Research Article
Determination of Glucocorticoids in UPLC-MS in Environmental Samples from an Occupational Setting
Table 3
Results of pad-tests on workers clothes of a pharmaceutical plant (2013). For each sample
. “I” indicates the internal surface of the smocks.
| Compound | Torax Mean (Min–Max) Std] | Right forearm Mean (Min–Max) Std] | Left forearm Mean (Min–Max) Std] | Back Mean (Min–Max) Std] | Right thigh Mean (Min–Max) Std] | Left thigh Mean (Min–Max) Std] | Right forearm - I Mean (Min–Max) Std] | Left forearm - I Mean (Min–Max) Std] |
| Beclomethasone dipropionate | 661.7 (5.5–3203.4) 1421.0] | 253.0 (6.1–1095.7) 472.0] | 473.2 (7.8–2254.2) 995.7] | 11.0 (0.7–48.8) 21.2] | 294.0 (17.3–1138.0) 479.4] | 298.3 (1.0–1080.2) 466.7] | 9.4 (0.8–19.1) 6.66] | 8.4 (3.9–14.8) 4.60] |
| Betamethasone dipropionate | 2.4 (0–4.1) 1.9] | 3.0 (0–5.1) 2.0] | 3.7 (1.9–4.6) 1.1] | 0.1 (0–0.4) 0.2] | 4.7 (0.8–9.8) 3.3] | 1.4 (0.7–2.8) 0.9] | 0.4 (0–1.1) 0.4] | 0.8 (0–2.2) 0.9] |
| Clobetasol 17-propionate | 2.7 (1.4–4.0) 1.3] | 4.1 (1.6–7.5) 2.4] | 3.5 (1.9–6.0) 1.7] | 0.3 (0–0.5) 0.3] | 10.8 (3.3–31.0) 11.4] | 6.3 (1.0–25.8) 10.9] | 1.9 (0.5–4.9) 1.7] | 1.2 (0.5–2.6) 0.9] |
| Clocortolone pivalate | 0.1 (0–0.5) 0.2] | 0.2 (0–0.5) 0.3] | 0.1 (0–0.5) 0.2] | 0.1 (0–0.5) 0.2] | 0.4 (0–0.5) 0.2] | 0.1 (0–0.5) 0.2] | 0.1 (0–0.5) 0.2] | 0.1 (0–0.5) 0.2] |
| Chlormadinone acetate | 6.2 (1.5–14.9) 6.2] | 5.5 (2.3–10.0) 3.2] | 6.2 (1.0–16.2) 5.8] | 0.7 (0–1.1) 0.5] | 8.3 (2.0–18.6) 7.1] | 3.8 (0.5–7.5) 2.6] | 10.0 (0–25.0) 11.1] | 5.8 (3.9–8.2) 2.1] |
| Delmadinone acetate | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] |
| Desonide | 4.1 (0–16.6) 7.0] | 5.5 (0–21.7) 9.2] | 4.3 (0–14.7) 6.0] | <0.1 (—) —] | 5.4 (0.8–18.9) 7.7] | 2.2 (0–6.9) 2.9] | 1.5 (0–3.7) 1.8] | 0.8 (0–3.4) 1.5] |
| Desoximetasone | 1.9 (0–5.1) 2.4] | 2.4 (0–8.1) 3.9] | 6.9 (0–26.7) 13.2] | <0.1 (—) —] | 3.3 (0–10.9) 5.2] | 2.6 (0–10.6) 5.3] | 5.7 (0–22.8) 11.4] | 3.3 (0–12.4) 6.1] |
| Diflucortolone valerate | 0.5 (0–1.1) 0.5] | 0.8 (0–1.4) 0.5] | 1.2 (0–4.1) 1.7] | <0.1 (—) —] | 0.9 (0–2.1) 1.0] | 0.4 (0–1.9) 0.8] | 3.4 (0–17.2) 7.7] | 7.7 (0–30.2) 15.0] |
| Exemestane | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] |
| Fluocinolone acetonide | 1.1 (0–1.9) 0.7] | 2.6 (0–9.5) 3.9] | 2.6 (0–10.6) 4.5] | <0.1 (—) —] | 3.2 (0–10.8) 4.3] | 1.6 (0–6.2) 2.7] | 0.5 (0–1.7) 0.8] | 0.8 (0–2.5) 1.2] |
| Fluocinonide | 2.8 (0.5–6.3) 2.7] | 7.8 (1.2–26.5) 10.6] | 7.7 (0.8–30.2) 12.7] | <0.1 (—) —] | 6.5 (1.4–19.0) 7.4] | 3.9 (0–16.6) 7.1] | 2.0 (0–6.0) 2.5] | 1.5 (0–4.6) 1.9] |
| Fluprednidene acetate | 0.3 (0–0.9) 0.4] | 0.5 (0–0.8) 0.3] | 0.8 (0–3.0) 1.2] | <0.1 (—) —] | 0.9 (0–1.7) 0.7] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] |
| Halcinonide | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] |
| Halometasone monohydrate | 1.0 (1.0–1.1) 0] | 1.4 (1.0–2.8) 0.8] | 1.2 (1.0–2.1) 0.5] | 1.0 1.0 0] | 1.5 (1.0–3.3) 1.0] | 1.0 1.0 0] | 1.0 1.0 0] | 1.0 1.0 0] |
| Hydrocortisone acetate | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] | <0.1 (—) —] |
| Megestrol acetate | 6.9 (0–34.0) 15.1] | 2.1 (0–8.0) 3.4] | 8.3 (0–40.0) 17.7] | 0.8 (0–3.0) 1.5] | 15.1 (0.5–73.0) 32.3] | 1.5 (0–7.0) 3.1] | 1.9 (0–8.0) 3.5] | 2.1 (0–9.0) 3.9] |
| Methylprednisolone acetate | 1.4 1.4 0] | 1.4 1.4 0] | 1.4 1.4 0] | 1.4 1.4 0] | 1.4 1.4 0] | 1.4 1.4 0] | 1.4 1.4 0] | 1.4 1.4 0] |
| Mometasone furoate | 129.3 (8.8–453.1) 216.4] | 418.3 (2.8–1573.0) 770.9] | 576.2 (7.2–2262.6) 1124.3] | 10.9 (0–42.0) 20.7] | 414.0 (8.7–1554.4) 760.6] | 372.2 (2.0–1445.7) 715.8] | 10.6 (2.0–20.8) 9.4] | 9.5 (1.5–31.0) 14.4] |
| Prednisolone 17-valerate 21-acetate | 37.9 (0–187.7) 83.8] | 93.8 (0–466.8) 208.5] | 44.0 (0–218.8) 97.7] | 0.9 (0–4.7) 2.1] | 61.9 (0–305.9) 136.4] | 10.2 (0–50.3) 22.4] | 1.6 (0–8.0) 3.6] | 0.6 (0–3.0) 1.3] |
| Triamcinolone acetonide | 2.5 (0–8.4) 3.6] | 3.5 (0–12.6) 5.2] | 2.2 (0.3–5.2) 2.0] | <0.1 (—) —] | 3.4 (0–9.1) 3.7] | 0.6 (0–1.8) 0.7] | 0.2 (0–0.9) 0.4] | 0.4 (0–1.4) 0.6] |
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