Vibrational Spectroscopy of Binary Titanium Borides: First-Principles and Experimental Studies

Figure 5

Backscattering Raman spectra of TiB crystal calculated at scattering geometries (a), (b), (c), and (d). Spectra are simulated at 300 K and with laser excitation wavelength of 532 nm. Peaks are represented by Lorentzian functions with artificial FWHMs of 2 cm⁻¹.

(a)

(b)

(c)

(d)