Structural Properties, Cytotoxicity, and Anti-Inflammatory Activity of Silver(I) Complexes with tris(p-tolyl)Phosphine and 5-Chloro-2-Mercaptobenzothiazole

Table 1

Selected bond lengths (́Å) and angles (deg) for compounds 1–3 with e.s.d.’s in parentheses in comparison with those found in [10, 30].

1 at 293(2)  K		2 at 120 K		[AgCl(TPTP)3]		3 at 120 K		[AgI(TPTP)3] (polymorph of 3)		[AgI(TPTP)3] (polymorph of 3)
				at 293 K [10]				at 140 K [10]		at 293 K [10]
Bond Distances (Å)		Bond Distances (Å)		Bond Distances (Å)		Bond Distances (Å)		Bond Distances (Å)		Bond Distances (Å)
Ag1–P1	2.4357(18)	Ag1–P1	2.5159(13)	Ag1–P1	2.5566(12)	Ag1–P1	2.511(2)	Ag1–P1	2.5208(15)	Ag1–P1	2.5294(17)
Ag1–P2	2.5013(16)	Ag1–P2	2.5438(13)	Ag1–P2	2.5347(11)	Ag1–P2	2.518(2)	Ag1–P2	2.5453(15)	Ag1–P2	2.558(2)
Ag1-S32	2.6486(16)	Ag1-P3	2.5342(14)	Ag1-P3	2.5609(11)	Ag1-P3	2.504(2)	Ag1-P3	2.5444(13)	Ag1-P3	2.5529(17)
Ag1-Cl4	2.6736(13)	Ag1-Cl1	2.6109(13)	Ag1-Cl1	2.6186(17)	Ag1-I1	2.8359(8)	Ag1-I1	2.8736(6)	Ag1-I1	2.8655(9)
C32-S32	1.666(4)
C32-N33	1.345(5)
N33-H33	1.0323
Bond Angles (°)		Bond Angles (°)		Bond Angles (°)		Bond Angles (°)		Bond Angles (°)		Bond Angles (°)
P1-Ag1–P2	129.05(5)	P1-Ag1-P3	115.56(5)	P1-Ag1-P3	108.40(4)	P3-Ag1–P1	111.40(7)	I1-Ag1–P1	101.55(4)	I1-Ag1–P1	102.37(5)
P1-Ag1-S32	109.04(5)	P1-Ag1–P2	118.85(4)	P2-Ag1–P1	115.89(4)	P3-Ag1–P2	114.32(8)	I1-Ag1–P2	112.12(4)	I1-Ag1–P2	111.54(5)
P2-Ag1-S32	103.91(6)	P3-Ag1–P2	108.03(4)	P2-Ag1-P3	118.22(4)	P1-Ag1–P2	112.77(7)	I1-Ag1-P3	98.57(3)	I1-Ag1-P3	99.44(5)
P1-Ag1-Cl4	113.91(5)	P1-Ag1-Cl1	104.56(5)	P1-Ag1-Cl1	108.88(5)	P3-Ag1-I1	103.79(5)	P1-Ag1–P2	118.13(5)	P1-Ag1–P2	117.81(6)
P2-Ag1-Cl4	95.13(5)	P3-Ag1-Cl1	109.07(5)	P3-Ag1-Cl1	99.54(5)	P1-Ag1-I1	101.52(6)	P1-Ag1-P3	111.87(5)	P1-Ag1-P3	111.94(6)
S32-Ag1-Cl4	102.30(5)	P2-Ag1-Cl1	99.04(5)	P2-Ag1-Cl1	104.17(5)	P2-Ag1-I1	111.95(6)	P2-Ag1-P3	112.31(5)	P2-Ag1-P3	111.77(6)