The Structures, Spectroscopic Properties, and Photodynamic Reactions of Three [RuCl(QN)NO]<sup>−</sup> Complexes (HQN = 8-Hydroxyquinoline and Its Derivatives) as Potential NO-Donating Drugs

<table class="table-group" id="tab4"><tr><td><table class="table"><tr><td class="thead-hr" colspan="6"><hr/></td></tr><tr class="thead"><td class="align_left" rowspan="2">Molecule</td><td class="align_center" rowspan="2">Peak position/cm<sup>−1</sup>(exp)</td><td class="align_center" colspan="2">Atomic charge</td><td class="align_center" colspan="2">Wiberg bond index</td></tr><tr class="thead"><td class="align_center">N</td><td class="align_center">O</td><td class="align_center">Ru-N</td><td class="align_center">N-O</td></tr><tr><td class="thead-hr" colspan="6"><hr/></td></tr><tr><td class="align_left">[RuCl(hqn)NO]<sup>−</sup></td><td class="align_center">1839.40</td><td class="align_center">0.454</td><td class="align_center">−0.210</td><td class="align_center">1.6503</td><td class="align_center">1.8449</td></tr><tr><td class="align_left">[RuCl(2mqn)NO]<sup>−</sup></td><td class="align_center">1844.01</td><td class="align_center">0.451</td><td class="align_center">−0.208</td><td class="align_center">1.6408</td><td class="align_center">1.8501</td></tr><tr><td class="align_left">[RuCl(2cqn)NO]<sup>−</sup></td><td class="align_center">1856.55</td><td class="align_center">0.467</td><td class="align_center">−0.189</td><td class="align_center">1.6251</td><td class="align_center">1.8757</td></tr><tr class="table-tr"><td colspan="6"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

<div>Natural atomic charges and Wiberg bond index of NO in the three [RuCl(QN)NO]<sup>−</sup> complexes.</div>

Bioinorganic Chemistry and Applications

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Table 4

Table 4: The Structures, Spectroscopic Properties, and Photodynamic Reactions of Three [RuCl(QN)NO]<sup>−</sup> Complexes (HQN = 8-Hydroxyquinoline and Its Derivatives) as Potential NO-Donating Drugs 

Table 4 | The Structures, Spectroscopic Properties, and Photodynamic Reactions of Three [RuCl(QN)NO]− Complexes (HQN = 8-Hydroxyquinoline and Its Derivatives) as Potential NO-Donating Drugs 