International Journal of Inorganic Chemistry
Volume 2010 (2010), Article ID 326568, 6 pages
doi:10.1155/2010/326568
Research Article

Syntheses and Crystal Structures of [Cu3{μ-(NSPh2)2N}2Cl2] and [Cu3{μ-(NSPh2)2N}2{(NSPh2)2N}2]Cl2

Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University, Izumi, Narashino, Chiba 275-8575, Japan

Received 31 August 2009; Accepted 10 November 2009

Academic Editor: J. D. Woollins

Copyright © 2010 Takayoshi Fujii et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. O. Glemser and R. Mews, “Chemistry of thiazyl fluoride (NSF) and thiazyl trifluoride (NSF3): a quarter century of sulfur-nitrogen-fluorine chemistry,” Angewandte Chemie International Edition, vol. 19, no. 11, pp. 883–899, 1980.
  2. U. Behrens, E. Lork, J. Petersen, A. Waterfeld, and R. Mews, “Thiazyltrifluoride NSF3 and thiazyldifluoridedimethylamide NSF2NMe2: ligands in organometallic chemistry,” Zeitschrift für Anorganische und Allgemeine Chemie, vol. 623, no. 10, pp. 1518–1524, 1997. View at Scopus
  3. R. Mews, E. Lork, P. G. Watson, and B. Görtler, “Coordination chemistry in and of sulfur dioxide,” Coordination Chemistry Reviews, vol. 197, no. 1, pp. 277–320, 2000. View at Scopus
  4. R. Mews, T. Borrmann, R. Hoppenheit, et al., “Fluorothiazynes, 50 years old and still exciting: electrophilic attack at the thiazyl nitrogen of NSF2NS(O)F2,” Journal of Fluorine Chemistry, vol. 125, no. 11, pp. 1649–1655, 2004. View at Publisher · View at Google Scholar · View at Scopus
  5. T. Yoshimura, K. Hamada, M. Imado, et al., “First preparation and X-ray crystallographic structure determination of S,S,S-triphenylthiazyne,” The Journal of Organic Chemistry, vol. 62, no. 12, pp. 3802–3803, 1997. View at Scopus
  6. T. Yoshimura, M. Ohkubo, T. Fujii, et al., “Synthesis, structure, and thermolysis mechanism of S-alkoxythiazynes,” Bulletin of the Chemical Society of Japan, vol. 71, no. 7, pp. 1629–1637, 1998. View at Scopus
  7. T. Yoshimura, T. Fujii, S. Murotani, et al., “The structures of [Ph2XS-N-SPh2NH]+ cations (X=NH, O),” Journal of Organometallic Chemistry, vol. 611, no. 1-2, pp. 272–279, 2000. View at Scopus
  8. T. Fujii, T. Fujimori, S. Miyoshi, S. Murotani, M. Ohkubo, and T. Yoshimura, “The structures of diphenyl(diphenylsulfimido) (nitrido)sulfur(VI) and diphenyl(diphenylsulfodiimido)(nitrido)sulfur(VI), Ph2(X)S=N-(Ph2)SN (X = lone pair, NH),” Heteroatom Chemistry, vol. 12, no. 4, pp. 263–268, 2001. View at Scopus
  9. T. Fujii, A. Itoh, K. Hamata, and T. Yoshimura, “First preparation and crystal structure of heterocyclic λ6-sulfanenitrile, 2,2-biphenylylene(phenyl)-λ6-sulfanenitrile,” Tetrahedron Letters, vol. 42, no. 30, pp. 5041–5043, 2001. View at Publisher · View at Google Scholar · View at Scopus
  10. T. Fujii, T. Suzuki, T. Sato, E. Horn, and T. Yoshimura, “Synthesis, structure, and reactivity of iminosulfonium ylides bearing an α-carbonyl group,” Tetrahedron Letters, vol. 42, no. 35, pp. 6151–6154, 2001. View at Publisher · View at Google Scholar · View at Scopus
  11. T. Fujii, T. Ikeda, T. Mikami, T. Suzuki, and T. Yoshimura, “Synthesis and structure of (MeN)Ph2S=C=SPh2(NMe),” Angewandte Chemie International Edition, vol. 41, no. 14, pp. 2576–2578, 2002. View at Publisher · View at Google Scholar · View at Scopus
  12. T. Fujii, S. Asai, T. Okada, W. Hao, H. Morita, and T. Yoshimura, “A new method for the preparation of fluoro-λ6-sulfanenitriles: reaction of sulfimides with selectfluorTM,” Tetrahedron Letters, vol. 44, no. 33, pp. 6203–6205, 2003. View at Publisher · View at Google Scholar · View at Scopus
  13. T. Fujii, M. Kanno, M. Hirata, T. Fujimori, and T. Yoshimura, “Synthesis and properties of Ph2S(=N-(Ph2)SN)2,” Inorganic Chemistry, vol. 44, no. 24, pp. 8653–8655, 2005. View at Publisher · View at Google Scholar · View at PubMed · View at Scopus
  14. T. Fujii, T. Takano, S. Asai, H. Morita, M. Hirata, and T. Yoshimura, “10-Oxo-10H-5λ4,10λ4-thianthren-5-ylideneamine as a probe for stereochemistry in the formation and amination of fluoro-λ6-sulfanenitriles,” Tetrahedron, vol. 62, no. 41, pp. 9622–9627, 2006. View at Publisher · View at Google Scholar · View at Scopus
  15. T. Fujii, M. Kanno, M. Hirata, T. Nakahodo, T. Wakahara, and T. Akasaka, “Synthesis and characterization of Co(II), Ni(II), and Cu(II) complexes containing an eight-membered disulfanenitrile chelating ring,” Inorganica Chimica Acta, vol. 361, no. 8, pp. 2540–2546, 2008. View at Publisher · View at Google Scholar · View at Scopus
  16. T. Fujii, S. Iwata, M. Hirata, et al., “Syntheses and crystal structures of [ClPh2Sn{E(Ph2SN)2}](E=CH,N),” Phosphorus, Sulfur and Silicon and the Related Elements. In press.
  17. G. M. Sheldrick, “A short history of SHELX,” Acta Crystallographica Section A, vol. 64, no. 1, pp. 112–122, 2008. View at Publisher · View at Google Scholar · View at PubMed · View at Scopus
  18. T. Yoshimura, T. Fujii, and H. Dai, “Synthesis and crystal structures of [CuCl2(μ-NSPh3)]2 and [CuCl2(Ph3SN)2]: novel copper complexes bearing organic λ6-sulfanenitrile as ligand,” Chemistry Letters, vol. 31, no. 10, pp. 1000–1001, 2002. View at Scopus