Research Article
Spectroscopic, Thermal, Electrochemical, and Antimicrobial Studies of Mononuclear Manganese(II) Ditolyldithiophosphates
Table 1
Synthetic and analytical data for the Mn(II) ditolyldithiophosphates.
| | S. no. | Complex |
Physical state*
Yield (%) | m.p. (°C) |
Molar conductance
(Ω−1 cm2 mol−1) | Analysis found (calcd.) (in %) | | C | H | S | N | Cl | Mn |
| | 1. |
[{(o-CH3C6H4O)2PS2}2Mn] | White
(95) | 55 | 4.62 | 49.89
(49.92) | 4.17
(4.19) | 19.03
(19.04) | — | — | 8.13
(8.16) | | 2. |
[{(m-CH3C6H4O)2PS2}2Mn] | White
(94) | 56 | 5.62 | 49.89
(49.92) | 4.18
(4.19) | 19.02
(19.04) | — | — | 8.12
(8.16) | | 3. |
[{(p-CH3C6H4O)2PS2}2Mn] | White
(98) | 55 | 5.30 | 49.90
(49.92) | 4.18
(4.19) | 19.02
(19.04) | — | — | 8.13
(8.16) | | 4. |
[{(p-Cl-m-CH3C6H3O)2PS2}2Mn] | White
(97) | 57 | 6.42 | 41.42
(41.44) | 2.96
(2.98) | 15.79
(15.81) | — | 17.46
(17.48) | 6.75
(6.77) | | 5. | [{(o-CH3C6H4O)2PS2}2Mn · N2C12H8] | Yellow
(94) | 61 | 7.63 | 56.23
(56.26) | 4.24
(4.25) | 15.00
(15.02) | 3.26
(3.28) | — | 6.40
(6.43) | | 6. | [{(m-CH3C6H4O)2PS2}2Mn · N2C12H8] | Yellow
(92) | 63 | 7.63 | 56.24
(56.26) | 4.22
(4.25) | 15.00
(15.02) | 3.25
(3.28) | — | 6.41
(6.43) | | 7. | [{(p-CH3C6H4O)2PS2}2Mn · N2C12H8] | Yellow
(97) | 62 | 6.54 | 56.24
(56.26) | 4.22
(4.25) | 14.99
(15.02) | 3.27
(3.28) | — | 6.40
(6.43) | | 8. | [{(p-Cl-m-CH3C6H3O)2PS2}2Mn · N2C12H8] | Yellow
(98) | 63 | 9.81 | 48.43
(48.45) | 3.22
(3.25) | 12.90
(12.93) | 3.22
(3.25) | 14.28
(14.30) | 5.51
(5.54) | | 9. | [{(o-CH3C6H4O)2PS2}2Mn · N2C10H8] | Yellow
(96) | 60 | 4.36 | 54.99
(55.00) | 4.35
(4.37) | 15.43
(15.46) | 3.37
(3.38) | — | 6.60
(6.62) | | 10. | [{(m-CH3C6H4O)2PS2}2Mn · N2C10H8] | Yellow
(91) | 61 | 7.63 | 54.97
(55.00) | 4.34
(4.37) | 15.44
(15.46) | 3.36
(3.38) | — | 6.59
(6.62) | | 11. | [{(p-CH3C6H4O)2PS2}2Mn · N2C10H8] | Yellow
(97) | 60 | 5.45 | 54.97
(55.00) | 4.36
(4.37) | 15.43
(15.46) | 3.37
(3.38) | — | 6.59
(6.62) | | 12. | [{(p-Cl-m-CH3C6H3O)2PS2}2Mn · N2C10H8] | Yellow
(98) | 62 | 5.45 | 47.15
(47.17) | 3.27
(3.30) | 13.23
(13.26) | 2.89
(2.90) | 14.63
(14.66) | 5.66
(5.68) | | 13. | [{(o-CH3C6H4O)2PS2}2Mn · 2NC5H5] | Pale yellow
(92) | 56 | 5.45 | 54.84
(54.87) | 4.57
(4.60) | 15.41
(15.42) | 3.34
(3.37) | — | 6.58
(6.60) | | 14. | [{(m-CH3C6H4O)2PS2}2Mn · 2NC5H5] | Pale yellow
(90) | 57 | 6.54 | 54.85
(54.87) | 4.58
(4.60) | 15.40
(15.42) | 3.35
(3.37) | — | 6.59
(6.60) | | 15. | [{(p-CH3C6H4O)2PS2}2Mn · 2NC5H5] | Pale yellow
(95) | 56 | 4.36 | 54.86
(54.87) | 4.57
(4.60) | 15.40
(15.42) | 3.36
(3.37) | — | 6.57
(6.60) | | 16. | [{(p-Cl-m-CH3C6H3O)2PS2}2Mn · 2NC5H5] | Pale yellow
(96) | 58 | 4.36 | 47.06
(47.07) | 3.50
(3.53) | 13.20
(13.23) | 2.87
(2.89) | 14.60
(14.63) | 5.66
(5.67) | | 17. | [{(o-CH3C6H4O)2PS2}2Mn · 2P(C6H5)3] | White
(90) | 64 | 6.54 | 64.13
(64.15) | 4.85
(4.88) | 10.68
(10.70) | — | — | 4.56
(4.58) | | 18. | [{(m-CH3C6H4O)2PS2}2Mn · 2P(C6H5)3] | White
(90) | 63 | 6.54 | 64.13
(64.15) | 4.85
(4.88) | 10.67
(10.70) | — | — | 4.56
(4.58) | | 19. | [{(p-CH3C6H4O)2PS2}2Mn · 2P(C6H5)3] | White
(94) | 67 | 5.45 | 64.12
(64.15) | 4.86
(4.88) | 10.68
(10.70) | — | — | 4.57
(4.58) | | 20. | [{(p-Cl-m-CH3C6H3O)2PS2}2Mn · 2P(C6H5)3] | White
(96) | 62 | 6.54 | 57.52
(57.54) | 4.05
(4.07) | 9.58
(9.60) | — | 10.59
(10.61) | 4.10
(4.11) |
|
|
*: solid.
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