Review Article

Contact and Distant Luminescence Quenching in Solutions

Figure 20

The dependence on diffusion of the effective electron transfer radius, . (a) The experimental data, indicated by circles, is approximated by a thin line representing the contact Smoluchowski-Collins-Kimball approach and by thick line depicting the same dependence, but for the exponential transfer rate from (119) with and . (b) The same but in a wider diffusion diapason. The dashed-dotted line at the bottom represents the high viscosity asymptote of the same dependence but for the Marcus transfer rate. (From [79]).
214219.fig.020a
(a)
214219.fig.020b
(b)