Effect of Hetero Atom on the Hammett’s Reaction Constant (<svg style="vertical-align:-3.69pt;width:13.4625px;" id="M1" height="15.075" version="1.1" viewBox="0 0 13.4625 15.075" width="13.4625" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns="http://www.w3.org/2000/svg"><g transform="matrix(.022,0,0,-.022,.062,10.413)"><path id="x1D746" d="M58 -110l62 267q23 98 66 167t96 103q53 35 115 35q67 0 116 -45t49 -135q0 -118 -86 -207q-86 -87 -188 -87q-55 0 -87 19l-25 -110q-16 -72 -28 -102h-115q10 25 25 95zM252 240l-33 -152q1 -29 20 -44.5t48 -15.5q56 0 108 82q53 83 53 171q0 131 -76 131
q-39 0 -72 -50q-33 -49 -48 -122z" /></g></svg>) from the Physical Basis of Dissociation Equilibriums of (Dithio) Benzoic Acids and (Thio) Phenols and Its Application to Solvolysis Reactions and Some Free Radical Reactions

Advances in Physical Chemistry

sch2

Scheme 2

Scheme 2: Effect of Hetero Atom on the Hammett’s Reaction Constant (<svg style="vertical-align:-3.69pt;width:13.4625px;" id="M1" height="15.075" version="1.1" viewBox="0 0 13.4625 15.075" width="13.4625" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns="http://www.w3.org/2000/svg"><g transform="matrix(.022,0,0,-.022,.062,10.413)"><path id="x1D746" d="M58 -110l62 267q23 98 66 167t96 103q53 35 115 35q67 0 116 -45t49 -135q0 -118 -86 -207q-86 -87 -188 -87q-55 0 -87 19l-25 -110q-16 -72 -28 -102h-115q10 25 25 95zM252 240l-33 -152q1 -29 20 -44.5t48 -15.5q56 0 108 82q53 83 53 171q0 131 -76 131
q-39 0 -72 -50q-33 -49 -48 -122z" /></g></svg>) from the Physical Basis of Dissociation Equilibriums of (Dithio) Benzoic Acids and (Thio) Phenols and Its Application to Solvolysis Reactions and Some Free Radical Reactions 

Scheme 2 | Effect of Hetero Atom on the Hammett’s Reaction Constant () from the Physical Basis of Dissociation Equilibriums of (Dithio) Benzoic Acids and (Thio) Phenols and Its Application to Solvolysis Reactions and Some Free Radical Reactions 