Bioinorganic Chemistry and Applications / 2010 / Article / Tab 1 / Research Article
Structural Properties, Cytotoxicity, and Anti-Inflammatory Activity of Silver(I) Complexes with tris(p-tolyl)Phosphine and 5-Chloro-2-Mercaptobenzothiazole Table 1 Selected bond lengths (
) and angles (deg) for compounds
1–3 with e.s.d.’s in parentheses in comparison with those found in [
10 ,
30 ].
1 at 293(2) K 2 at 120 K[AgCl(TPTP)3 ] 3 at 120 K[AgI(TPTP)3 ] (polymorph of 3 ) [AgI(TPTP)3 ] (polymorph of 3 ) at 293 K [10 ] at 140 K [10 ] at 293 K [10 ] Bond Distances (Å) Bond Distances (Å) Bond Distances (Å) Bond Distances (Å) Bond Distances (Å) Bond Distances (Å) Ag1–P1 2.4357(18) Ag1–P1 2.5159(13) Ag1–P1 2.5566(12) Ag1–P1 2.511(2) Ag1–P1 2.5208(15) Ag1–P1 2.5294(17) Ag1–P2 2.5013(16) Ag1–P2 2.5438(13) Ag1–P2 2.5347(11) Ag1–P2 2.518(2) Ag1–P2 2.5453(15) Ag1–P2 2.558(2) Ag1-S32 2.6486(16) Ag1-P3 2.5342(14) Ag1-P3 2.5609(11) Ag1-P3 2.504(2) Ag1-P3 2.5444(13) Ag1-P3 2.5529(17) Ag1-Cl4 2.6736(13) Ag1-Cl1 2.6109(13) Ag1-Cl1 2.6186(17) Ag1-I1 2.8359(8) Ag1-I1 2.8736(6) Ag1-I1 2.8655(9) C32-S32 1.666(4) C32-N33 1.345(5) N33-H33 1.0323 Bond Angles (°) Bond Angles (°) Bond Angles (°) Bond Angles (°) Bond Angles (°) Bond Angles (°) P1-Ag1–P2 129.05(5) P1-Ag1-P3 115.56(5) P1-Ag1-P3 108.40(4) P3-Ag1–P1 111.40(7) I1-Ag1–P1 101.55(4) I1-Ag1–P1 102.37(5) P1-Ag1-S32 109.04(5) P1-Ag1–P2 118.85(4) P2-Ag1–P1 115.89(4) P3-Ag1–P2 114.32(8) I1-Ag1–P2 112.12(4) I1-Ag1–P2 111.54(5) P2-Ag1-S32 103.91(6) P3-Ag1–P2 108.03(4) P2-Ag1-P3 118.22(4) P1-Ag1–P2 112.77(7) I1-Ag1-P3 98.57(3) I1-Ag1-P3 99.44(5) P1-Ag1-Cl4 113.91(5) P1-Ag1-Cl1 104.56(5) P1-Ag1-Cl1 108.88(5) P3-Ag1-I1 103.79(5) P1-Ag1–P2 118.13(5) P1-Ag1–P2 117.81(6) P2-Ag1-Cl4 95.13(5) P3-Ag1-Cl1 109.07(5) P3-Ag1-Cl1 99.54(5) P1-Ag1-I1 101.52(6) P1-Ag1-P3 111.87(5) P1-Ag1-P3 111.94(6) S32-Ag1-Cl4 102.30(5) P2-Ag1-Cl1 99.04(5) P2-Ag1-Cl1 104.17(5) P2-Ag1-I1 111.95(6) P2-Ag1-P3 112.31(5) P2-Ag1-P3 111.77(6)