Kinetics of Free Radical Polymerization of N-Substituted Amides and Their Structural Implications

Table 3

Dimensional characteristics of poly(NAM) and poly(NMNVA).

(a) Poly(NAM)

Code	IP	C (%)	(DP)
6; (anisole)	3.8	99.0	28 165; (200)	42 327	1.50
7; (1,4 dioxane)	4.8	90.6	12 279; (87)	58 065	4.73
8; (toluene)	2.4	71.0	31 709; (225)	126 879	4.00
9; (THF)	4.0	79.0	3 633; (26)	11 349	3.12

(b) Poly(NMNVA)

Code	IP	C (%)	(DP)
10; (methanol)	5.2	64.2	—		—
11; (1,4 dioxane)	4.8	75.9	5 587; (56)	23 947	4.28
12; (THF)	4.0	73.4	4 387; (44)	20 894	4.76
13; (toluene)	2.4	53.3	17 729; (179)	63 748	3.40
14; (diphenyl ether)	2.2		—		—
			—		—

In the brackets the estimated value from the elemental analysis.
Liquid phase.  Solid phase.
IP is polarity index; C is conversion;     (DP) is number average molecular weight degree of polymerization;   is molecular weight;   is dispersity index.