Research Article
Catalyst Initiation in the Oscillatory Carbonylation Reaction
Table 3
Rate constants (Models 5–8) estimated using BatchCad kinetic fitting package.
| Rate constant (min−1) | Model 5 | Model 6 | Model 7 | Model 8 | Model 5 | Model 6 | Model 7 | Model 8 | Additional constraint: = 0 |
| | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | | 8.26·10−3 | 8.26·10−3 | 8.26·10−3 | 8.26·10−3 | 8.26·10−3 | 8.26·10−3 | 8.26·10−3 | 8.26·10−3 | | 3.88·102 | 1.69·102 | 2.59·102 | 6.74·102 | 4.15·102 | 1.69·102 | 2.59·102 | 6.74·102 | | 3.95·10−3 | 4.16·10−3 | 4.81·10−3 | 9.18·10−2 | 5.14·10−3 | 4.16·10−3 | 4.81·10−3 | 9.18·10−2 | | 2.38·10−6 | 3.86·10−6 | 5.46·10−10 | 8.38·10−16 | 3.53·10−7 | 3.86·10−6 | 5.46·10−10 | 8.40·10−16 | | 5.69·10−3 | 8.04·10−3 | 6.01·10−3 | 1.53·10−5 | 3.21·10−3 | 8.04·10−3 | 6.01·10−3 | 1.53·10−5 | | 1.52·10−6 | 7.63·10−7 | 2.22·10−6 | 2.00·101 | 1.00·102 | 1.00·102 | 1.00·102 | 3.97·101 | | 2.66·107 | | | | 5.18·107 | | | | | | 1.39·106 | | | | 1.39·106 | | | | | | 1.21·106 | | | | 1.21·106 | | | | | | 2.63 | | | | 2.63 |
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