Table 9:
Experimental correlation times and predicted rotational diffusion constants for the different carbons at various temperatures for
C
7
0
in o-dichlorobenzene-
d
4
.
Carbon 1
Carbon 2
Carbon 3
Carbon 4
T
𝜏
e
ff
𝐶
𝜏
e
ff
𝐶
𝜏
e
ff
𝐶
𝜏
e
ff
𝐶
𝐷
𝑋
×
1
0
−
1
0
𝐷
𝑍
×
1
0
−
1
0
(K)
(ps)
(ps)
(ps)
(ps)
(1/s)
(1/s)
283
26.1
15.9
15.9
17.9
0.6
1.9
293
13.5
13.8
13.7
14.2
1.2
1.2
303
10.3
11.3
10.5
11.7
1.5
1.5
313
8.9
7.6
8.0
8.5
1.9
2.3
323
7.8
6.5
6.2
6.2
2.1
3.6