About this Journal Submit a Manuscript Table of Contents
Advances in Physical Chemistry
Volume 2014 (2014), Article ID 659531, 9 pages
http://dx.doi.org/10.1155/2014/659531
Research Article

Dielectric Relaxation Studies of 2-Butoxyethanol with Aniline and Substituted Anilines Using Time Domain Reflectometry

1Dr.Nallini Institute of Engineering and Technology, Dharapuram, Tamil Nadu 638673, India
2Department of Physics, Annamalai University, Annamalai Nagar, Tamil Nadu 608002, India
3School of Physics, S.R.T.M. University, Nanded, Maharashtra 431606, India

Received 19 June 2013; Revised 17 October 2013; Accepted 25 October 2013; Published 18 February 2014

Academic Editor: Jyh-Ping Hsu

Copyright © 2014 P. Jeevanandham et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. D. Balamurugan, S. Kumar, and S. Krishnan, “Dielectric relaxation studies of higher order alcohol complexes with amines using time domain reflectometry,” Journal of Molecular Liquids, vol. 122, no. 1–3, pp. 11–14, 2005. View at Publisher · View at Google Scholar · View at Scopus
  2. P. Sivagurunathan, K. Dharmalingam, K. Ramachandran, B. Prabhakar Undre, P. W. Khirade, and S. C. Mehrotra, “Dielectric relaxation study of ethyl acrylate-alcohol mixtures using time domain Reflectometry,” Lithanian Journal of Physics, vol. 46, no. 4, pp. 441–445, 2006. View at Publisher · View at Google Scholar
  3. Y. S. Joshi and A. C. Kumbharkhane, “Study of heterogeneous interaction in binary mixtures of 2-methoxyethanol-water using dielectric relaxation spectroscopy,” Journal of Molecular Liquids, vol. 161, no. 3, pp. 120–124, 2011. View at Publisher · View at Google Scholar · View at Scopus
  4. V. A. Rana, A. D. Vyas, and S. C. Mehrotra, “Dielectric relaxation study of mixtures of 1-propanol with aniline, 2-chloroaniline and 3-chloroaniline at different temperatures using time domain reflectometry,” Journal of Molecular Liquids, vol. 102, no. 1–3, pp. 379–391, 2003. View at Publisher · View at Google Scholar · View at Scopus
  5. T. V. Krishna and S. S. Sastry, “Dielectric and thermodynamic studies on the hydrogen bonded binary system of isopropyl alcohol and aniline,” Journal of Solution Chemistry, vol. 39, no. 9, pp. 1377–1393, 2010. View at Publisher · View at Google Scholar · View at Scopus
  6. T. Kalaivani and S. Krishnan, “Dielectric relaxation studies of ternary liquid mixtures of aniline and substituted anilines with acrylonitrile in the microwave region,” Indian Journal of Pure and Applied Physics, vol. 47, no. 12, pp. 880–882, 2009. View at Scopus
  7. R. J. Sengwa, V. Khatri, and S. Sankhla, “Dielectric properties and hydrogen bonding interaction behaviour in binary mixtures of glycerol with amides and amines,” Fluid Phase Equilibria, vol. 266, no. 1-2, pp. 54–58, 2008. View at Publisher · View at Google Scholar · View at Scopus
  8. A. N. Prajapati, V. A. Rana, and A. D. Vyas, “Dielectric dispersion studies of mixtures of aniline and benzonitrile in benzene solutions,” Journal of Molecular Liquids, vol. 144, no. 1-2, pp. 1–4, 2009. View at Publisher · View at Google Scholar · View at Scopus
  9. K. K. Gupta, A. K. Bansal, P. J. Singh, and K. S. Sharma, “Structural change analysis of pyridine and piperidine through dielectric relaxation studies,” Journal of Molecular Liquids, vol. 108, no. 1–3, pp. 79–93, 2003. View at Publisher · View at Google Scholar · View at Scopus
  10. U. Becker and M. Stockhausen, “A dielectric relaxation study of some mixtures of mono and dihydric alcohols,” Journal of Molecular Liquids, vol. 81, no. 2, pp. 89–100, 1999. View at Scopus
  11. A. C. Kumbharkhane, S. M. Puranik, and S. C. Mehrotra, “Dielectric relaxation study and structural properties of 2-nitroacetophenone-ethanol solutions from 10 MHz to 10 GHz,” Journal of Molecular Liquids, vol. 51, no. 3-4, pp. 307–319, 1992. View at Scopus
  12. S. M. Puranik, A. C. Kumbharkhane, and S. C. Mehrotra, “Dielectric relaxation studies of aqueous N,N-dimethylformamide using a picosecond time domain technique,” Journal of Solution Chemistry, vol. 22, no. 3, pp. 219–229, 1993. View at Publisher · View at Google Scholar · View at Scopus
  13. Y. S. Joshi, P. G. Hudge, A. C. Kumbharkhane, and S. C. Mehrotra, “The dielectric relaxation study of 2(2-alkoxyethoxy)ethanol-water mixtures using time domain reflectometry,” Journal of Molecular Liquids, vol. 163, no. 2, pp. 70–76, 2011. View at Publisher · View at Google Scholar · View at Scopus
  14. P. R. Bevington, Data Reduction and Error Analysis for the Physical Sciences, McGraw Hill, New York, NY, USA, 1969.
  15. A. Chaudhari, N. M. More, and S. C. Mehrotra, “Static dielectric constant and relaxation time for the binary mixture of water, ethanol, N,N-dimethylformamide, dimethylsulphoxide, and N,N-dimethylacetamide with 2-methoxyethanol,” Bulletin of the Korean Chemical Society, vol. 22, no. 4, pp. 357–361, 2001. View at Scopus
  16. A. C. Kumbharkhane, S. N. Helambe, S. Doraiswamy, and S. C. Mehrotra, “Dielectric relaxation study of hexamethylphosphoramide-water mixtures using time domain reflectometry,” The Journal of Chemical Physics, vol. 99, no. 4, pp. 2405–2409, 1993. View at Scopus
  17. B. D. Achole, A. V. Patil, V. P. Pawar, and S. C. Mehrotra, “Study of interaction through dielectrics: behavior of -OH group molecules from 10 MHz to 20 GHz,” Journal of Molecular Liquids, vol. 159, no. 2, pp. 152–156, 2011. View at Publisher · View at Google Scholar · View at Scopus
  18. L. S. Gabrielyan and S. A. Markarian, “Dielectric relaxation study of dipropylsulfoxide/water mixtures,” Journal of Molecular Liquids, vol. 162, no. 3, pp. 135–140, 2011. View at Publisher · View at Google Scholar · View at Scopus
  19. Y. S. Joshi, P. G. Hudge, and A. C. Kumbharkhane, “Dielectric relaxation study of aqueous 2-ethoxyethanol using time domain reflectometry technique,” Indian Journal of Physics, vol. 85, no. 11, pp. 1603–1614, 2011. View at Scopus
  20. K. K. Srivastava and J. K. Vij, “Dielectric relaxation and molecular structure. I. Dielectric relaxation in substituted anilines,” Bulletin of Chemical Society of Japan, vol. 43, pp. 2307–2312, 1970. View at Publisher · View at Google Scholar
  21. J. G. Kirkwood, “The dielectric polarization of polar liquids,” The Journal of Chemical Physics, vol. 7, no. 10, pp. 911–919, 1939. View at Scopus
  22. S. B. Sayyad, P. B. Undre, P. Yannewar, S. S. Patil, P. W. Khirade, and S. C. Mehrotra, “Investigations of intermolecular interactions between 2-methoxyethanol and nitrobenzene through dielectric relaxation study,” Lithuanian Journal of Physics, vol. 51, no. 1, pp. 29–37, 2011. View at Publisher · View at Google Scholar · View at Scopus
  23. D. A. G. Bruggeman, “The dielectric constant of a composite material,” Annals of Physics, vol. 5, p. 636, 1935.
  24. J. B. Hasted, Aqueous Dielectrics, Champan and Hall, London, UK, 1973.
  25. V. P. Pawar and S. C. Mehrotra, “Dielectric relaxation study of chlorobenzene with formamide at microwave frequency using time domain reflectometry,” Journal of Molecular Liquids, vol. 115, no. 1, pp. 17–22, 2004. View at Publisher · View at Google Scholar · View at Scopus
  26. P. Undre, S. N. Helambe, S. B. Jagdale, P. W. Khirade, and S. C. Mehrotra, “Microwave dielectric characterization of binary mixture of formamide with N, N-dimethylaminoethanol,” Pramana, vol. 68, no. 5, pp. 851–861, 2007. View at Publisher · View at Google Scholar · View at Scopus
  27. D. A. G. Bruggeman, “The dielectric constant of a composite material-a problem in classical physics,” Annals of Physics, vol. 24, p. 636, 1967.
  28. A. Chaudhari, S. Ahire, M. Lokhande, and S. C. Mehrotra, “Dielectric study of pyridine- alcohol binary liquids at 25°C,” Proceedings of the National Academy of Sciences India Section A, vol. 1, pp. 75–83, 2001.
  29. A. Chaudhari, C. S. Patil, A. G. Shankarwar, B. R. Arbad, and S. C. Mehrotra, “Temperature dependent dielectric relaxation study of aniline in dimethylsulphoxide and dimethylformamide using time domain technique,” Journal of Korean Chemical Society, vol. 45, pp. 201–206, 2001.
  30. S. C. Mehrotra and J. E. Boggs, “A new approach to time-dependent perturbation theory,” The Journal of Chemical Physics, vol. 64, no. 7, pp. 2796–2803, 1976. View at Scopus
  31. T. V. Krishna and T. MadhuMohan, “Study of molecular interactions in the polar binary mixtures of N-methyl aniline and alcohols, using excess dielectric and thermodynamic parameters,” Journal of Chemical Thermodynamics, vol. 47, pp. 267–275, 2012. View at Publisher · View at Google Scholar · View at Scopus
  32. T. M. Mohan, S. S. Sastry, and V. R. K. Murthy, “Thermodynamic, dielectric and conformational studies on hydrogen bonded binary mixtures of propan-1-ol with methyl benzoate and ethyl benzoate,” Journal of Solution Chemistry, vol. 40, no. 1, pp. 131–146, 2011. View at Publisher · View at Google Scholar · View at Scopus
  33. T. Thenappan and U. Sankar, “Study of correlation factors and dipolar excess free energies of esters in benzene,” Journal of Molecular Liquids, vol. 126, no. 1–3, pp. 23–28, 2006. View at Publisher · View at Google Scholar · View at Scopus
  34. G. Arivazhagan, G. Parthipan, and T. Thenappan, “Solute-solvent interactions of acid-1,4-dioxane mixtures-By dielectric, FTIR, UV-vis and 13C NMR spectrometric methods,” Spectrochimica Acta A, vol. 74, no. 4, pp. 860–868, 2009. View at Publisher · View at Google Scholar · View at Scopus
  35. G. Parthipan and T. Thenappan, “Dielectric and thermodynamic behavior of binary mixture of anisole with morpholine and aniline at different temperatures,” Journal of Molecular Liquids, vol. 138, no. 1–3, pp. 20–25, 2008. View at Publisher · View at Google Scholar · View at Scopus
  36. B. B. Swain and G. S. Roy, “Dielectric studies of binary mixtures of butanols in nonpolar solvents-solute-solvent interactions,” Journal of Molecular Liquids, vol. 34, no. 4, pp. 257–268, 1987. View at Scopus
  37. O. Redlich and A. T. Kister, “Algebraic representation of thermodynamic properties and the classification of solutions,” Industrial and Engineering Chemistry, vol. 40, no. 2, pp. 345–348, 1948. View at Publisher · View at Google Scholar