The Effects of Mixing, Reaction Rates, and Stoichiometry on Yield for Mixing Sensitive Reactions—Part II: Design Protocols

Table 2

Stoichiometries of reaction schemes and the corresponding dimensionless reaction rate ratio for the eight different C-C reactions. Da was always Da =𝑘^′₁(𝜌_𝑇/𝑀)(𝐿²_𝐵/𝐷_𝐵).

Case	Reaction scheme	𝜖,𝛼,𝛽,𝛾	𝑘2/𝑘1
1	𝐴+𝐵−−→^𝑘′12𝑃	1, 2, 1, 1	(1/2)𝑘^′2/𝑘^′1
	𝑃+𝐵−−→^𝑘′2𝑆
2	𝐴+𝐵−−→^𝑘′1𝑃	1, 1, 1, 1	(1/2)𝑘^′2/𝑘^′1
	𝑃+𝐵−−→^𝑘′2𝑆
3	𝐴+𝐵−−→^𝑘′1𝑃	1, 1, 2, 1	(1/2)𝜌𝑇/𝑀𝑘^′2/𝑘^′1
	2𝑃+𝐵−−→^𝑘′2𝑆
4	𝐴+𝐵−−→^𝑘′12𝑃	1, 2, 2, 1	𝜌𝑇/𝑀𝑘^′2/𝑘^′1
	2𝑃+𝐵−−→^𝑘′2𝑆
5	𝐴+𝐵−−→^𝑘′12𝑃	1, 2, 1, 2	(1/2)𝜌𝑇/𝑀𝑘^′2/𝑘^′1
	𝑃+2𝐵−−→^𝑘′2𝑆
6	𝐴+𝐵−−→^𝑘′1𝑃	1, 1, 1, 2	(1/2)𝜌𝑇/𝑀𝑘^′2/𝑘^′1
	𝑃+2𝐵−−→^𝑘′2𝑆
7	𝐴+𝐵−−→^𝑘′1𝑃	1, 1, 2, 2	(1/2)𝜌𝑇/𝑀^2𝑘^′2/𝑘^′1
	2𝑃+2𝐵−−→^𝑘′2𝑆
8	𝐴+𝐵−−→^𝑘′12𝑃	1, 2, 2, 2	𝜌𝑇/𝑀^2𝑘^′2/𝑘^′1
	2𝑃+2𝐵−−→^𝑘′2𝑆