Advanced Control of a Continuous Solution Copolymerization Process

Table 8

Kinetic and thermodynamic parameters for deterministic model.

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Kinetic parameters

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𝜀=1

𝐴_𝑖=4,5⋅10¹⁴ l/s

𝐴_𝑐𝑎𝑎=4,209⋅10¹¹ m³/kmol ⋅ s

𝐴_𝑐𝑏𝑏=1,61⋅10⁹ m³/kmol ⋅ s

𝐴_𝑑𝑎𝑎=0,0; 𝐴_𝑑𝑏𝑏=0,0

𝐴_𝑝𝑎𝑎=3,207⋅10⁶ m³/kmol ⋅ s

𝐴_𝑝𝑎𝑏=1,233⋅10⁵ m³/kmol ⋅ s

𝐴_𝑝𝑏𝑎=2,103⋅10⁸ m³/kmol ⋅ s

𝐴_𝑝𝑏𝑏=6,308⋅10⁶ m³/kmol ⋅ s

𝐴_𝑥𝑎𝑎=32,08 m³/kmol ⋅ s

𝐴_𝑥𝑎𝑏=1,234 m³/kmol ⋅ s

𝐴_𝑥𝑎𝑠=86,6 m³/kmol ⋅ s

𝐴_𝑥𝑎𝑡=2085,0 m³/kmol ⋅ s

𝐴_𝑥𝑏𝑎=5,257⋅10⁴ m³/kmol ⋅ s

𝐴_𝑥𝑏𝑏=1577,0 m³/kmol ⋅ s

𝐴_𝑥𝑏𝑠=1514,0 m³/kmol ⋅ s

𝐴_𝑥𝑏𝑡=4,163⋅10⁵ m³/kmol ⋅ s

𝐴_𝑧𝑎=2,2 m³/kmol ⋅ s

𝐴_𝑧𝑏=1,13⋅10⁵ m³/kmol ⋅ s

𝐸_𝑖=1,255⋅10⁵² kJ/kmol

𝐸_𝑐𝑎𝑎=2,69⋅10⁴ kJ/kmol

𝐸_𝑐𝑏𝑏=4,00×10³ kJ/kmol

𝐸_𝑑𝑎𝑎=0,0; 𝐸_𝑑𝑏𝑏=0,0

𝐸_𝑝𝑎𝑎=2,42⋅10⁴ kJ/kmol

𝐸_𝑝𝑎𝑏=2,42⋅10⁴ kJ/kmol

𝐸_𝑝𝑏𝑎=1,80⋅10⁴ kJ/kmol

𝐸_𝑝𝑏𝑏=1,80⋅10⁴ kJ/kmol

𝐸_𝑥𝑎𝑎=2,42⋅10⁴ kJ/kmol

𝐸_𝑥𝑎𝑏=2,42⋅10⁴ kJ/kmol

𝐸_𝑥𝑎𝑠=2,42⋅10⁴ kJ/kmol

𝐸_𝑥𝑎𝑡=2,42⋅10⁴ kJ/kmol

𝐸_𝑥𝑏𝑎=1,80⋅10⁴ kJ/kmol

𝐸_𝑥𝑏𝑏=1,80⋅10⁴ kJ/kmol

𝐸_𝑥𝑏𝑠=1,80⋅10⁴ kJ/kmol

𝐸_𝑥𝑏𝑡=1,80⋅10⁴ kJ/kmol

𝐸_𝑧𝑎=0,0; 𝐸_𝑧𝑏=0,0

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Thermodynamic parameters

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- Δ𝐻_𝑝𝑎𝑎=54,0⋅10³ kJ/kmol

- Δ𝐻_𝑝𝑏𝑎=54,0⋅10³ kJ/kmol

- Δ𝐻_𝑝𝑎𝑏=86,0⋅10³ kJ/kmol

- Δ𝐻_𝑝𝑏𝑏=86,0⋅10³ kJ/kmol

𝜌_𝑟=8,79⋅10² kg/m³, 𝐶_𝑟=2,01 kJ/kg ⋅ K, 𝑈_𝑟=6,0.10⁻² kJ/m² ⋅ s ⋅ K

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