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Analytes | Samples | Extraction | Determination | Analytical parameters | Reference |
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26 steroids including natural and synthetic estrogens, progestogens, and androgens | Water samples | SPE | LC-MS2 | Recovery > 80% MDLs: 0.1–0.73 ng·L−1 | [105] |
Resveratrol, daidzein, coumestrol, genistein | River water | SPE | LC- MS2 | Recovery > 80% LODs ≤ 2 ng·L−1 | [106] |
36 endocrine disrupting chemicals including estrogens and progestogens | Potable and river water | SPE | UPLC-Q-TOF-MS | Recovery: 46–134% LODs < 0.72 ng·L−1 | [107] |
Boldenone, nandrolone, testosterone, methyltestosterone, epiandrosterone, androsterone, satnozolol | Human urine | In-tube SPME | LC-MS2 | Recovery: 86–117% LODs: 9–182 pg·mL−1 | [108] |
28 steroids including natural and synthetic estrogens, androgens, progestogens, and glucocorticoids | Sludge | UAE | LC-MS2 | Recovery: 63–138% LODs: 0.08–2.06 ng·g−1 | [100] |
β-Estradiol, estriol, 17α-ethinylestradiol | Sewage sludge | MAE | LC-MS2 | Recovery: 72–103% LODs: 0.6–3.5 ng·g−1 | [75] |
Estrone, testosterone, androstenedione, norethindrone, levonorgestrel, progesterone | Soil | PLE | LC-MS2 | Recovery: 45–100% LODs: 0.08–0.89 ng·g−1 | [88] |
α-Estradiol, β-estradiol, estriol, estrone and ethynylestradiol and their sulfate, glucuronide and acetate conjugates | River sediments | MAE | LC-MS2 | Recovery: 83–107% LODs < 1 ng·g−1 | [109] |
Estrone, 17α-estradiol, 17β-estradiol, estriol, 17α-ethinylestradiol, diethylstilbestrol, estradiol 17-glucoronide, estrone 3-glucoronide, estradiol 3-sulfate, estrone 3-sulfate, estradiol 17-acetate | Sewage sludge | PLE | LC-MS2 | Recovery > 81% LODs < 26 ng·g−1 | [85] |
Estradiol, estrone, estriol, estradiol-17-glucuronide, estrone-3-sulfate, ethynylestradiol, diethylstilbestrol, bisphenol, progesterone, levonorgestrel, norethindrone | River water | SPE | LC-MS2 | Recovery: 70–104% MDLs ≤ 3.94 ng·L−1 | [97] |
Eighteen androgens and progestogens | Environmental waters | DLLME-SFO | UHPLC-MS2 | Recovery: 87–116% LODs: 0.8–3.1 μg·L−1 | [99] |
Flurogestone acetate, delmadinone acetate, megestrol acetate, chlormadinone acetate, melengestrol acetate, medroxyprogesterone acetate, and chlorotestosterone acetate | Kidney | ASE | LC-MS2 | Recovery: 17–58% | [103] |
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