Research Article
Garcinia indica as an Environmentally Safe Corrosion Inhibitor for Aluminium in 0.5 M Phosphoric Acid
Table 1
Results of Tafel polarization studies on aluminum in 0.5 M phosphoric acid solution containing different concentrations of inhibitor GIE.
| Temp. (°C) | Conc. of inhibitor (ppm) | (mV versus SCE) | (×m A cm−2) |
(mV dec−1) |
(mV dec−1) | CR (mm y−1) | (%) |
| 30 | Blank | −797 | 0.17 | 637 | 354 | 1.89 | — | 100 | −795 | 0.09 | 626 | 356 | 1.03 | 45.33 | 200 | −805 | 0.08 | 634 | 346 | 0.91 | 51.96 | 300 | −772 | 0.08 | 611 | 361 | 0.85 | 54.77 | 400 | −801 | 0.06 | 686 | 333 | 0.70 | 62.99 | 500 | −785 | 0.06 | 664 | 346 | 0.63 | 66.58 |
| 35 | Blank | −793 | 0.22 | 610 | 353 | 2.39 | — | 100 | −788 | 0.11 | 641 | 367 | 1.18 | 50.64 | 200 | −779 | 0.10 | 674 | 342 | 1.06 | 55.66 | 300 | −796 | 0.09 | 668 | 365 | 0.96 | 59.68 | 400 | −796 | 0.07 | 685 | 353 | 0.80 | 66.70 | 500 | −764 | 0.06 | 632 | 319 | 0.71 | 70.37 |
| 40 | Blank | −797 | 0.28 | 596 | 364 | 3.00 | — | 100 | −774 | 0.12 | 615 | 374 | 1.34 | 55.38 | 200 | −789 | 0.11 | 621 | 373 | 1.16 | 61.30 | 300 | −796 | 0.10 | 642 | 371 | 1.06 | 64.56 | 400 | −777 | 0.08 | 670 | 321 | 0.84 | 72.15 | 500 | −769 | 0.07 | 655 | 299 | 0.75 | 75.17 |
| 45 | Blank | −804 | 0.40 | 595 | 367 | 4.38 | — | 100 | −797 | 0.16 | 578 | 397 | 1.75 | 60.04 | 200 | −799 | 0.14 | 616 | 380 | 1.49 | 66.01 | 300 | −793 | 0.11 | 642 | 380 | 1.24 | 71.70 | 400 | −780 | 0.10 | 716 | 312 | 1.14 | 74.03 | 500 | −665 | 0.08 | 546 | 264 | 0.84 | 80.84 |
| 50 | Blank | −800 | 0.48 | 579 | 379 | 5.20 | — | 100 | −765 | 0.16 | 573 | 370 | 1.73 | 66.75 | 200 | −806 | 0.14 | 586 | 396 | 1.56 | 70.09 | 300 | −810 | 0.12 | 595 | 392 | 1.28 | 75.38 | 400 | −738 | 0.09 | 609 | 366 | 1.02 | 80.44 | 500 | −639 | 0.07 | 616 | 343 | 0.75 | 85.59 |
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