Research Article

In Situ Generated Colloid Transport of Cu and Zn in Reclaimed Mine Soil Profiles Associated with Biosolids Application

Table 3

Total, colloidal, and percent-bound Cu and Zn for eluents from the Virginia and Kentucky treatments*.

VNαVRVSVBKNKRKSKB

Total Cu (mg)0.04 a (<0.01)0.32 a (0.27)0.04 a (0.05)0.93 a (0.72)0.12 b (0.04)0.0 b (na)0.49 b (0.10)3.30 a (0.91)
Dissolved Cu (mg)0.03 a (<0.01)0.05 a (0.05)0.04 a (0.05)0.87 a (0.66)0.02 b (<0.01)0.0 b (na)0.75 b (0.10)3.04 a (0.87)
Colloid Cu (mg)0.01 a (<0.01)0.23 a (0.21)0.01 a (<0.01)0.07 a (0.06)0.10 b (0.03)0.0 c (na)0.0 c (na)0.26 a (0.04)
Bound Cu (%)27.3 b (9.69)82.0 a (1.64)29.9 b (28.37)6.5 b (1.18)80.9 a (3.1)0.0 c (na)0.0 c (na)8.2 b (1.08)
Total Zn (mg)5.13 b (0.46)3.29 b (2.60)6.78 b (3.09)21.53 a (8.53)11.76 a (0.04)2.75 a (1.47)50.73 a (39.2)7.04 a (6.8)
Dissolved Zn (mg)5.09 b (0.45)2.93 b (2.73)6.74 b (3.10)20.75 a (8.30)11.44 a (0.08)2.41 a (1.54)50.73 a (39.2)6.39 a (6.20)
Colloid Zn (mg)0.04 b (<0.01)0.36 b (0.13)0.04 b (0.01)0.78 a (0.22)0.32 a (0.13)0.34 a (0.07)0.0 a (na)0.65 a (0.60)
Bound Zn (%)0.7 a (0.09)18.2 a (18.4)0.5 a (0.37)3.7 a (0.46)2.7 ab (1.05)15.4 a (10.78)0.0 b (na)9.7 ab (0.78)

* = Statistical differences (LSD = 0.05) are represented by letters and are compared within row by sites only, standard deviations are in parenthesis, na = not applicable.
= VN: Virginia Natural, VR: Virginia Reclaimed, VS: Virginia Spoil, VB: Virginia Biosolids, KN: Kentucky Natural, KR: Kentucky Reclaimed, KS: Kentucky Spoil, KB: Kentucky Biosolidsg.