Simple Ion Transfer at Liquid|Liquid Interfaces

Figure 1

Cyclic voltammograms for the transfer of TEA⁺. Quiescent solutions (black line) and aqueous phase agitated at 600 rpm (red line). Organic phase: 1.0 × 10⁻²M TPADCC. Aqueous phase: KCl 1.0 × 10⁻² M + 8.0 × 10⁻⁴ M TEABr. 𝜈=0.025 V s⁻¹.