Research Article

Suppression of Intramolecular Vibrational Energy Redistribution by Intense CW-Laser Fields

Figure 4

Population dynamics of SCCl2 molecule with changing coupling parameter Ω . Corresponding laser power is as follows: (a) 0.0 W/cm2, (b) 2 . 4 8 × 1 0 9  W/cm2, (c) 9 . 9 1 × 1 0 9 W/cm2, (d) 3 . 9 6 × 1 0 1 0 W/cm2, (e) 8 . 9 2 × 1 0 1 0  W/cm2. The hatched area denoted by IVR corresponds to the population distributed over background manifolds | 𝐵 𝑗 . The white area in (a) denotes the population of | 𝑚 , whereas the area painted by black background with horizontal lines in (b) corresponds to the population of | . Note that the population of | 𝑚 and | is so little and hardly seen in Figures 4(c) and 4(e).
584082.fig.004a
(a) Ω = 0  cm 1
584082.fig.004b
(b) Ω = 5 0 c m 1
584082.fig.004c
(c) Ω = 1 0 0 c m 1
584082.fig.004d
(d) Ω = 2 0 0 c m 1
584082.fig.004e
(e) Ω = 3 0 0 c m 1