Research Article
Catalyst Initiation in the Oscillatory Carbonylation Reaction
Table 1
Hypothetical reactions.
| | Hypothetical reactions | Reaction rate | Model | | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 |
| a | CO→ | [CO] | + | + | + | + | + | + | + | + | + | + | + | + | b | →CO | | + | + | + | + | + | + | + | + | + | + | + | + | c | PdI2 + CO + H2O → HPdI + HI + CO2 | [PdI2][CO] | + | | | + | + | + | + | + | + | + | + | + | d | PdI2 + CO + H2O → IPdCOOH + HI | [PdI2][CO] | | + | | | | | | | | | | | e | IPdCOOH → HPdI + CO2 | [IPdCOOH] | | + | | | | | | | | | | | f | HPdI → HI + Pd | [HPdI] | + | + | | + | + | + | + | + | + | + | + | + | g | PdI2 + CH3OH + CO → IPdCOOCH3 + HI | [PdI2][CO] | | | + | + | + | + | + | + | + | + | + | + | h | IPdCOOCH3 + HI → PdI2 + CH3OH + CO | [IPdCOOCH3][HI] | | | + | + | + | + | + | + | + | + | + | + | i | Pd + PdI2→ Pd2I2 | [Pd][PdI2] | | | | | + | + | + | + | + | + | + | + | j | PdI2 + CO + H2O → HPdI + HI + CO2 | [PdI2][H2O][Pd] | | | | | + | | | | | | | | k | PdI2 + CO + H2O → HPdI + HI + CO2 | [PdI2][H2O][HI] | | | | | | + | | | | | | | l | PdI2 + CO + H2O → HPdI + HI + CO2 | [PdI2][H2O][HPdI] | | | | | | | + | | | | | | m | PdI2 + CO + H2O → HPdI + HI + CO2 | [PdI2][H2O][Pd2I2] | | | | | | | | + | | | | | n | HPdI → HI + Pd | [HPdI][Pd] | | | | | | | | | + | | | | o | HPdI → HI + Pd | [HPdI][HI] | | | | | | | | | | + | | | p | HPdI → HI + Pd | [HPdI]2 | | | | | | | | | | | + | | q | HPdI → HI + Pd | [HPdI][Pd2I2] | | | | | | | | | | | | + |
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