Structure of Copper(II) Complexes with 2-[2-Hydroxy-Phenil]-4,4-Diphenyl-1,2-Dihydro-4H-3,1-Benzoxazine in Chloroform

<table class="table-group" id="tab2"><tr><td><table class="table"><tr><td class="thead-hr" colspan="4"><hr/></td></tr><tr><td align="left">Complex:</td><td align="center" colspan="2">CuL<sub>2</sub></td><td align="center">Cu<sub>2</sub>L<sub>2</sub>Ac<sub>2</sub></td></tr><tr><td align="left">Variant:</td><td align="center">(1)</td><td align="center">(2)</td><td align="center">(2) </td></tr><tr><td align="center" colspan="4"><hr/></td></tr><tr><td align="left"><span style="width: 31.875px;"><svg height="13.8375" id="M29" style="vertical-align:-4.90039pt" version="1.1" viewbox="0 0 31.875 13.8375" width="31.875" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,7.675)"><path d="M391 364q0 -28 -20.5 -53.5t-50 -43.5t-70 -34t-73.5 -25t-68 -17v-29q0 -48 20 -81t65 -33q73 0 157 76l16 -23q-107 -113 -221 -113q-21 0 -40.5 6.5t-39 22t-31.5 47t-12 75.5q0 69 33.5 139.5t95.5 114.5q77 55 143 55q42 0 69 -24.5t27 -59.5zM313 350
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<g transform="matrix(.012,-0,0,-.012,7.1,11.762)"><path d="M548 455q-32 -77 -74 -77q-37 0 -103 10l-3 -2q36 -30 48.5 -62t12.5 -80q0 -103 -75 -179.5t-175 -76.5q-70 0 -113 45t-43 128q0 115 83.5 200.5t209.5 85.5q31 0 77.5 -4t67.5 -4q36 0 62 30zM350 274q0 54 -17 86q-19 35 -57 35q-50 0 -90 -37.5t-59 -91.5t-19 -109
q0 -61 24.5 -96.5t65.5 -35.5q51 0 87.5 46.5t50.5 100.5t14 102z" id="x1D70E"></path></g><g transform="matrix(.012,-0,0,-.012,13.823,11.762)"><path d="M300 -147l-18 -23q-106 71 -159 185.5t-53 254.5v1q0 139 53 252.5t159 186.5l18 -24q-74 -62 -115.5 -173.5t-41.5 -242.5q0 -130 41.5 -242.5t115.5 -174.5z" id="x28"></path></g><g transform="matrix(.012,-0,0,-.012,17.94,11.762)"><path d="M745 361q0 -166 -116 -272t-291 -106q-136 0 -225.5 83t-89.5 218q0 161 115.5 272t288.5 111q137 0 227.5 -83t90.5 -223zM643 359q0 126 -56 199.5t-167 73.5q-130 0 -213.5 -104t-83.5 -246q0 -117 58 -190.5t165 -73.5q91 0 160.5 52t103 128.5t33.5 160.5z" id="x1D442"></path></g><g transform="matrix(.012,-0,0,-.012,27.078,11.762)"><path d="M275 270q0 -296 -211 -440l-19 23q75 62 116.5 174t41.5 243t-42 243t-116 173l19 24q211 -144 211 -440z" id="x29"></path></g>
</svg></span></td><td align="center">7100</td><td align="center">7100</td><td align="center">7100</td></tr><tr><td align="left"><span style="width: 33.137501px;"><svg height="13.8375" id="M30" style="vertical-align:-4.90039pt" version="1.1" viewbox="0 0 33.137501 13.8375" width="33.137501" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
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q0 26 -14.5 40.5t-37.5 14.5q-32 0 -44 -7q-82 -46 -104 -175q200 49 200 127z" id="x1D452"></path></g>
<g transform="matrix(.012,-0,0,-.012,7.1,11.762)"><path d="M548 455q-32 -77 -74 -77q-37 0 -103 10l-3 -2q36 -30 48.5 -62t12.5 -80q0 -103 -75 -179.5t-175 -76.5q-70 0 -113 45t-43 128q0 115 83.5 200.5t209.5 85.5q31 0 77.5 -4t67.5 -4q36 0 62 30zM350 274q0 54 -17 86q-19 35 -57 35q-50 0 -90 -37.5t-59 -91.5t-19 -109
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</svg></span></td><td align="center">6220</td><td align="center">7963</td><td align="center">8322</td></tr><tr><td align="left"><span style="width: 39.075001px;"><svg height="14.925" id="M31" style="vertical-align:-5.76988pt" version="1.1" viewbox="0 0 39.075001 14.925" width="39.075001" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,7.675)"><path d="M391 364q0 -28 -20.5 -53.5t-50 -43.5t-70 -34t-73.5 -25t-68 -17v-29q0 -48 20 -81t65 -33q73 0 157 76l16 -23q-107 -113 -221 -113q-21 0 -40.5 6.5t-39 22t-31.5 47t-12 75.5q0 69 33.5 139.5t95.5 114.5q77 55 143 55q42 0 69 -24.5t27 -59.5zM313 350
q0 26 -14.5 40.5t-37.5 14.5q-32 0 -44 -7q-82 -46 -104 -175q200 49 200 127z" id="x1D452"></path></g>
<g transform="matrix(.012,-0,0,-.012,7.1,11.762)"><path d="M574 449q-23 -58 -38 -79q-16 -4 -79 -4q-27 -100 -46 -219q-14 -87 7 -87t74 36l13 -27q-74 -81 -139 -81q-48 0 -48 62q0 22 8 59l60 258l-154 4q-21 -103 -54.5 -209t-64.5 -151q-38 -23 -83 -23l-7 15q46 36 94 152.5t64 216.5q-81 0 -138 -54l-18 23q22 27 39.5 43
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</svg></span></td><td align="center">1062.5</td><td align="center">2370</td><td align="center">3011</td></tr><tr><td align="left"><span style="width: 40.337502px;"><svg height="14.925" id="M32" style="vertical-align:-5.76988pt" version="1.1" viewbox="0 0 40.337502 14.925" width="40.337502" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,7.675)"><path d="M391 364q0 -28 -20.5 -53.5t-50 -43.5t-70 -34t-73.5 -25t-68 -17v-29q0 -48 20 -81t65 -33q73 0 157 76l16 -23q-107 -113 -221 -113q-21 0 -40.5 6.5t-39 22t-31.5 47t-12 75.5q0 69 33.5 139.5t95.5 114.5q77 55 143 55q42 0 69 -24.5t27 -59.5zM313 350
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<g transform="matrix(.012,-0,0,-.012,7.1,11.762)"><path d="M574 449q-23 -58 -38 -79q-16 -4 -79 -4q-27 -100 -46 -219q-14 -87 7 -87t74 36l13 -27q-74 -81 -139 -81q-48 0 -48 62q0 22 8 59l60 258l-154 4q-21 -103 -54.5 -209t-64.5 -151q-38 -23 -83 -23l-7 15q46 36 94 152.5t64 216.5q-81 0 -138 -54l-18 23q22 27 39.5 43
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</svg></span></td><td align="center">1946.5</td><td align="center">3254</td><td align="center">2050</td></tr><tr><td align="left"><span style="width: 96.349998px;"><svg height="14.5625" id="M33" style="vertical-align:-4.90039pt" version="1.1" viewbox="0 0 96.349998 14.5625" width="96.349998" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
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<g transform="matrix(.017,-0,0,-.017,42.562,8.387)"><path d="M535 230h-212v-233h-58v233h-213v50h213v210h58v-210h212v-50z" id="x2B"></path></g><g transform="matrix(.017,-0,0,-.017,56.297,8.387)"><path d="M391 364q0 -28 -20.5 -53.5t-50 -43.5t-70 -34t-73.5 -25t-68 -17v-29q0 -48 20 -81t65 -33q73 0 157 76l16 -23q-107 -113 -221 -113q-21 0 -40.5 6.5t-39 22t-31.5 47t-12 75.5q0 69 33.5 139.5t95.5 114.5q77 55 143 55q42 0 69 -24.5t27 -59.5zM313 350
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</svg></span></td><td align="center">2458.5</td><td align="center">4637</td><td align="center">4543</td></tr><tr class="table-tr"><td colspan="4"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

Parameters AOM (cm<sup>-1</sup>) calculated on electronic spectra.

Advances in Physical Chemistry

tab2

Table 2

Table 2: Structure of Copper(II) Complexes with 2-[2-Hydroxy-Phenil]-4,4-Diphenyl-1,2-Dihydro-4H-3,1-Benzoxazine in Chloroform 