Bioinorganic Chemistry and Applications
Volume 2008 (2008), Article ID 647873, 8 pages
doi:10.1155/2008/647873
Research Article

The First Metal Complexes of 4,6-diamino-1-hydro- 5-hydroxy-pyrimidine-2-thione: Preparation, Physical and Spectroscopic Studies, and Preliminary Antimicrobial Properties

Sahar I. Mostafa,1 Constantina Papatriantafyllopoulou,2 Spyros P. Perlepes,2 and Nick Hadjiliadis3

1Chemistry Department, Faculty of Science, Mansoura University, 35516 Mansoura, Egypt
2Department of Chemistry, University of Patras, 265 04 Patras, Greece
3Laboratory of Inorganic and General Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, Greece

Received 2 June 2008; Revised 10 October 2008; Accepted 14 December 2008

Academic Editor: Ian Butler

Copyright © 2008 Sahar I. Mostafa et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. S. K. Hadjikakou, M. A. Demertzis, M. Kubicki, and D. Kovala-Demertzi, “Organotin adducts with pyrimidinethione: crystal structure of dimethyldi(pyrimidine-2-thiolato)tin(IV) and diphenyldi(pyrimidine-2-thiolato)tin(IV),” Applied Organometallic Chemistry, vol. 14, no. 11, pp. 727–734, 2000. View at Publisher · View at Google Scholar
  2. C.-L. Ma, Y. Shi, Q.-F. Zhang, and Q. Jiang, “Syntheses, characterization and crystal structures of diorganotin compounds with 2-mercaptopyrimidine and 4-amino-2-mercaptopyrimidine,” Polyhedron, vol. 24, no. 10, pp. 1109–1116, 2005. View at Publisher · View at Google Scholar
  3. M. A. Romero-Molina, M. D. Gutierrez-Valero, R. Lopez-Garzon, J. M. Salas-Peregrin, M. I. Arriortua, and F. J. Zuñiga, “Studies on pyrimidine derivative complexes: spectroscopy, thermal behaviour and crystal structure of μ-dichloro-μ-sulphur-chloro(4,6-diamino-1,2-dihydro-2-thiopyrimidine-N3, S2)cadmium(II) monohydrate,” Inorganica Chimica Acta, vol. 136, no. 2, pp. 87–92, 1987. View at Publisher · View at Google Scholar
  4. E. Barea, J. A. R. Navarro, J. M. Salas, N. Masciocchi, S. Galli, and A. Sironi, “[Cu(4-oxopyrimidinate)2⋅nH2O]∞: a robust sodalite type metal-organic framework exhibiting a rich host-guest chemistry,” Polyhedron, vol. 22, no. 22, pp. 3051–3057, 2003. View at Publisher · View at Google Scholar
  5. N. Masciocchi, S. Galli, A. Sironi, et al., “Rich structural and magnetic chemistry of cobalt(II) pyrimidin-2-olate and pyrimidin-4-olate complexes. Synthesis, X-ray powder diffraction studies, and thermal behavior,” Chemistry of Materials, vol. 15, no. 11, pp. 2153–2160, 2003. View at Publisher · View at Google Scholar
  6. Z. Qin, M. C. Jennings, and R. J. Puddephatt, “Molecular triangle of palladium(II) and its anion binding properties,” Inorganic Chemistry, vol. 41, no. 15, pp. 3967–3974, 2002. View at Publisher · View at Google Scholar
  7. S. I. Mostafa, M. A. Kabil, E. M. Saad, and A. A. El-Asmy, “Ligational and analytical applications of a uracil derivative toward some transition metal ions,” Journal of Coordination Chemistry, vol. 59, no. 3, pp. 279–293, 2006. View at Publisher · View at Google Scholar
  8. N. P. Johnson, C. J. L. Lock, and G. Wilkinson, “Amine, phosphine, arsine, and stibine complexes of rhenium-(III), -(IV), and -(V),” Journal of the Chemical Society, pp. 1054–1066, 1964. View at Publisher · View at Google Scholar
  9. F. A. Cotton, G. Wilkinson, C. A. Murillo, and M. Bochmann, Advanced Inorganic Chemistry, John Wiley & Sons, New York, NY, USA, 6th edition, 1999.
  10. W. J. Geary, “The use of conductivity measurements in organic solvents for the characterisation of coordination compounds,” Coordination Chemistry Reviews, vol. 7, no. 1, pp. 81–122, 1971. View at Publisher · View at Google Scholar
  11. F. W. Moore and R. E. Rice, “Physicochemical and spectral properties of octahedral dioxomolybdenum(VI) complexes,” Inorganic Chemistry, vol. 7, no. 12, pp. 2510–2514, 1968. View at Publisher · View at Google Scholar
  12. A. B. P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, The Netherlands, 2nd edition, 1984.
  13. N. Lalioti, C. P. Raptopoulou, A. Terzis, A. Panagiotopoulos, S. P. Perlepes, and E. Manessi-Zoupa, “New metal-binding modes for 5-aminoorotic acid: preparation, characterization and crystal structures of zinc(II) complexes,” Journal of the Chemical Society, Dalton Transactions, no. 8, pp. 1327–1334, 1998. View at Publisher · View at Google Scholar
  14. S. P. Perlepes, V. Lazaridou, B. Sankhla, and J. M. Tsangaris, “Synthesis, physical properties and spectroscopic studies of isoorotato, 5-aminoorotato and 2-thioorotato lanthanide(III) complexes,” Bulletin de la Société Chimique de France, vol. 127, pp. 597–608, 1990.
  15. J. Romero, M. L. Durán, A. Rodriguez, et al., “Electrochemical synthesis and characterization of indium pyrimidine-2-thiolate complexes. Molecular structure of tris (pyrimidine-2-thiolato) indium (III) and tris [(5-ethyl-4,6-dimethyl)pyrimidine-2-thiolato]indium(III),” Inorganica Chimica Acta, vol. 274, no. 2, pp. 131–136, 1998. View at Publisher · View at Google Scholar
  16. A. K. Boudalis, V. Nastopoulos, S. P. Perlepes, C. P. Raptopoulou, and A. Terzis, “Reactions of 2,2′-bipyridine (bpy) and 1,10-phenanthroline (phen) with yttrium(III) nitrate: preparation, X-ray crystal structures and spectroscopic characterization of the bis-bpy and bis-phen complexes,” Transition Metal Chemistry, vol. 26, no. 3, pp. 276–281, 2001. View at Publisher · View at Google Scholar
  17. A. G. de A. Fernandes, P. I. da S. Maia, E. J. de Souza, et al., “Rhenium chelate complexes with maltolate or kojate,” Polyhedron, vol. 27, no. 13, pp. 2983–2989, 2008. View at Publisher · View at Google Scholar
  18. E. López-Torres and M. A. Mendiola, “Complexes of a triazine-3-thione ligand with divalent metals: crystal structure of [CdL2DMF]2⋅2DMF⋅1/4H2O,” Polyhedron, vol. 24, no. 12, pp. 1435–1444, 2005. View at Publisher · View at Google Scholar
  19. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley & Sons, New York, NY, USA, 4th edition, 1986.
  20. Z.-H. Zhou, H.-L. Wan, and K.-R. Tsai, “Syntheses and spectroscopic and structural characterization of molybdenum(VI) citrato monomeric raceme and dimer, K4[MoO3(cit)]⋅2H2O and K4[(MoO2)2O(Hcit)2]⋅4H2O,” Inorganic Chemistry, vol. 39, no. 1, pp. 59–64, 2000. View at Publisher · View at Google Scholar
  21. H. Arzoumanian, G. Agrifoglio, M. V. Capparelli, R. Atencio, A. Briceño, and A. Alvarez-Larena, “Synthesis and characterization of thiocyanato and chlorodioxo tungsten(VI) compounds: comparative oxygen atom transfer capability with molybdenum analogs,” Inorganica Chimica Acta, vol. 359, no. 1, pp. 81–89, 2006. View at Publisher · View at Google Scholar
  22. C. H. Collins and P. M. Lyne, Microbiological Methods, University Park Press, Baltimore, Md, USA, 1970.
  23. R. P. John, A. Sreekanth, V. Rajakannan, T. A. Ajith, and M. R. P. Kurup, “New copper(II) complexes of 2-hydroxyacetophenone N(4)-substituted thiosemicarbazones and polypyridyl co-ligands: structural, electrochemical and antimicrobial studies,” Polyhedron, vol. 23, no. 16, pp. 2549–2559, 2004. View at Publisher · View at Google Scholar