Bioinorganic Chemistry and Applications / 2010 / Article / Tab 5 / Research Article
Antineoplastic Activity of New Transition Metal Complexes of 6-Methylpyridine-2-carbaldehyde-N(4)-ethylthiosemicarbazone: X-Ray Crystal Structures of [VO 2 (mpETSC)] and [Pt(mpETSC)Cl] Table 5 Selected bond lengths and bond angles for [VO2 (mpETSC)].
bond lengths (Å) Bond angles (°) V(1 )–O(1 ) 1.6145(12) O(2)–V(1 )–S(8) 96.73(5) V(1 )–O(2) 1.6356(12) N(1 )–V(1 )–S(8) 151.43(4) V(1 )–N(1 ) 2.1333(14) N(7)–V(1 )–S(8) 76.48(4) V(1 )–N(7) 2.1651(13) C(8)–S(8)–V(1 ) 100.39(6) V(1 )–S(8) 2.3800(5) C(2)–N(1 )–C(6) 118.72(14) S(8)–C(8) 1.7472(17) C(2)–N(1 )–V(1 ) 125.52(11) N(1 )–C(2) 1.351(2) C(6)–N(1 )–V(1 ) 115.75(11) N(1 )–C(6) 1.361(2) C(7)–N(7)–N(8) 116.94(13) N(7)–C(7) 1.287(2) C(7)–N(7)–V(1 ) 116.04(10) N(7)–N(8) 1.3708(17) N(8)–N(7)–V(1 ) 127.01(10) N(8)–C(8) 1.322(2) C(8)–N(8)–N(7) 111.43(13) N(9)–C(8) 1.339(2) C(8)–N(9)–C(9) 124.07(16) N(9)–C(9) 1.454(2) N(1 )–C(2)–C(3) 120.41(16) C(1 )–C(2) 1.494(2) N(1 )–C(2)–C(1 ) 119.13(15) C(2)–C(3) 1.398(2) C(3)–C(2)–C(1 ) 120.45(15) C(3)–C(4) 1.379(3) C(4)–C(3)–C(2) 120.71(15) C(4)–C(5) 1.390(2) C(3)–C(4)–C(5) 118.81(16) C(5)–C(6) 1.385(2) C(6)–C(5)–C(4) 118.35(16) C(6)–C(7) 1.451(2) N(1 )–C(6)–C(5) 122.94(16) C(9)–C(10) 1.509(3) N(1 )–C(6)–C(7) 115.08(14) C(5)–C(6)–C(7) 121.98(15) N(7)–C(7)–C(6) 117.71(14) N(8)–C(8)–N(9) 118.62(15) N(8)–C(8)–S(8) 124.50(12) N(9)–C(8)–S(8) 116.87(13) N(9)–C(9)–C(10) 112.49(17) O(1 )–V(1 )–O(2) 107.64(7) O(1 )–V(1 )–N(1 ) 96.08(6) O(2)–V(1 )–N(1 ) 101.30(6) O(1 )–V(1 )–N(7) 113.29(6) O(2)–V(1 )–N(7) 139.07(6) N(1 )–V(1 )–N(7) 75.37(5) O(1 )–V(1 )–S(8) 99.35(5)