Research Article
Zinc(II) and Nickel(II) Benzoate Complexes from the Use of 1-methyl-4,5-diphenylimidazole
Table 2
Selected interatomic distances (Å), angles and torsion angles (
) for
1·2MeOH and
2·2MeCN.
| | Compound | 1·2MeOH | 2·2MeCN |
| | M | Zn | Ni | | M | | 2.734 | | M–N3A | 2.007 | 2.017(2) | | M–N3B | 2.065 | | | M–O1 | 1.947 | 2.015(2) | | M–O3 | 1.950 | 2.039(2) | | M–O2 | | 2.008(2) | | M–O4 | | 2.026(2) |
| | N3A–M–N3B | 96.6 | | | N3A–M–O1 | 123.4 | 91.9 | | N3A–M–O2 | | 103.3 | | N3A–M–O3 | 123.9 | 98.2 | | N3A–M–O4 | | 96.7 | | N3B–M–O1 | 103.0 | | | N3B–M–O3 | 97.2 | | | O1–M–O3 | 105.7(4) | 88.0 | | O1–M–O4 | | 89.9 | | O2–M–O3 | | 90.7 | | O2–M–O4 | | 87.4 | | C19–M–C26 | 112.46(4) | |
| | A2–A3* | 70.5 | 61.9 | | B2–B3* | 67.0 | | | C4A–C5A–C13A–C14A | −57.8(2) | −53.0(4) | | C4B–C5B–C13B–C14B | −56.8(2) | | | C5A–C4A–C7A–C12A | −46.6(2) | −40.5(4) | | C5B–C4B–C7B–C12B | −37.3(2) | |
|
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between the mean-planes of the named phenyl rings (see Figure 1).
Symmetry codes: (i) ,
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