Antineoplastic Activity of New Transition Metal Complexes of 6-Methylpyridine-2-carbaldehyde-N(4)-ethylthiosemicarbazone: X-Ray Crystal Structures of [VO2(mpETSC)] and [Pt(mpETSC)Cl]

Table 7

Selected bond lengths and bond angles for the [Pt(mpETSC)Cl] complex.

bond lengths (Å)		Bond angles (°)
Pt($1$)–N(7)	1.979(5)	C(8)–S($1$)–Pt1	95.02(11)
Pt($1$)–N($1$)	2.116(3)	C(2)–N($1$)–C(6)	118.6(3)
Pt($1$)–S($1$)	2.2533(8)	C(2)–N($1$)–Pt1	132.4(2)
Pt($1$)–Cl($1$)	2.3178(15)	C(6)–N($1$)–Pt1	109.0(2)
S($1$)–C(8)	1.757(3)	C(7)–N(7)–N(8)	121.8(5)
N($1$)–C(2)	1.350(4)	C(7)–N(7)–Pt1	116.1(4)
N($1$)–C(6)	1.370(5)	N(8)–N(7)–Pt1	121.9(3)
N(7)–C(7)	1.287(8)	C(8)–N(8)–N(7)	113.4(4)
N(7)–N(8)	1.365(6)	C(8)–N(9)–C(9)	127.1(3)
N(8)–C(8)	1.333(5)	N($1$)–C(2)–C(3)	120.3(3)
N(9)–C(8)	1.331(4)	N($1$)–C(2)–C($1$)	119.7(3)
N(9)–C(9)	1.449(4)	C(3)–C(2)–C($1$)	120.0(3)
C($1$)–C(2)	1.494(4)	C(4)–C(3)–C(2)	121.1(3)
C(2)–C(3)	1.400(5)	C(3)–C(4)–C(5)	118.4(3)
C(3)–C(4)	1.370(5)	C(6)–C(5)–C(4)	119.1(3)
C(4)–C(5)	1.389(5)	N($1$)–C(6)–C(5)	122.3(3)
C(5)–C(6)	1.381(5)	N($1$)–C(6)–C(7)	116.5(4)
C(6)–C(7)	1.426(8)	C(5)–C(6)–C(7)	121.2(4)
C(9)–C(10)	1.491(5)	N(7)–C(7)–C(6)	117.7(6)
		N(9)–C(8)–N(8)	116.8(3)
		N(9)–C(8)–S($1$)	118.8(3)
		N(8)–C(8)–S($1$)	124.4(3)
		N(9)–C(9)–C(10)	113.1(3)
		N(7)–Pt1–N($1$)	80.15(16)
		N(7)–Pt1–S($1$)	85.25(14)
		N($1$)–Pt1–S($1$)	165.40(8)
		N(7)–Pt1–Cl1	174.13(12)
		N($1$)–Pt1–Cl1	105.02(8)
		S($1$)–Pt1–Cl1	89.57(4)