Review Article

Biomarkers of Type II Synthetic Pyrethroid Pesticides in Freshwater Fish

Table 1

Pyrethrins, type I pyrethroids, and type II pyrethroids*.

Active ingredientPyrethrins: constituents of natural pyrethrum extractsSynthetic derivatives of pyrethrin: pyrethroids
Esters of Chrysanthemic acidEsters of Pyrethric acidType I
Esters without alpha-cyano group
Type II
Esters with alpha-cyano group

Types of pyrethrins/pyrethroids gradually developedPyrethrin-IPyrethrin-IIAllethrin
1st generation
Fenvalerate
3rd generation
Cinerin-ICinerin-IIResmethrin
2nd generation
Cyhalothrin
4th generation
Jasmolin-IJasmolin-IIPermethrin
3rd generation
Cypermethrin
4th generation
Bifenthrin
4th generation
Deltamethrin
4th generation

 *Based on [1, 2].