Pt(II) and Pd(II) Complexes with 𝜷-Alanine

Table 3

Selected stereochemical data for the studied compounds.

	Trans-[Pd(-Ala)2]	Trans-[Pt(-Ala)2]	Cis-[Pt(-Ala)2]	K2[Pt(-Ala)2I2𝛽2H2O
Pt–O	2.004(2) 2.004(2)	1.997(5) 1.996(6)	1.994(7) 2.033(7)	—
			2.019(7) 2.014(8)
Pt–N	2.026(2) 2.026(2)	2.031(7) 2.026(8)	1.979(9) 2.015(8)	2.047(5)
			1.986(9) 2.009(7)
Pt–Hal	—	—	—	2.5902(5)
K–I	—	—	—	3.797(1)
				4.285(2)
K–O	—	—	—	2.780(4) 2.820(5)
				2.808(5) 2.863(5)
				2.851(4)
𝛽 NPtO	94.35(8)	94.0(3)	95.1(3) 95.0(3)	—
			96.1(3) 94.9(3)
C–O	1.291(3) 1.232(2)	1.290(11) 1.235(11)	1.291(15) 1.188(15)	1.249(7) 1.255(7)
			1.308(13) 1.186(14)
		1.281(10) 1.221(11)	1.259(14) 1.252(14)
			1.317(13) 1.219(14)
C–N	1.463(3)	1.486(11) 1.461(14)	1.525(15) 1.461(15)
			1.539(14) 1.468(14)