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Advances in Materials Science and Engineering
Volume 2013 (2013), Article ID 360935, 6 pages
A Nonlocal Model for Carbon Nanotubes under Axial Loads
Department of Structures for Engineering and Architecture, University of Naples Federico II, Via Claudio 21, 80125 Naples, Italy
Received 7 July 2013; Revised 8 October 2013; Accepted 10 October 2013
Academic Editor: Jun Liu
Copyright © 2013 Raffaele Barretta and Francesco Marotti de Sciarra. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Various beam theories are formulated in literature using the nonlocal differential constitutive relation proposed by Eringen. A new variational framework is derived in the present paper by following a consistent thermodynamic approach based on a nonlocal constitutive law of gradient-type. Contrary to the results obtained by Eringen, the new model exhibits the nonlocality effect also for constant axial load distributions. The treatment can be adopted to get new benchmarks for numerical analyses.
Carbon nanotubes (CNTs) are a topic of major interest both from theoretical and applicative points of view. This subject is widely investigated in literature to describe small-scale effects [1–4], vibration and buckling [5–13], and nonlocal finite element analysis [14–18]. A comprehensive review on applications of nonlocal elastic models for CNTs is reported in  and therein references. Buckling of triple-walled CNTs under temperature fields is dealt with in . An alternative methodology is based on an atomistic-based approach  which predicts the positions of atoms in terms of interactive forces and boundary conditions. The standard approach to analyze CNTs under axial loads consists in solving an inhomogeneous second-order ordinary differential equation providing the axial displacement field, see, for example, . The known term of the differential equation is the sum of two contributions. The former describes the local effects linearly depending on the axial load. The latter characterizes the small-scale effects depending linearly on the second derivative along the rod axis of the axial load. This model is thus not able to evaluate small-scale effects due to, constant axial loads per unit length. This approach, commonly adopted in literature, is based on the following nonlocal linearly elastic constitutive law proposed by Eringen : where is a material constant, is the internal length, is the Young modulus, is the normal stress, the apex is second derivative along the rod axis, and is the axial elongation. Indeed, integrating on the rod cross section domain and imposing that the axial force is equal to the resultant of normal stress field we get the differential equation where , with being first derivative along the rod axis of the axial displacement field , where is the rod length and denotes the cross section area. Since the equilibrium prescribes that the first derivative of is opposite to the axial load , we infer the well-known differential equation (see, e.g., ) as follows: Note that the nonlocal contribution vanishes for constant loads . In the present paper, an alternative nonlocal constitutive behavior is adopted to assess small-scale effects in nanotubes also for constant axial loads. The corresponding axial displacement field is shown to be governed by a fourth-order inhomogeneous differential equation. Boundary conditions are naturally inferred by performing a standard localization procedure of a variational problem formulated by making recourse to thermodynamic restrictions see, for example, [24–26], according to the geometric approach illustrated in [27–30]. As an example, the displacement field of nanotubes under constant axial loads per unit length is evaluated in the appendix. Vibration and buckling effects are not the subject of this paper and will be addressed in a forthcoming paper.
2. Nonlocal Variational Formulation
Let be the three-dimensional spatial domain of a straight rod subjected to axial loads. An apex stands for th derivative along the rod centroidal -axis. Kinematic compatibility between axial elongations and axial displacements is expressed by the differential equation . Denoting by a dot the time-rate, the following noteworthy relations hold true The differential equation of equilibrium turns out to be . Boundary equilibrium prescribes that at the end cross sections act axial loads equal to for and to for . Let us now consider a nonlocal constitutive model of gradient-type defined by assigning the following elastic energy functional per unit volume: with being nonlocal parameter. Relation (5) is similar to the elastic energy density proposed in  where a homogeneous quadratic functional including also mixed terms is assumed. The elastic energy time rate is hence expressed by the formula where are the static variables conjugating with the kinematic variables and . The static variable is the scalar counterpart of the so-called double stress tensor . By imposing the thermodynamic condition (see, e.g., [32–34]) where is the normal stress, we infer the relation The relevant differential and boundary equations are thus obtained as shown hereafter. Substituting the expression of the rates and in terms of the axial displacement of the cross section at abscissa , we get the formulae with axial force (static equivalence condition on the cross sections) and for . Thermodynamic condition (9) provides the axial contribution
3. Differential and Boundary Equations of Elastic Equilibrium
Resorting to Green’s formula, a standard localization procedure provides the differential and boundary equations corresponding to the variational conditions inferred in Section 2, as follows. A direct computation gives
Substituting into the variational condition (11), a suitable localization provides the relevant differential equation and boundary conditions
These conditions can be conveniently expressed in terms of the axial displacement field as follows. A direct evaluation of the scalar functions for and of their derivatives gives with . Accordingly, the boundary and differential conditions of elastic equilibrium (13) and (14) take the form
Let us consider a straight rod subject to a constant axial load as depicted in Figure 1. End cross sections and are assumed to be hinged and simply supported, respectively. As illustrated in Section 3, the computation of the rod axial displacement field involves the following cross section geometric and elastic properties: area , Young modulus , and nonlocal parameter . By setting and , the differential equation of elastic equilibrium is as follows: The general integral takes thus the form (see the appendix) with The evaluation of the constants is carried out by imposing the following boundary conditions (see also Section 3): Resorting to the expressions of the derivatives and for , and having , a direct computation provides the algebraic system A further condition can be obtained by imposing that the scalar field is a particular solution of the differential equation (17), whence it follows that . The remaining constants are given by the formulae having . A plot of the rod axial displacement field for different values of the nonlocal parameter is provided in Figure 2. It is apparent that the rod becomes stiffer if the nonlocal parameter increases. The evaluated axial displacement at the free end of the rod provides the same value independently of the nonlocal parameter. Such a value coincides with the displacement of the point if a local model is considered. Moreover, the limit of the axial displacement field for tending to plus infinity can be evaluated to get the lower bound Hence, large values of the nonlocal parameter provide a displacement field which tends to a linear one, see Figure 2, for . Further, the limit value of the axial displacement for and , obtained by (25), yields nm which coincides with the axial displacement at for any value of the nonlocal parameter , see Figure 3 and Table 1.
The upper bound of the axial displacement is provided by the local solution (i.e., ) The axial displacement evaluated for by (26) yields the value nm which coincides with the axial displacement at for any value of , see Figure 3 and Table 1. For the considered model, the upper and lower bounds of the axial displacement field are given by (25) and (26). The axial displacement at the middle point of the rod and the maximum axial displacement as functions of the nonlocal parameter are depicted in Figure 3. The corresponding numerical values of and are listed in Table 1.
It is worth noting that equilibrium prescribes that axial force must be a linear function, confirmed by the blue diagram in Figure 4 obtained as difference between the local contribution (dashed line) and the nonlocal one (continuous thin line), according to (14)1 for any value of .
The outcomes of the present paper may be summarized as follows. (i) Linearly elastic carbon nanotubes under axial loads have been investigated by a nonlocal variational approach based on thermodynamic restrictions. The treatment provides an effective tool to evaluate small-scale effects in nanotubes subject also to constant axial loads, a goal not achievable by the Eringen model commonly adopted in literature as motivated in Section 1. (ii)Relevant boundary and differential conditions of elastic equilibrium have been inferred by a standard localization procedure. Such a procedure provides, in a consistent way, the relevant class of boundary conditions for the nonlocal model. (iii)The present approach yields a firm thermodynamic procedure to derive different nonlocal models for CNTs by suitable specializations of the elastic energy. (iv)Exact solutions of carbon nanotubes subject to a constant axial load have been obtained. An advantage of the proposed procedure consists in providing an effective tool to be used as a benchmark for numerical analyses. Finally, a range to which any nonlocal solution must belong is analytically evaluated.
The procedure to solve the ordinary differential equation with , being constant coefficients and being a continuous function, is summarized as follows. Let us consider the homogeneous differential equation and the relevant characteristic (algebraic) equation . The roots of the polynomial are with multiplicity 2, with multiplicity 1 and with multiplicity 1. The general integral of (A.2) is thus expressed by the formula with denoting exponential function and for . The general integral of (A.1) is writen therefore as where is a particular solution of (A.1). It is worth noting that, for defined by a polynomial of degree , the solution can be looked for by setting with for .
The authors were supported by the “Polo delle Scienze e delle Tecnologie,” University of Naples Federico II, through the research project FARO. Useful hints and precious comments by anonymous reviewers are also gratefully acknowledged.
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