B3LYP Study on Reduction Mechanisms from <svg style="vertical-align:-4.50008pt;width:24.775px;" id="M1" height="20.887501" version="1.1" viewBox="0 0 24.775 20.887501" width="24.775"  xmlns="http://www.w3.org/2000/svg">
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			<text transform="matrix(1,0,0,-1,-52.23,59.83)">
				<tspan style="font-size: 17.93px; " x="0" y="0">O</tspan>
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</svg> at the Catalytic Sites of Fully Reduced and Mixed-Valence Bovine Cytochrome <svg style="vertical-align:-0.198pt;width:10.55px;"  height="10.2625" version="1.1" viewBox="0 0 10.55 10.2625" width="10.55"  xmlns="http://www.w3.org/2000/svg">
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</svg> Oxidases

<table>Two reaction pathways to produce FeOOH (<b>10</b>) from FeOO (<b>2</b>).</table>

Bioinorganic Chemistry and Applications

sch2

Scheme 2

Scheme 2: B3LYP Study on Reduction Mechanisms from <svg style="vertical-align:-4.50008pt;width:24.775px;" id="M1" height="20.887501" version="1.1" viewBox="0 0 24.775 20.887501" width="24.775"  xmlns="http://www.w3.org/2000/svg">
	<g transform="matrix(1.25,0,0,-1.25,0,20.8875)">
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	<g transform="matrix(1.25,0,0,-1.25,0,20.8875)">
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				<tspan style="font-size: 17.93px; " x="0" y="0">O</tspan>
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</svg> at the Catalytic Sites of Fully Reduced and Mixed-Valence Bovine Cytochrome <svg style="vertical-align:-0.198pt;width:10.55px;"  height="10.2625" version="1.1" viewBox="0 0 10.55 10.2625" width="10.55"  xmlns="http://www.w3.org/2000/svg">
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</svg> Oxidases 

Scheme 2 | B3LYP Study on Reduction Mechanisms from 
	
		
			
				O
			

			
				2
			

		
	
 to 
	
		
			
				H
			

			
				2
			

			
				O
			

		
	
 at the Catalytic Sites of Fully Reduced and Mixed-Valence Bovine Cytochrome 
	
		
			
				𝑐
			

		
	
 Oxidases 

Bioinorganic Chemistry and Applications

B3LYP Study on Reduction Mechanisms from O 2 to H 2 O at the Catalytic Sites of Fully Reduced and Mixed-Valence Bovine Cytochrome 𝑐 Oxidases

Scheme 2

B3LYP Study on Reduction Mechanisms from to at the Catalytic Sites of Fully Reduced and Mixed-Valence Bovine Cytochrome Oxidases