Contact and Distant Luminescence Quenching in Solutions

Figure 5

The time effective rate “constants” for the forward and reverse transfer, 𝑘_𝑓(𝑡)=𝑘^eff_𝑓/𝑘_𝑎 (solid lines) and 𝑘_𝑟(𝑡)=𝑘^eff_𝑟/𝑘_𝑎 (dashed lines), calculated with IET (a) and MET (b) at 𝜏_𝐵=∞, equal concentrations of 𝐴 and 𝐵 and equal kinetic constants 𝑘^eff_𝑓(0)=𝑘^eff_𝑟(0)=𝑘_𝑎=10𝑘_𝐷. The thin solid line shows the stationary value of 𝑘^eff_𝑟(∞) [44].

(a)

(b)