Research Article

Binuclear Cu(II) and Co(II) Complexes of Tridentate Heterocyclic Shiff Base Derived from Salicylaldehyde with 4-Aminoantipyrine

Table 2

Characteristic IR and electronic spectral data of the metal complexes.

No.ComplexesUV/ VIS
λ max (cm−1)
μ eff. BMIR spectra cm−1
υC=OυC=NυC–OυM–NυM–O

1[Cu2(L1)2 H2O]11085, 16595, 279900.91650 s1600 m1265 s460 w530 w
2[Cu2(L2)2(H2O)4]11080, 16590, 279951.691670 s1610 m1260 s465 w535 w
3[Co2(L1)2H2O]10370, 14380, 18720, 356905.041665 s1610 m1270 s470 w520 w
4[Co2(L2)2(H2O)4]10375, 14385, 18725, 356954.901660 s1590 m1270 s460 w515 w