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Advances in Physical Chemistry
Volume 2009 (2009), Article ID 365949, 4 pages
http://dx.doi.org/10.1155/2009/365949
Research Article

Structure of Copper(II) Complexes with 2-[2-Hydroxy-Phenil]-4,4-Diphenyl-1,2-Dihydro-4H-3,1-Benzoxazine in Chloroform

1Kuban State University, Russian Federation, 149, Stavropolskay Street, 350040 Krasnodar, Russia
2Chechen State University, Russian Federation, 33, Kievskay Street, 364051 Grozny, Russia

Received 27 May 2009; Accepted 19 August 2009

Academic Editor: Alaa Abd-El-Aziz

Copyright © 2009 S. N. Bolotin et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Electronic spectra of copper(II) complexes C u L 2 and C u 2 L 2 A c 2 (L-2-[2-hydroxy-phenil]-4,4-diphenyl-1,2-dihydro-4H-3,1-benzoxazine, Ac – C H 3 C O O ) (L) in chloroform are studied. It is shown that complex C u l 2 has rhombic bipyramid polyhedron and complex C u 2 L 2 A c 2 has tetragonal pyramidal polyhedron of copper ion. Results of definition of geometry for complexes in solution correlate with structure of solid complexes.