Syntheses, Characterization, Thermal, and Antimicrobial Studies of Lanthanum(III) Tolyl/Benzyldithiocarbonates

Table 2

Mass spectral data of tolyl/benzyl dithiocarbonates of La(III) and their adducts.

S. No.*	M.W.	𝑚/𝑧, Relative intensities of the ions and assignment
5.	688	[M^+] 688 (11) [La(𝑜-CH3C6H4OCS2)3]; [M^+] 183 (30) [𝑜-CH3C6H4OCS2]; [M^+] 107 (18) [𝑜-CH3C6H4O]; [M^+] 504 (15) [La(𝑜-CH3C6H4OCS2)2]; [M^+] 321 (7) [La(𝑜-CH3C6H4OCS2)]; [M^+] 503 (15) [(C6H4OCS2)3]; [M^+] 474 (9) [La(C6H4OCS2)2]; [M^+] 306 (10) [La(C6H4OCS2)]; [M^+] 168 (8) [(C6H4OCS2)].
9.	846	[M^−] 846 (7) [La(𝑜-CH3C6H4OCS2)3La.2NC5H5]; [M^+] 687 (15) [La(𝑜-CH3C6H4OCS2)3]; [M^−] 183 (15); [(𝑜-CH3C6H4OCS2)]; [M^−] 107 (16) [𝑜-CH3C6H4O]; [M^+] 662 (15) [La(𝑜-CH3C6H4OCS2)2·2NC5H5]; [M^+] 296 (12) [La.2NC5H5].
14.	1213	[M^+] 1213 (5) [La(𝑚-CH3C6H4OCS2)3·2P(C6H5)3]; [M^+] 949 (6) [La(𝑚-CH3C6H4OCS2)3·P(C6H5)3]; [M^+] 687 (4) [La(𝑚-CH3C6H4OCS2)3]; [M^+] 1029 (9) [La(𝑚-CH3C6H4OCS2)2·2P(C6H5)3]; [M^+] 504 (6) [La(𝑚-CH3C6H4OCS2)2]; [M^+] 183 (7) [𝑚-CH3C6H4OCS2]; [M^−] 107 (7) [𝑚-CH3C6H4O].
19.	868	[M^+] 868 (6) [La(𝑝-CH3C6H4OCS2)3·N2C12H8]; [M^+] 687 (8) [La(𝑝-CH3C6H4OCS2)3]; [M^+] 684 (7) [La(𝑝-CH3C6H4OCS2)2·N2C12H8]; [M^+] 321 (4) [La(𝑝-CH3C6H4OCS2)]; [M^−] 107 (6) [𝑝-CH3C6H4O]; [M^+] 318 (5) [La·N2C12H8]; [M^+] 180 (5) [N2C12H8];
22.	844	[M^+] 844 (6) [La(𝑚-CH3C6H4OCS2)3·N2C10H8]; [M^+] 687 (8) [La(𝑚-CH3C6H4OCS2)3]; [M^+] 687 (8) [La(𝑚-CH3C6H4OCS2)2]; [M^+] 183 (5) [𝑜-CH3C6H4OCS2]; [M^−] 477 (6) [La(𝑚-CH3C6H4OCS2)·N2C10H8]; [M^+] 294 (4) [La·N2C10H8]; [M^+] 156 (20) [N2C10H8].
24.	844	[M^+] 844 (10) [La(C6H5CH2OCS2)3·N2C10H8]; [M^+] 687 (6) [La(C6H5CH2OCS2)3]; [M^+] 613 (4) [La(CH2OCS2)3·N2C10H8)] [M^+] 456 (13) [La(CH2OCS2)3]; [M^+] 294 (6) [La·N2C10H8]; [M^+] 156 (14) [N2C10H8].

Bracket = 𝑚/𝑧; parentheses = intensities in %; ∗S. number of the complexes is according to Table 1.