Review Article

Potential Energy Surfaces for Reactions of X Metal Atoms (X = Cu, Zn, Cd, Ga, Al, Au, or Hg) with YH4 Molecules (Y = C, Si, or Ge) and Transition Probabilities at Avoided Crossings in Some Cases

Figure 3

Insertion mechanism of the three lowest states of the Cu atom (2S, 2P, and 2D) into a C–H bond of methane. 2A′ interaction energy states as a function of the angle theta. The 4p1 character follows the path from the second excited state to the minimum in the X A′ state, where the final products are formed.
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