Vegetable Oil Derived Solvent, and Catalyst Free “Click Chemistry” Thermoplastic Polytriazoles

Scheme 1

Synthesis of vegetable derived diazide monomer. (a) Grubbs 2nd gen, neat, 45°C, 12 h. (b) LiAlH₄, THF, 0°C → RT, 4 h. (c) TsCl, TEA, DMAP, CH₂Cl₂ 0°C → RT, 6 h. (d) NaN₃, DMSO, H₂O, 100°C, 12 h.