Antineoplastic Activity of New Transition Metal Complexes of 6-Methylpyridine-2-carbaldehyde-N(4)-ethylthiosemicarbazone: X-Ray Crystal Structures of [VO2(mpETSC)] and [Pt(mpETSC)Cl]

Table 5

Selected bond lengths and bond angles for [VO₂(mpETSC)].

bond lengths (Å)		Bond angles (°)
V($1$)–O($1$)	1.6145(12)	O(2)–V($1$)–S(8)	96.73(5)
V($1$)–O(2)	1.6356(12)	N($1$)–V($1$)–S(8)	151.43(4)
V($1$)–N($1$)	2.1333(14)	N(7)–V($1$)–S(8)	76.48(4)
V($1$)–N(7)	2.1651(13)	C(8)–S(8)–V($1$)	100.39(6)
V($1$)–S(8)	2.3800(5)	C(2)–N($1$)–C(6)	118.72(14)
S(8)–C(8)	1.7472(17)	C(2)–N($1$)–V($1$)	125.52(11)
N($1$)–C(2)	1.351(2)	C(6)–N($1$)–V($1$)	115.75(11)
N($1$)–C(6)	1.361(2)	C(7)–N(7)–N(8)	116.94(13)
N(7)–C(7)	1.287(2)	C(7)–N(7)–V($1$)	116.04(10)
N(7)–N(8)	1.3708(17)	N(8)–N(7)–V($1$)	127.01(10)
N(8)–C(8)	1.322(2)	C(8)–N(8)–N(7)	111.43(13)
N(9)–C(8)	1.339(2)	C(8)–N(9)–C(9)	124.07(16)
N(9)–C(9)	1.454(2)	N($1$)–C(2)–C(3)	120.41(16)
C($1$)–C(2)	1.494(2)	N($1$)–C(2)–C($1$)	119.13(15)
C(2)–C(3)	1.398(2)	C(3)–C(2)–C($1$)	120.45(15)
C(3)–C(4)	1.379(3)	C(4)–C(3)–C(2)	120.71(15)
C(4)–C(5)	1.390(2)	C(3)–C(4)–C(5)	118.81(16)
C(5)–C(6)	1.385(2)	C(6)–C(5)–C(4)	118.35(16)
C(6)–C(7)	1.451(2)	N($1$)–C(6)–C(5)	122.94(16)
C(9)–C(10)	1.509(3)	N($1$)–C(6)–C(7)	115.08(14)
		C(5)–C(6)–C(7)	121.98(15)
		N(7)–C(7)–C(6)	117.71(14)
		N(8)–C(8)–N(9)	118.62(15)
		N(8)–C(8)–S(8)	124.50(12)
		N(9)–C(8)–S(8)	116.87(13)
		N(9)–C(9)–C(10)	112.49(17)
		O($1$)–V($1$)–O(2)	107.64(7)
		O($1$)–V($1$)–N($1$)	96.08(6)
		O(2)–V($1$)–N($1$)	101.30(6)
		O($1$)–V($1$)–N(7)	113.29(6)
		O(2)–V($1$)–N(7)	139.07(6)
		N($1$)–V($1$)–N(7)	75.37(5)
		O($1$)–V($1$)–S(8)	99.35(5)