Diorganotin Complexes of a Thiosemicarbazone, Synthesis: Properties, X-Ray Crystal Structure, and Antiproliferative Activity of Diorganotin Complexes

Table 3

C–H→π interactions and intermolecular hydrogen bonds for 5.

C–H(I) → Cg(J)^a			H–Cg	C–Cg	∠C–H–Cg
C(11)–H(11) [1] → Cg(4)^(i)			2.71	3.5394	159
C(60)–H(60) [2] → Cg(5)^(ii)			2.66	3.4118	135
D	H	A^b	H ⋯ A	D ⋯ A	∠D–H ⋯ A
N(1)–H(1A)⋯N(4)^(iii)			2.13	3.005(2)	165
N(1)–H(1B)⋯O(51)^(iv)			2.28	3.065(2)	150
N(1)–H(1B)⋯O(52)^(iv)			2.55	3.124(2)	124
N(51)–H(51A)⋯N(54)^(v)			2.16	2.993(3)	168
N(51)–H(51B)⋯O(1)			2.24	3.013(2)	152
C(8)–H(8)⋯S(51)			2.84	3.673(2)	143
C(14)–H(14)⋯N(2)^(iii)			2.50	3.442(2)	175
C(58)–H(58)⋯S(51)			2.85	3.564(2)	127
C(62)–H(62)⋯O(51)			2.55	3.132(2)	118
C(64)–H(64)⋯N(52)^(v)			2.58	3.483(2)	174

^aWhere Cg(4) and Cg(5) are referred to the rings C(1)–C(6) and C(7)–C(12); ^bCg-Cg is the distance between ring centroids; symmetry transformations, (i) 1−𝑥, −𝑦, −𝑧; (ii) 1−𝑥, 1−𝑦, −𝑧; (iii) 1−𝑥, −𝑦,1−𝑧; (iv) 𝑥, −1+𝑦, 𝑧; (v) 2−𝑥, 1−𝑦, 1−𝑧.