Research Article

Titanium Dioxide-Mediated Photcatalysed Degradation of Two Herbicide Derivatives Chloridazon and Metribuzin in Aqueous Suspensions

Table 1

(a) Comparison of degradation rate of CHL and MET in the presence of different types of TiO2 samples. Experimental conditions: CHL (0.18 mM), MET (0.30 mM),  mL, photocatalysts: Degussa P25 (1 gL−1), Sachtleben Hombikat UV100 (1 gL−1), PC500 (1 g−1), irradiation time: 60 min (CHL), 28 min (MET). (b) Comparison of mineralization rate of CHL and MET in the presence of TiO2 and TiO2/H2O2. Experimental conditions: CHL (0.55 mM), MET (0.11 mM),  mL, photocatalysts: Degussa P25 (1 gL−1), irradiation time: 60 min (CHL), 28 min (MET).

(a) Rate of photodegradation (mmol L−1 min−1) (b) Rate of photomineralization (mmol L−1 min−1)
P25UV100 PC500 /P25 /P25/H2O2

Chloridazon0.00210.00180.0011 0.0003 0.0022
Metribuzin 0.0360.025 0.025 0.0003 0.0008