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International Journal of Corrosion
Volume 2012 (2012), Article ID 573964, 6 pages
http://dx.doi.org/10.1155/2012/573964
Research Article

Study of a Triazole Derivative as Corrosion Inhibitor for Mild Steel in Phosphoric Acid Solution

School of Chemical Science and Technology, Yunnan University, Kunming, Yunnan 650091, China

Received 14 July 2011; Accepted 16 November 2011

Academic Editor: Omar S. Es-Said

Copyright © 2012 Lin Wang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The corrosion inhibition by a triazole derivative (PAMT) on mild steel in phosphoric acid (H3PO4) solution has been investigated by weight loss and polarization methods. The experimental results reveal that the compound has a significant inhibiting effect on the corrosion of steel in H3PO4 solution. It also shows good corrosion inhibition at higher concentration of H3PO4. Potentiodynamic polarization studies have shown that the compound acts as a mixed-type inhibitor retarding the anodic and cathodic corrosion reactions with predominant effect on the cathodic reaction. The values of inhibition efficiency obtained from weight loss and polarization measurements are in good agreement. The adsorption of this compound is found to obey the Langmuir adsorption isotherm. Some kinetic and thermodynamic parameters such as apparent activation energy, frequency factor, and adsorption free energy have been calculated and discussed.