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Advances in Materials Science and Engineering
Volume 2013 (2013), Article ID 356824, 14 pages
Curing Pressure Influence of Out-of-Autoclave Processing on Structural Composites for Commercial Aviation
1Polymeric Composites Laboratory, GloCal/F.R.E.E.D.O.M., 3131 Western Avenue M526, Seattle, WA 98121, USA
2University of Texas at Arlington, 500 West First Street, Arlington, TX 76019, USA
3University of Cyprus, P.O. Box 20537, 1678 Nicosia, Cyprus
Received 6 September 2012; Revised 11 December 2012; Accepted 11 January 2013
Academic Editor: Abbas Milani
Copyright © 2013 Vasileios M. Drakonakis et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Autoclaving is a process that ensures the highest quality of carbon fiber reinforced polymer (CFRP) composite structures used in aviation. During the autoclave process, consolidation of prepreg laminas through simultaneous elevated pressure and temperature results in a uniform high-end material system. This work focuses on analyzing in a fundamental way the applications of pressure and temperature separately during prepreg consolidation. A controlled pressure vessel (press-clave) has been designed that applies pressure during the curing process while the temperature is being applied locally by heat blankets. This vessel gives the ability to design manufacturing processes with different pressures while applying temperature at desired regions of the composite. The pressure role on the curing extent and its effect on the interlayer region are also tested in order to evaluate the consolidation of prepregs to a completely uniform material. Such studies may also be used to provide insight into the morphology of interlayer reinforcement concepts, which are widely used in the featherweight composites. Specimens manufactured by press-clave, which separates pressure from heat, are analytically tested and compared to autoclaved specimens in order to demonstrate the suitability of the press-clave to manufacture high-quality composites with excessively reduced cost.
Autoclaving is among several manufacturing methods for polymeric composites. It is a process mainly utilized in the field of aviation as it guarantees the highest quality for composite structures. The autoclaving process brings the individual prepreg plies together and consolidates them through pressure into a uniform solid material. Elevated temperatures are necessary to initiate and complete the curing reaction for thermoset-based prepregs. This work focuses on an effort to analyze in a fundamental way the applications of pressure and temperature separately during prepreg consolidation. A controlled pressure vessel has been designed that applies pressure during the curing process while the temperature is being applied locally by heat blankets. This vessel gives the ability to design manufacturing processes with different pressures while applying temperature at desired regions of the composite. The role of pressure on the curing extent and its effect on the interlayer region are also tested in order to evaluate the consolidation of prepregs to a completely uniform material. Such studies may also be used to provide insight into the morphology of the interlayer reinforcement concepts such as -direction oriented aligned carbon nanotubes (CNTs) that have shown promise in increasing interlaminar toughness of unidirectional prepregs [1, 2]. Independent variation of temperature and pressure allows these effects to be understood on the CNT alignment and overall penetration into the adjacent bridged plies.
The combination of heat and pressure applied on prepreg plies is necessary in order to consolidate them into a fiber-reinforced polymer composite based on fabricated prepregs. Furthermore, the curing reaction initiation and completion of thermosetting prepreg materials requires elevated temperatures. Several techniques, such as press- or autoclave operations, are available to conduct this manufacturing operation . For manufacturing high-performance polymeric composite materials, autoclaving is the most common technique, mainly due to the versatility and comprehensiveness of this processing type and the large parts production capability with relatively inexpensive tooling . Nevertheless, long tool assembly and processing time make this method a costly, inefficient, and unattractive process for high-volume manufacturing. This is the main reason for utilizing autoclaving in aerospace industrial applications, where the importance of materials outweighs cost. The option of a more affordable technique though with similar quality potential is still very attractive.
Although autoclaving is the manufacturing process used for almost all the polymeric composite parts utilized in aerospace field, in our days, the economic situation requires solutions that will be more affordable than the conventional autoclave processing without sacrificing quality. Efforts are made to manufacture materials of the same quality but with less expensive methods such as vacuum-assisted resin transfer molding (VARTM) [4–7], resin infusion techniques [8, 9], and resin transfer molding (RTM) techniques . The weaknesses of these methods are the inability to control temperature and pressure while curing as well as nonuniformity throughout the structure, which is translated in void formation. Furthermore, these techniques are not able to utilize prepregs apart perhaps from the RTM techniques when the mold is able to heat up (e.g., in a press) [11, 12]. The autoclave, on the other hand, is designed to cure prepregs, and it gives a neat uniform structure with controlled size of voids or no voids at all [3, 12, 13]. The necessity of prepregs in aerospace composite structures is carried in the prepreg nature to be first, pre-wetted with resin without letting voids to be formed, second, responsible for allowing a high-quality composite part, third, of assistance in a much faster manufacturing process compared to the processed mentioned earlier as there is no need for resin handling, and finally, able to control the desired accumulation of resin into the composite part [3, 12, 13]. The latter reasons make it inevitable for the aerospace field to stop utilizing prepregs; as a consequence, the affordability has to focus on the method. A process that will be able to cure prepregs with the same quality as autoclave but in lower cost is in demand.
Such an affordable method is the pressurized vessel or “repair clave,” such as the one manufactured by Heatcon Composite Systems in Seattle, WA, USA. The main characteristic of this clave is the separation of pressure and temperature while curing. Despite its first purpose of being utilized as a repair technique in aviation, this work brings the beginning of a breakthrough to prove that this technique can be used for manufacturing as well, without major differences in the final material product quality. Carbon fiber prepreg panels were manufactured in the clave under different pressures, and they were tested in dynamic mechanical analysis (DMA) and differential scanning calorimetry (DSC) to investigate the pressure effect on the dynamic mechanical properties as well as on the curing quality of the materials. The description of future work needed to further investigate this effort is also mentioned in this paper .
2. Autoclave Processing
High-quality polymeric composites manufacturing requires high-pressure procedures of 70 to 90 psi such as autoclaving, which is used in high tech applications and mainly in aviation. The autoclave is a device that can generate a controlled pressure and temperature environment. While several autoclave types are available, all consist primarily of three units: a pressure vessel, a heating/cooling system, and a control unit. When prepreg-based composites are processed using autoclaves, they undergo several steps prior to the actual autoclaving. These steps usually follow a strict procedure because they have been found to affect the final properties of the composite . Similar to other composite manufacturing techniques, the prepreg materials are stacked or laid-up to yield a laminate of the required dimensions. The entire lay-up including prepreg plies, release film, and breather cloth is then covered with a vacuum bag as shown in Figure 1. Since the pressures in the bag and autoclave are different, a compacting force that corresponds to this pressure difference is exerted on the laminate. Through this feature and the flexible characteristics of the vacuum bag, the pressure is always acting normally to the laminate surface, which leads to a uniform pressure distribution. This uniform pressure distribution, which is applied continuously throughout cure, reduces the risk of void formation, especially when dealing with thermosetting prepreg materials [16–21].
After completion of the vacuum bag, the laminate can be autoclaved using a certain temperature and pressure profile. In composite fabrication, the autoclave is usually pressurized with nitrogen so that fire hazards imposed by the exothermic prepreg materials are reduced . Heat is applied using heat exchangers in conjunction with fans that assist heat transfer [3, 14, 23].
Generally for autoclaves, the usual processing procedure for thermosetting prepreg curing is to firstly increase pressure and right afterwards heating the autoclave at a chosen heating rate to the desired temperature. According to most fluids behaviour, the viscosity of the matrix will decrease with this temperature rise. As a result, at elevated temperature, the resin will freely flow, facilitating the consolidation process until eventually the chemical cross-linking starts occurring and forming gelation. At this point, the resin will soon change from a liquid into a solid, and it will start preventing viscous flow. It is, therefore, important that the chemorheology of the prepreg resins is known in order to complete consolidation and volatile removal prior to resin gelation. A typical autoclave cycle containing two isothermal dwells is shown in Figure 2. The first dwell is performed to prolong the time range for consolidation and eventually to prereact the matrix to reduce the risks of large exotherms. The second dwell is the actual cure step. Most commercial epoxy-based prepreg systems require cure temperatures of 121°C or 178°C. The application of pressure assists the consolidation and helps suppress voids in the laminates.
Nevertheless, high pressures might eventually drive too much resin out of the fiber bed leading again to void formation, resulting from resin starvation this time. Even though much research has focused on the autoclave consolidation and processing optimization, the developed models are of limited use. So, many variables such as prepreg type, part dimensions, vacuum bag materials, lay-up, and processing conditions influence the consolidation that the composites industry has determined almost all operating conditions by trial and error. Consequently, the aerospace industry has tried to employ standardized procedures. For instance, the majority of these parts are cured using 121°C or 178°C standard cure cycles. In addition, one distinguishes between high-, intermediate-, and low-flow prepreg systems. Considering this information, the lay-up can be adjusted such that the optimum part qualities can be accomplished [3, 14, 15, 18, 19, 23].
3. Pressurized Vessel
The repair clave (Figure 3) is a semiportable pressure vessel, designed to provide controlled temperature, vacuum, and pressure for repair of composite and metal-bonded parts that require higher pressures than can be achieved by vacuum only. Unlike a conventional autoclave, there are no internal heating elements in the vessel; so, the heat for curing is derived from heat blankets or other heating elements. This study focuses mainly on the cures that are done with the help of heat blankets.
Although the main difference between a repair clave and an autoclave comes from the fact that one is mainly dedicated to repairs of composite parts while the other for manufacturing, it is believed that a repair clave could become a useful tool in manufacturing simple parts at a much more affordable cost. Currently, autoclaves could be used for repairs also, if extensive rebuild of a part is needed. The repair clave can be referred to as an affordable autoclave, as it reaches almost the same pressures, but it permits the use of localized heat which results in much more economical cures. However, one needs to investigate if the quality of a repaired part can be maintained at the standards of a part manufactured through an autoclave.
There are of course many differences that put the two claves apart, but by understanding these differences, one can see at which common point the repair clave might be used as a possible future autoclave for manufacturing simple composite parts (Table 1).
In order to investigate the role of pressure during manufacturing, when it is applied separately from the temperature, and how it affects the final material, four different plates were manufactured under four different process pressures. The four different pressures were 0, 30, 50, and 70 psi. Each panel had eight plies of woven carbon fiber prepreg (type: Cytec Engineered Materials BMS 8–297, HMF 934 Carbon Prepreg Fiberite 934, resin density 1.3 g/cc). The configuration of the plies is (0, 90, ±45)s. Dimensions of the panels were inches with an approximate thickness of 1 mm. After being manufactured, the panels were cut to appropriate samples for dynamic mechanical analysis and differential scanning calorimetry analyses.
The prepreg plies were stored in a refrigerator at a temperature below 0°F or −17.7°C. They were cut to the desired dimensions and orientation. After that, the lay-up took place. The plies were placed in the desired configuration, and on top of them, all the layers described in Table 2 were applied.
The vacuum has to be at least 22 in Hg 0°C. When the desired vacuum is accomplished, the laid-up panel enters the vessel. The vessel is sealed, and the pressure can be adjusted to the desired level. Since the pressure is at the level required by the experiment, the temperature profile by controlling the heat blanket initiates curing. All the measurement parameters can be controlled by a data acquisition system attached to the vessel. The processing/claving lasts about 4 hours. The first step elevates the temperature up to 177°C with a rate 2.5°C/min, and then it goes through an isothermal period of two hours at 177°C. After two hours in the isothermal phase, the temperature starts reducing with a rate of 2.5°C per min. The pressure is released, and the panel is ready after removing all the lay-up extra layers.
4.1.1. DSC Analysis
The differential scanning calorimeter that was used for these experiments was a 29 series DSC of TA Instruments, model 291°. Three different temperature elevating rates were used, 0.5, 1, and 5°C/min. For all of those three different rates, the samples were elevated up to 400°C. Taking the panels manufactured in the pressurized vessel “repair clave,” small samples of 5 to 20 mg weight were cut for all the four different panels. Hence, eventually, experiments of the 4 different panels manufactured at 0, 30, 50, and 70 psi were tested in 3 different rates, that is, 0.5, 1, and 5°C/min.
4.1.2. Scanning Electron Microscopy (SEM) Characterization
The manufactured samples are also characterized by scanning electron microscopy, through visual examination of surfaces resulting after manufacturing. Samples were cut in dimensions of mm3 so that the cross-section mm2) can be observed in the microscope. Although carbon fibers are conductive, the matrix reduces the conductivity for SEM observation, and for this reason, higher conductivity was achieved through low-vacuum sputter coating with gold. The SEM was a VEGA TESCAN 3SB microscope. Samples are exposed to an electron beam, which comes through a tungsten heated filament electron gun. Finally, the SEM resolution utilized was as high as 3 nm at 30 kV and as low as 8 nm at 3 kV. Particularly, the CFRP samples were tested at 20 kV and 30 kV.
4.1.3. DMA Analysis
The dynamic mechanical analyzer used for this study was a Triton DMA. Two different temperature elevating rates were used, 1 and 5°C/min. For both of these two different rates, the samples were elevated up to 300°C. The samples were tested in 3-point bending experiments. Taking the panels manufactured in the pressurized vessel “repair clave,” samples of approximately mm2 () were cut for all four different panels and were tested in the DMA. The thickness was approximately 1.65 mm for the 0 psi, 1.58 mm for the 30 psi, 1.51 mm for the 50 psi, and 1.47 mm for the 70 psi. Thus, eventually, experiments of the 4 different panels manufactured at 0, 30, 50, and 70 psi were tested in 2 different rates 1 and 5°C/min under 3-point bending loading.
4.1.4. Flexural Mechanical Testing
The specimens were tested in a screw Instron machine (model 4505). More than five specimens were tested for each of the four different CFRP panels of 0, 30, 50, and 70 psi manufactured. Specimens of mm2 were cut from the CFRP panels (the length mentioned is the gauge length). The thickness was approximately 1.65 mm for the 0 psi, 1.58 mm for the 30 psi, 1.51 mm for the 50 psi, and 1.47 mm for the 70 psi. The crosshead of the machine in the three-point bending test had a speed of 5 mm/min, and the test was performed from no loading state to failure. A 5 kN load cell was utilized to perform these experiments.
4.1.5. Compression Testing
Furthermore, specimens from the panels were also tested under compression testing in the same Instron machine that flexural testing took place. Specimens of mm2 were cut from the CFRP panels (the length mentioned is the gauge length). The thickness is again proportional to the psi that the CFRP panel was manufactured. The crosshead of the machine in the compression test had a speed of 1.5 mm/min, and the test was performed from no loading state to failure.
5. Results and Discussion
5.1. Differential Scanning Calorimetry
At first, uncured samples of the prepreg with which the panels were manufactured were tested in DSC. Figure 4 shows the DSC scans for all uncured samples at 0.5, 1, and 5°C/min heating rates. It can be easily noticed that with an increasing heating rate, the area under the peaks, which by integral represents the heat of the exothermic reaction needed for the cure, is increasing as well. Thus, the higher the heating rate, the higher the heat of cure [24–26]. This happens due to the fact that the macromolecules of the polymer need more time to respond to the temperature elevation when the later increases rapidly, due to the curing kinetics of the thermoset. Because of this time lag in the curing response, the material appears to extend and increase the exothermic heat of the polymerization reaction.
Secondly, dynamic scans from 0 to 400°C, at heating rates of 5°C /min, 1°C/min, and 5°C/min, were carried through for all different samples manufactured under the pressures of 0 psi to 70 psi. The sample weight varied from 3 mg to 20 mg, and generally, two samples were collected for each of the pressure cases in each of the heating rates, in order to verify the results.
Graphs are provided to give an indication of the evaluation of the samples in DSC based on the exothermic peak.
In Figure 5, the comparison between the two cases 0 psi and 70 psi can be observed. For the rate of 1°C /min, the 0 psi samples present a slight elevation, which, however, cannot be considered as an exothermic reaction. At the same time, the 70 psi samples at 1°C/min do not show any peaks or elevations at all. By checking the 5°C /min rates, the behavior between the 0 and the 70 psi samples is similar, as although there are small exothermic peaks for both 0 and 70 psi, the integral energy does not significantly vary. As a result, it is considered that the pressure during manufacturing does not really affect the percentage of curing. Specifically, in this case, the rate of heating dominates in affecting the curing percentage.
Figure 6 shows the curves for all the 8 plies samples analyzed at a rate of 5°C/min. As it can be seen, there is no consistent pattern of behavior for all pressure cases, meaning that the curing percentage does not increase or decrease as a function of pressure, but it presents a random behavior. The two exothermic peaks are noticed for 0 psi and 70 psi, the two extreme pressure cases. However, for the cases in between (30 and 50 psi), there are no peaks, which shows that these were better cured than the rest of the samples, or that the rate of heating did not affect the curing under these pressures. Again though, these indications are very random, and there is no conclusion that can be derived for the curing pressure and curing percentage relation. This observation can partly verify the conclusion that was made earlier regarding the pressure nonmonotonic effect on the curing percentage. Furthermore, it has also to be mentioned that the correlation of the DSC experiments of cured samples with the uncured ones gave a percentage of curing between 93% and 99%, not consistently distributed from 0 to 70 psi, which can also be concluded from the DSC graphs and can demonstrate the curing percentage independence from the curing pressure.
5.2. Microstructure Characterization
5.3. Dynamic Mechanical Analysis
It can be seen that there is a slight increase of the modulus while the manufacturing pressure increases, which is expected, as the higher the pressure, the less void formation within the composite. There are other factors such as density change, degree of curing, or glass transition temperature change, which one could think that may be responsible for this modulus increase; nevertheless, the first argument regarding the fewer voids with higher pressure is the most prevailing one as first, the density does not significantly vary with the pressure variation according to thermogravimetric analysis that has been performed  for the same specimens, second, the degree of curing is not affected by pressure as it has been seen through the DSC analysis, and finally, the glass transition temperature change is explained in Figure 12.
It is observed that the glass transition temperature decreases while the pressure increases. The glass transition reduction at 1°C /min heating rate is in the order of around 30°C (°C at 70 psi and °C at 0 psi). This difference expands when the heating rate increases to 5°C/min in the order of around 50°C 80°C at 70 psi and °C at 0 psi).
This can be explained due to internal stresses  that the higher pressure imparts into the composite. Thus, the temperature increase relieves the stresses and the material softens, leading to an apparent decrease of the glass transition temperature. This was verified by annealing the 70 psi manufactured samples at 220°C for an hour and then performing DMA at the 5°C/min heating rate. The value was increased from 180°C to 214°C, which is a value very close to the 0 psi manufactured sample (Figure 12).
Finally, the of different manufacturing pressures at 1 and 5°C/min heating rate is presented ( is the damping ratio, and represents the loss over the storage modulus). The glass transition temperature presents similar behavior as in the storage modulus. Also, the damping from the 0 psi to 70 psi decreases for both heating rates, which correlates with the storage modulus slight increase while the manufacturing pressure increases.
The loss modulus (not shown here) influenced by the elastic energy that is lost to the environment basically decreases as the pressure increases presenting a proportional behavior to . This is also expected as the higher the pressure while manufacturing, the higher alignment of the macromolecule chains within the composite, and as a result, the material softens in lower temperature presenting the loss modulus peak in a lower temperature .
5.4. Mechanical Testing
Two different tests were performed for the CFRP specimens manufactured under 0, 30, 50, and 70 psi. As stated in the experimental description, the first testing was flexural mechanical testing (three-point bending). Figure 14 presents average specimens tested in each of the manufacturing pressures.
Following, in Figure 15, a comparison of the four different panels manufactured under 0, 30, 50, and 70 psi in flexural mechanical testing is presented.
It can be seen that the specimens manufactured under 70 psi have a larger inclination than the specimens manufactured under 0 psi in relation to the strain axis, which is translated to a higher modulus.
The flexural modulus is calculated by (1): where is the flexural modulus (MPa), is the gauge length (mm), is the specimen cross-section width (mm), is the specimen cross-section height (mm), is the load (N), and is the the deflection due to load (mm).
By calculating the flexural modulus with type 2 applied for the elastic region of the stress-strain curve, the values of the flexural modulus are similar to the ones calculated by (1) as where and are two random stress values on the stress-strain elastic region ( > ), and and are two random strain values on the stress-strain elastic region ( > ).
Equation (2) actually gives the direction coefficient of the stress-strain curve elastic region, which is the respective modulus.
Regarding the compression testing that was performed, Figure 16 presents the stress-strain curves of average specimens tested in each of the manufacturing pressures.
Following, in Figure 17, a comparison of the four different panels manufactured under 0, 30, 50, and 70 psi in compression mechanical testing is presented.
It can be seen that there are no large differences in the inclination of the stress-strain curves at the elastic region. This means that the modulus of CFRPs manufactured under different pressures does not present significant changes in compression loads from low to higher pressures while manufacturing. The compression modulus is derived from (2), applied for the elastic region of the compression testing stress-strain curve.
The moduli and strength behaviour can also be seen in Table 3, where the average flexural and compression moduli and strengths for each of the CFRP panels are presented. Also, Table 3 illustrates mechanical testing results of specimens manufactured through conventional autoclave compared with those manufactured through the Press Clave. It can be seen that the high-pressure—70 psi—specimens present mechanical properties very similar to the autoclaved ones.
The results presented in Table 3 are statistically significant as well as the differences between the values of the specimens manufactured at 0, 30, 50, and 70 psi. Linear regression analysis was performed for the experimental results. A level of significance at 0.15 was used to compare the results. It turned out that in all cases, the value of the regression analysis was below the 0.15 significance level, and as a result, the mechanical properties comparison shows statistically significant values and differences as a function of pressure. Taking the intervals of each group of experiments average through a double-sided -test with a 0.15 level of significance, we are 85% confident that the values of the mechanical properties will lie within the range that is presented in Table 3 for each combination of property and pressure.
The analysis made throughout this section of innovative manufacturing with DSC, DMA, flexural and compression, and SEM characterizations gives the picture of the quality of composites manufactured through the press clave. DSC testing assures that composites are properly cured; DMA examines the viscoelastic behaviour of composites; flexural testing exhibits the stiffness improvement analogously with the higher manufacturing pressure; SEM gives information on the surface quality of the samples manufactured under different pressures. Furthermore, compression tests show that both modulus and strength under compression do not vary, and as a result, they are not affected by the different manufacturing pressure. Consequently, the well-cured specimens under the press-clave, the acceptable surface that they present in SEM characterization, and most importantly the slight differences in flexural strength and modulus under high-pressure manufacturing demonstrate that the press clave can be utilized as a decent alternative manufacturing process of the extremely expensive autoclave. Of course, this high-quality manufacturing through the press clave is achieved by the use of heat blankets, which are necessary for achieving the appropriate curing temperature profile while manufacturing and the thermal uniformity within the part while curing. The latter is very accurate in conventional autoclaves as it is very important for high-quality CFRP parts. Thus, the heat blanket is a mandatory tool in press clave manufacturing for accurate thermal uniformity within the part that is manufactured. Nevertheless, besides the obvious financial and other benefits from the utilization of heat blankets, their limitation compared to the heating system of an autoclave is the three-dimensional and the complex geometry manufacturing of composite parts.
The DSC results were not conclusive with respect to expected percentages of curing. It could not be concluded that the percentage of cure would be higher with a higher pressure, and also it was noticed that the differences from one pressure to another were quite small. These small differences could appear also because of the way the lay-up is done or the way the vacuum was maintained through the curing process. It is also possible that the differences are so small because of the small number of plies subjected to the experiments. An increased number of plies and an increased number of experiments could offer more definitive answers with respect to the influence of pressure on the manufacturing process of composite parts. In the future, it is planned to further investigate the press clave manufacturing technique and specifically test several specimens in DSC that have been manufactured with increased number of plies and more experiments to investigate the percentage of curing in several levels of the composite thickness, which will be demanded since the number of plies is increased.
Furthermore, the dynamic mechanical analysis DMA gives the expected results regarding the storage modulus reaction with the manufacturing pressure increase. The higher the manufacturing pressure the higher the modulus. However, there is a significant decrease in glass transition temperature as the manufacturing pressure, increases. This happens due to internal stresses formed in the materials when pressure is higher. Then, these internal stresses are relieved during heating and soften the material, resulting in a reduced .
Additionally, scanning electron microscopy observation was performed for samples from all pressures. The results verified the storage modulus increase, as the higher the pressure, the less void formation. Finally, as far as the mechanical testing is concerned, the specimens under flexural testing exhibited a significant increase of both the flexural modulus and strength as the manufacturing pressure increases. On the other hand, the compression testing showed that the compression modulus is not dependent on the manufacturing pressure, and thus, besides a slight increase from 0 to 70 psi which is considered negligible, it presents relatively similar values for all the specimens. Similar behavior of manufacturing pressure independence is presented by the compression strength as well. The mechanical comparison with autoclaved samples exhibits the press clave potential as a curing alternative of the highly costly autoclave.
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