear to be larger due to the increasing importance of elastic forces that tend to establish a spatially homogeneous structure. The observed SRO is in line with the Imry-Ma theorem , claiming that even infinitesimally weak RF-type disorder can destroy the LRO of a pure system reached via a continuous symmetry-breaking transition.
Next we consider structures obtained from the homogeneous histories. In this case, either LRO, QLRO, or SRO is obtained depending on values of and . For low enough values of and one obtains LRO. In this case saturates at a finite value independent of , as shown in Figure 9. On increasing or , quasi-long-range order is formed. In this case dependence becomes pronounced as it is demonstrated in Figure 10. The linear dependence in a log-log diagram reveals a power law dependence. The key features of the established QLRO are obtained by using the ansatz Equation (14b). In the weak coupling limit, LRO is formed with relatively weak variations in . Consequently, is expected. On the other hand, in the strong coupling limit one expects in the thermodynamic limit that , that is, for a finite number . Taking into account , where corresponds to the linear simulation cell size, one expects in the strong interaction limit.
In Figure 11 is plotted as a function of for deep in the nematic phase. In accordance with our expectations we obtain for , whereas roughly approaches towards 3 on increasing above the percolation threshold. The temperature dependence of is analyzed in Figure 12. One sees that increases with increasing . Such a behavior is expected because the thermal fluctuations are increasing, and thus, the same happens with the degree of disorder. From the diagrams we infer that is a nonuniversal quantity, because it exhibits a dependence on and material properties of the systems. For even higher values of coupling SRO is established. This is demonstrated in Figure 13 where is plotted as a function of for different values of . One sees that for and the disorder is strong enough to form SRO.
Our study is motivated by studies in magnetism which have shown that random-field-type disorder might give rise to different orientational structures [24, 25]. Because the main mechanism behind observed is continuous symmetry breaking, similar features are expected to be observed in liquid crystals. For this purpose we carried out systematic study of the impact of the samples history on the degree of orientational ordering in randomly perturbed nematic LCs. The dynamic Lebwohl-Lasher-type lattice model has been used. The systems of interest simulate to good extent the mixtures of LCs and aerosils or mixtures of similar type. In order to demonstrate the possible structural variation range that one could encounter, two limiting histories of samples have been studied: the homogeneous and the random history, respectively. The first one could be realized by temporarily subjecting the LC to a strong enough electric or magnetic field. The other case could be realized via a sudden quench from an isotropic ordering into the orientationally ordered phase. It has been demonstrated that for random histories SRO is expected. On the other hand, for homogeneous histories LRO, QLRO, or even SRO could be realized depending on the values of and . These observations are from qualitative and roughly also from quantitative point in line with known behavior of magnetic systems [24–26].
A. Calculation of Thermal Fluctuations
In order to set the thermal fluctuation vector in (11), one must consider the rotation of the spins in their respective eigen frame denoted by unit vectors . The -axis is aligned along the spin direction. Only the rotations of a spin about the perpendicular local - and -axes are relevant, and it is assumed that both rotations are independent of each other. We imagine the thermal fluctuations as the rotational kinetic free energy contributions with two independent components of angular velocity and . The related rotational kinetic energy reads where and are the corresponding rotation angles and is the appropriate dimensionless tuning parameter. Assuming the canonical distribution we express the probability for a range of angles within the phase-space element as where is the normalization constant. It is convenient to rewrite (A.2) in the two-dimensional polar coordinate system. Taking into account the dimensionless quantities defined in Section 2 it follows where is the magnitude of the vector and the angle defines its direction with respect to . The distribution of is uniform in the interval , while the probability distribution function for in the interval is given by where .
After the thermal rotation of the spin in its own frame, the coordinates of the rotated spin are transformed into the laboratory system . The thermal rotation of the individual spin can be finally written in the laboratory frame using the following vector transformation formula: The elements of the matrix are expressed with the spin components prior to rotations. Two rotations of the coordinate system are performed; the first for the spherical azimuthal angle about the -axis, and the second one for the polar angle about the new -axis. The vector to the right of the matrix is the rotated spin in its own coordinate system.
B. Impact of Impurities on I-N Phase Transition Temperature
We consider a mesomorphic binary mixture of rod-like molecules of comparable size [27, 28]. The concentration of the first component (i.e., LC spins) is given by while the concentration of the second component (i.e., impurities) by . The state of the th component is defined by the orientational distribution function , where the angle determines the orientation of a spin with respect to the symmetry axis. The low temperature orientationally ordered nematic phase is determined by an infinite set of orientational order parameters where are the Legendre polynomials. In the nematic phase the orientational entropy change is given by The dominant role is played by the order parameters and , that is, The anisotropic contribution to the internal energy is taken to be where is the intermolecular orientational interaction between components 1, the orientational interaction between the components 2, while is the orientational interaction between the spins of components 1 and 2, respectively.
The free energy difference between the nematic and isotropic phases can be written as It follows where , , , are positive material constants and describes the contribution of impurities. In the temperature regime where the nematic phase is stable, the temperature dependence of constants , , can be neglected. Furthermore, if the interaction coupling with the impurities is negligible, then the I-N phase transition temperature is given by where determines the I-N phase transition for .
G. Cordoyiannis, Z. Kutnjak, and S. Kralj acknowledge the financial support of the European Office of Aerospace Research and Development Grant FA8655-12-1-2068. G. Cordoyiannis acknowledges the support of the Project PE3-1535 within the Action “Supporting Postdoctoral Researchers” of the Operational Program “Education and Lifelong Learning,” cofinanced by the European Social Fund and the Greek State. A. Ranjkesh acknowledges the support of the Slovenian Research Agency (ARRS) for young researchers.
- A. J. Bray, “Theory of phase-ordering kinetics,” Advances in Physics, vol. 43, pp. 357–459, 1994.
- A. C. Balazs, T. Emrick, and T. P. Russell, “Nanoparticle polymer composites: where two small worlds meet,” Science, vol. 314, no. 5802, pp. 1107–1110, 2006.
- T. W. B. Kibble, “Topology of cosmic domains and strings,” Journal of Physics A, vol. 9, no. 8, pp. 1387–1398, 1976.
- W. H. Zurek, “Cosmological experiments in superfluid helium?” Nature, vol. 317, no. 6037, pp. 505–508, 1985.
- N. D. Mermin, “The topological theory of defects in ordered media,” Reviews of Modern Physics, vol. 51, pp. 591–648, 1979.
- P. C. Hendry, N. S. Lawson, R. Lee, P. V. E. McClintok, and C. D. H. Williams, “Generation of defects in superfluid 4He as an analogue of the formation of cosmic strings,” Nature, vol. 368, pp. 315–317, 1994.
- C. Bauerle, Y. M. Bunkov, S. N. Fisher, H. Godfrin, and G. R. Pickett, “Laboratory simulation of cosmic string formation in the early Universe using superfluid 3He,” Nature, vol. 382, no. 6589, pp. 332–334, 1996.
- S. Kralj, Z. Bradac, and V. Popa-Nita, “The influence of nanoparticles on the phase and structural ordering for nematic liquid crystals,” Journal of Physics: Condensed Matter, vol. 20, no. 24, Article ID 244112, 2008.
- V. J. Anderson, E. M. Terentjev, S. P. Meeker, J. Crain, and W. C. K. Poon, “Cellular solid behaviour of liquid crystal colloids 1. Phase separation and morphology,” European Physical Journal E, vol. 4, no. 1, pp. 11–20, 2001.
- T. Bellini, L. Radzihovsky, J. Toner, and N. A. Clark, “Universality and scaling in the disordering of a smectic liquid crystal,” Science, vol. 294, no. 5544, pp. 1074–1079, 2001.
- G. S. Iannacchione, C. W. Garland, J. T. Mang, and T. P. Rieker, “Calorimetric and small angle x-ray scattering study of phase transitions in octylcyanobiphenyl-aerosil dispersions,” Physical Review E, vol. 58, no. 5, pp. 5966–5981, 1998.
- T. Jin and D. Finotello, “Controlling disorder in liquid crystal aerosil dispersions,” Physical Review E, vol. 69, no. 4, Article ID 041704, 12 pages, 2004.
- T. Bellini, M. Buscaglia, C. Chiccoli, F. Mantegazza, P. Pasini, and C. Zannoni, “Nematics with quenched disorder: what is left when long range order is disrupted?” Physical Review Letters, vol. 85, no. 5, pp. 1008–1011, 2000.
- A. Hourri, T. K. Bose, and J. Thoen, “Effect of silica aerosil dispersions on the dielectric properties of a nematic liquid crystal,” Physical Review E, vol. 63, no. 5, Article ID 051702, 6 pages, 2001.
- P. A. Lebwohl and G. Lasher, “Nematic-liquid-crystal order—a Monte Carlo calculation,” Physical Review A, vol. 6, no. 1, pp. 426–429, 1972.
- P. G. de Gennes and J. Prost, The Physics of Liquid Crystals, Oxford University Press, Oxford, UK, 1993.
- O. D. Lavrentovich, “Topological defects in dispersed words and worlds around liquid crystals, or liquid crystal drops,” Liquid Crystals, vol. 24, no. 1, pp. 117–126, 1998.
- S. Copar and S. Zumer, “Topological and geometric decomposition of nematic textures,” Physical Review E, vol. 85, no. 3, Article ID 031701, 7 pages, 2012.
- P. Poulin, V. Cabuil, and D. A. Weitz, “Direct measurement of colloidal forces in an anisotropic solvent,” Physical Review Letters, vol. 79, no. 24, pp. 4862–4865, 1997.
- P. Poulin and D. A. Weitz, “Inverted and multiple nematic emulsions,” Physical Review E, vol. 57, no. 1, pp. 626–637, 1998.
- D. J. Cleaver, S. Kralj, T. J. Sluckin, and M. P. Allen, Liquid Crystals in Complex Geometries Formed by Polymer and Porous Networks, Oxford University Press, London, UK, 1996.
- V. Popa-Nita and S. Romano, “Nematic-smectic—a phase transition in porous media,” Chemical Physics, vol. 264, no. 1, pp. 91–99, 2001.
- V. Popa-Nita, “Statics and kinetics at the nematic-isotropic interface in porous media,” The European Physical Journal B, vol. 12, pp. 83–90, 1999.
- Y. Imry and S. Ma, “Random-field instability of the ordered state of continuous symmetry,” Physical Review Letters, vol. 35, no. 21, pp. 1399–1401, 1975.
- D. R. Denholm and T. J. Sluckin, “Monte Carlo studies of two-dimensional random-anisotropy magnets,” Physical Review B, vol. 48, no. 2, pp. 901–912, 1993.
- R. Harris, M. Plischke, and M. J. Zuckerman, “New model for amorphous magnetism,” Physical Review Letters, vol. 31, no. 3, pp. 160–162, 1973.
- M. Kleman and O. D. Lavrentovich, Soft Matter Physics, Springer, Berlin, Germany, 2002.
- S. Kralj, Z. Bradac, and V. Popa-Nita, “The influence of nanoparticles on the phase and structural ordering for nematic liquid crystals,” Journal of Physics: Condensed Matter, vol. 20, no. 24, Article ID 244112, 2008.