Research Article
Synthesis and Spectroscopic and Biological Activities of Zn(II) Porphyrin with Oxygen Donors
Table 5
Mass data (m/z ratio) and elemental analytical data of X-Zn-t(p-CH3)PP (X = different phenols as axial ligand) along with their calculated values.
| | Porphyrins | Molecular formula | m/z ratio
calculated (found) | Percentage
calculated (found) | | C | H | N |
| phO-Zn-t(p-CH3)PP
(C6H5O)Zn(C48H36N4) | C54H41N4ZnO | 828.39
(828.29) | 78.29
(78.30) | 4.99
(4.99) | 6.76
(6.76) | -Naphthol-Zn-t(p-CH3)PP
(C10H7O)Zn(C48H36N4) | C58H43N4ZnO | 878.90
(878.96) | 79.31
(79.17) | 4.94
(4.93) | 6.38
(6.37) | p-NH2phO-Zn-t(p-CH3)PP
(C6H6NO)Zn(C48H36N4) | C54H43N5ZnO | 843.39
(844.46) | 76.81
(76.85) | 5.13
(5.14) | 8.3
(8.30) | o-OCH3phO-Zn-t(p-CH3)PP
(C7H7O2)Zn(C48H36N4) | C55H43N4ZnO2 | 858.53
(858.49) | 76.94
(76.77) | 5.05
(5.03) | 6.53
(6.51) | m-ClphO-Zn-t(p-CH3)PP
(C6H4ClO)Zn(C48H36N4) | C54H40N4ZnOCl | 862.95
(862.90) | 75.16
(75.08) | 4.67
(4.67) | 6.49
(6.49) | 2,4Cl2phO-Zn-t(p-CH3)PP
(C6H3Cl2O)Zn(C48H36N4) | C54H39N4ZnOCl2 | 897.39
(897.30) | 72.27
(72.36) | 4.38
(4.39) | 6.24
(6.25) |
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