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International Journal of Analytical Chemistry
Volume 2013 (2013), Article ID 743792, 4 pages
http://dx.doi.org/10.1155/2013/743792
Research Article

Application of Dispersive Liquid-Liquid Microextraction with Graphite Furnace Atomic Absorption Spectrometry for Determination of Trace Amounts of Zinc in Water Samples

Department of Chemistry, Shahre Ray Branch, Islamic Azad University, Tehran 18155-144, Iran

Received 9 February 2013; Accepted 18 April 2013

Academic Editor: M. A. Raggi

Copyright © 2013 Ali Mazloomifar. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A selective and simple method for separation and preconcentration of zinc ions was developed by using dispersive liquid-liquid microextraction. Parameters that have an effect on the microextraction efficiency such as volume of extraction and disperser solvent, extraction time, and adding salt were investigated. Under optimum conditions, a preconcentration factor of 250 was obtained. The limit of detection (LOD) obtained under the optimal conditions was 0.09 ng mL−1. The linearity of method was obtained in range of 0.2–50 ng mL−1 with a correlation coefficient ( ) of 0.9974. The relative standard deviation for 10 replicate determinations at 1.0 ng mL−1 of zinc was 2.53%. The proposed method was successfully applied to the analysis of zinc in water sample.