Novel Zinc(II) Complexes of Heterocyclic Ligands as Antimicrobial Agents: Synthesis, Characterisation, and Antimicrobial Studies

<table class="table-group" id="tab2"><tr><td><table class="table"><tr><td class="thead-hr" colspan="7"><hr/></td></tr><tr class="thead"><td align="left">Complex</td><td align="center">Lattice water <svg height="13.8375" id="M36" style="vertical-align:-4.90038pt" version="1.1" viewbox="0 0 37.162498 13.8375" width="37.162498" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
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<g transform="matrix(.012,-0,0,-.012,10.35,11.762)"><path d="M300 -147l-18 -23q-106 71 -159 185.5t-53 254.5v1q0 139 53 252.5t159 186.5l18 -24q-74 -62 -115.5 -173.5t-41.5 -242.5q0 -130 41.5 -242.5t115.5 -174.5z" id="x28"></path></g><g transform="matrix(.012,-0,0,-.012,14.467,11.762)"><path d="M381 665q131 0 226.5 -93t95.5 -239q0 -158 -96 -253t-238 -95q-137 0 -231 95t-94 238q0 142 92.5 244.5t244.5 102.5zM359 629q-89 0 -151 -74.5t-62 -208.5q0 -141 69 -233t175 -92q90 0 150.5 74t60.5 211q0 152 -69 237.5t-173 85.5z" id="x4F"></path></g><g transform="matrix(.012,-0,0,-.012,23.26,11.762)"><path d="M729 650v-28q-62 -5 -76 -19.5t-14 -75.5v-404q0 -62 13.5 -76t75.5 -19v-28h-268v28q65 5 79.5 19t14.5 76v199h-341v-199q0 -62 14 -76t76 -19v-28h-263v28q61 5 74.5 19t13.5 76v404q0 62 -14 76t-76 19v28h259v-28q-58 -5 -71 -19t-13 -76v-162h341v162
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</svg> cm<sup>−1</sup></td><td align="center"><svg height="12" id="M37" style="vertical-align:-3.41936pt" version="1.1" viewbox="0 0 34.825001 12" width="34.825001" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
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<g transform="matrix(.012,-0,0,-.012,10.35,11.762)"><path d="M614 175l29 -10q-33 -109 -57 -154q-121 -26 -184 -26q-90 0 -160.5 29t-112.5 77t-63.5 105.5t-21.5 119.5q0 157 108 253t277 96q36 0 71.5 -5t69 -13.5t36.5 -8.5q15 -102 20 -150l-29 -8q-20 79 -66.5 114t-128.5 35q-119 0 -187.5 -86t-68.5 -207
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</svg> cm<sup>−1</sup></td><td align="center"><svg height="12" id="M38" style="vertical-align:-3.41936pt" version="1.1" viewbox="0 0 34.775002 12" width="34.775002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
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<g transform="matrix(.012,-0,0,-.012,10.35,11.762)"><path d="M614 175l29 -10q-33 -109 -57 -154q-121 -26 -184 -26q-90 0 -160.5 29t-112.5 77t-63.5 105.5t-21.5 119.5q0 157 108 253t277 96q36 0 71.5 -5t69 -13.5t36.5 -8.5q15 -102 20 -150l-29 -8q-20 79 -66.5 114t-128.5 35q-119 0 -187.5 -86t-68.5 -207
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</svg> cm<sup>−1</sup></td><td align="center"><svg height="16.487499" id="M39" style="vertical-align:-3.41936pt" version="1.1" viewbox="0 0 84.824997 16.487499" width="84.824997" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.162)"><path d="M46 650h247q112 0 169 -41q64 -49 64 -141q0 -91 -56.5 -143t-138.5 -62q-23 -3 -45 -1l-74 19v-157q0 -63 15.5 -77t83.5 -19v-28h-271v28q60 5 74 20t14 77v400q0 65 -12.5 79t-69.5 18v28zM212 559v-245q31 -12 73 -12q59 0 102 38t43 124q0 77 -42.5 115.5
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<g transform="matrix(.012,-0,0,-.012,60.85,16.25)"><path d="M614 175l29 -10q-33 -109 -57 -154q-121 -26 -184 -26q-90 0 -160.5 29t-112.5 77t-63.5 105.5t-21.5 119.5q0 157 108 253t277 96q36 0 71.5 -5t69 -13.5t36.5 -8.5q15 -102 20 -150l-29 -8q-20 79 -66.5 114t-128.5 35q-119 0 -187.5 -86t-68.5 -207
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</svg> cm<sup>−1</sup></td><td align="center"><svg height="11.925" id="M40" style="vertical-align:-3.36203pt" version="1.1" viewbox="0 0 36.962502 11.925" width="36.962502" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,7.675)"><path d="M509 373q0 -52 -42.5 -118.5t-124.5 -159.5l-94 -107h-27q-22 209 -78 342q-21 48 -41 48q-18 0 -63 -62l-22 21q77 111 125 111q30 0 52 -21.5t38 -75.5q37 -130 52 -285q48 62 74.5 99.5t53.5 87t27 76.5q0 43 -17 60q-5 5 -5 15q0 17 12.5 30.5t28.5 13.5
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<g transform="matrix(.012,-0,0,-.012,10.35,11.762)"><path d="M861 0h-263v28q61 5 73 22t12 97l-4 408h-4l-244 -548h-20l-224 534h-2l-15 -285q-5 -98 -3 -166q1 -34 19.5 -45t72.5 -17v-28h-233v28q45 5 62.5 17t22.5 43q11 65 19 183l14 208q3 36 3.5 55t-2.5 37.5t-6.5 25t-16.5 13t-25.5 8t-39.5 4.5v28h164l228 -501l232 501
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</svg> cm<sup>−1</sup></td><td align="center"><svg height="12" id="M41" style="vertical-align:-3.41936pt" version="1.1" viewbox="0 0 37.012501 12" width="37.012501" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,7.675)"><path d="M509 373q0 -52 -42.5 -118.5t-124.5 -159.5l-94 -107h-27q-22 209 -78 342q-21 48 -41 48q-18 0 -63 -62l-22 21q77 111 125 111q30 0 52 -21.5t38 -75.5q37 -130 52 -285q48 62 74.5 99.5t53.5 87t27 76.5q0 43 -17 60q-5 5 -5 15q0 17 12.5 30.5t28.5 13.5
q21 0 36 -22.5t15 -52.5z" id="x1D708"></path></g>
<g transform="matrix(.012,-0,0,-.012,10.35,11.762)"><path d="M861 0h-263v28q61 5 73 22t12 97l-4 408h-4l-244 -548h-20l-224 534h-2l-15 -285q-5 -98 -3 -166q1 -34 19.5 -45t72.5 -17v-28h-233v28q45 5 62.5 17t22.5 43q11 65 19 183l14 208q3 36 3.5 55t-2.5 37.5t-6.5 25t-16.5 13t-25.5 8t-39.5 4.5v28h164l228 -501l232 501
h170v-28q-68 -6 -81 -21.5t-11 -91.5l9 -362q2 -80 15 -97t78 -22v-28z" id="x4D"></path></g><g transform="matrix(.012,-0,0,-.012,20.952,11.762)"><path d="M300 253l-14 -55h-229l14 55h229z" id="x2D"></path></g><g transform="matrix(.012,-0,0,-.012,23.213,11.762)"><path d="M300 253l-14 -55h-229l14 55h229z" id="x2D"></path></g><g transform="matrix(.012,-0,0,-.012,27.449,11.762)"><path d="M381 665q131 0 226.5 -93t95.5 -239q0 -158 -96 -253t-238 -95q-137 0 -231 95t-94 238q0 142 92.5 244.5t244.5 102.5zM359 629q-89 0 -151 -74.5t-62 -208.5q0 -141 69 -233t175 -92q90 0 150.5 74t60.5 211q0 152 -69 237.5t-173 85.5z" id="x4F"></path></g>
</svg> cm<sup>−1</sup></td></tr><tr><td class="thead-hr" colspan="7"><hr/></td></tr><tr><td align="left"><svg height="14.85" id="M42" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M290 -163h-170v866h170v-28q-79 -7 -94 -19.5t-15 -72.5v-627q0 -59 14.5 -71.5t94.5 -19.5v-28z" id="x5B"></path></g>
</svg>Zn(NMAPIMHMC)<sub>2</sub><svg height="14.85" id="M43" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M226 -163h-170v27q79 7 94 20t15 73v627q0 59 -15 72t-94 20v27h170v-866z" id="x5D"></path></g>
</svg>·2H<sub>2</sub>O</td><td align="center">3122</td><td align="center">1727 (lactone)</td><td align="center">1631</td><td align="center">1371</td><td align="center">543</td><td align="center">453</td></tr><tr><td align="left"><svg height="14.85" id="M44" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M290 -163h-170v866h170v-28q-79 -7 -94 -19.5t-15 -72.5v-627q0 -59 14.5 -71.5t94.5 -19.5v-28z" id="x5B"></path></g>
</svg>Zn(HBABO)<sub>2</sub><svg height="14.85" id="M45" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M226 -163h-170v27q79 7 94 20t15 73v627q0 59 -15 72t-94 20v27h170v-866z" id="x5D"></path></g>
</svg>·2H<sub>2</sub>O</td><td align="center">3282</td><td align="center">1750 (Oxazolidinone)</td><td align="center">1625</td><td align="center">1446</td><td align="center">530</td><td align="center">449</td></tr><tr><td align="left"><svg height="14.85" id="M46" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M290 -163h-170v866h170v-28q-79 -7 -94 -19.5t-15 -72.5v-627q0 -59 14.5 -71.5t94.5 -19.5v-28z" id="x5B"></path></g>
</svg>Zn(TMPIMP)<sub>2</sub><svg height="14.85" id="M47" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M226 -163h-170v27q79 7 94 20t15 73v627q0 59 -15 72t-94 20v27h170v-866z" id="x5D"></path></g>
</svg>·2H<sub>2</sub>O</td><td align="center">3312</td><td align="center">NA</td><td align="center">1619</td><td align="center">1452</td><td align="center">522</td><td align="center">447</td></tr><tr class="table-tr"><td colspan="7"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

FT-IR bands for metal complexes and their assignments.

Bioinorganic Chemistry and Applications

tab2

Table 2

Table 2: Novel Zinc(II) Complexes of Heterocyclic Ligands as Antimicrobial Agents: Synthesis, Characterisation, and Antimicrobial Studies 