Research Article

Oxidase-Like Catalytic Performance of Nano-MnO2 and Its Potential Application for Metal Ions Detection in Water

Table 1

Analytical results for the detection of metal ion-contaminated water samples by MnO2 nanozyme-2,6-DMP detecting systems.

Real samplesAdded Cu2+ (mmol·L−1)Detected Cu2+ (mmol·L−1)RecoveryRSD (n = 5)Added Zn2+ (mmol·L−1)Detected Zn2+ (mmol·L−1)RecoveryRSD (n = 5)Added Mn2+ (mmol·L−1)Detected Mn2+ (mmol·L−1)RecoveryRSD (n = 5)Added Fe2+ (mmol·L−1)Detected Fe2+ (mmol·L−1)RecoveryRSD (n = 5)

Pond water 10.0020.002104.8%6.9%0.0020.002108.6%7.3%0.0020.002106.7%5.4%0.0020.002116.5%13.2%
0.010.010101.1%3.7%0.010.013111.2%10.5%0.010.00998.6%6.3%0.010.011114.9%8.8%
0.050.052105.8%5.4%0.050.051102.7%3.8%0.050.053106.1%7.4%0.050.056111.9%26.1%
0.250.253106.6%4.9%0.250.024897.8%4.3%0.250.255112.4%11.2%0.250.24696.6%12.0%

Pond water 20.0020.002106.9%9.8%0.0020.00295.0%6.7%0.0020.002106.5%6.3%0.0020.002110.5%15.7%
0.010.00993.0%11.2%0.010.013111.2%5.3%0.010.012124.0%11.8%0.010.011114.3%8.6%
0.050.054108.6%7.6%0.050.052104.4%4.2%0.050.04794.5%4.9%0.050.04897.2%7.3%
0.250.24899.4%3.3%0.250.24698.5%3.1%0.250.254101.7%2.2%0.250.252100.9%3.5%