Use of the 2-Pyridinealdoxime/N,N′-Donor Ligand Combination in Cobalt(III) Chemistry: Synthesis and Characterization of Two Cationic Mononuclear Cobalt(III) Complexes

Table 2

Selected bond distances (Å) and angles (°) for complexes 1 ⋅2H₂O and 2 ⋅1.5MeOH,^a with the estimated standard deviations in parentheses.

	1 ⋅2H2O	2 ⋅1.5MeOH
Bond distances
Co–N(1)	1.928(4)	1.937(3)
Co–N(2)	1.904(4)	1.909(4)
Co–N(3)	1.986(4)	1.977(4)
Co–N(1^′)	1.928(4)	1.937(3)
Co–N(2^′)	1.904(4)	1.909(4)
Co–N(3^′)	1.986(4)	1.977(4)
N(2)–O/O(1)	1.294(6)	1.273(5)
N(3)–C(7)	1.322(7)	1.343(6)
N(1)–C(1)	1.343(7)	1.340(6)
N(2)–C(6)	1.298(7)	1.309(7)
Bond angles
N(3)–Co–N(3′)	82.7(2)	82.2(2)
N(1)–Co–N(3)	88.6(2)	93.6(2)
N(1)–Co–N(2)	83.7(2)	83.7(2)
N(2)–Co–N(2^′)	89.9(3)	89.8(2)
N(1)–Co–N(3^′)	96.1(2)	90.7(2)
Co–N(2)–O/O(1)	122.7(4)	123.3(3)

aUnprimed and primed atoms are related by symmetry.